PVA水溶液浓度对PTFE纤维膜形貌与性能的影响

张晨阳, 李新梅*, 刘伟斌, 王晓辉, 黄永

化工新型材料 ›› 2022, Vol. 50 ›› Issue (11) : 70 -73.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (11) : 70-73. DOI: 10.19817/j.cnki.issn1006-3536.2022.11.013
新材料与新技术

PVA水溶液浓度对PTFE纤维膜形貌与性能的影响

    张晨阳, 李新梅*, 刘伟斌, 王晓辉, 黄永
作者信息 +

Effect of concentration of PVA solution on morphology and properties of PTFE fiber membranes

  • Zhang Chenyang, Li Xinmei, Liu Weibin, Wang Xiaohui, Huang Yong
Author information +
文章历史 +
PDF

摘要

采用静电纺丝法,以聚乙烯醇(PVA)为粘结剂,聚四氟乙烯(PTFE)为溶质,制备PTFE超疏水纳米纤维膜。通过扫描电镜和光学水接触角测量仪分析不同PVA水溶液浓度下的纤维膜表面形貌及疏水性能。结果表明,纺丝液具有良好的纺丝性能;当PVA水溶液浓度为10%时,电纺法制备的PTFE纤维膜形貌良好,且水接触角高达160°,具有优异的超疏水性能。

Abstract

Using PVA as binder and PTFE as solute,super hydrophobic PTFE nanofiber membranes were prepared by electrospinning method.The surface morphology and hydrophobic properties of the fiber membranes under different concentrations of PVA solution were analyzed via scanning electron microscopy (SEM) and optical water contact angle.The results showed that the spinning solution exhibited good spinning properties.When the concentration of PVA solution was 10%,the PTFE fiber membranes prepared by electrospinning method had a good morphology water contact Angle was up to 160°,and presented excellent superhydrophobic properties.

关键词

静电纺丝 / 超疏水 / 聚四氟乙烯 / 纳米纤维膜 / 聚乙烯醇浓度

Key words

electrospinning / super hydrophobic / PTFE / nanofiber membrane / concentration of PVA solution

引用本文

引用格式 ▾
PVA水溶液浓度对PTFE纤维膜形貌与性能的影响[J]. 化工新型材料, 2022, 50(11): 70-73 DOI:10.19817/j.cnki.issn1006-3536.2022.11.013

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 李国滨,刘海峰,李金辉,等.超疏水材料的研究进展[J].高分子材料科学与工程,2020(12):142-150.
[2] 顾榴俊.聚四氟乙烯及其应用研究进展[J].浙江化工,2020(3):1-5.
[3] 王瑞柳,徐广标,何越超.聚四氟乙烯(PTFE)纤维结构、性能与应用研究进展[J].纺织科学与工程学报,2018,35(3):113-117,123.
[4] Yong J L,Fang Y,Chen F,et al.Femtosecond laser ablated durable superhydrophobic PTFE films with micro-through-holes for oil/water separation:separating oil from water and corrosive solutions[J].Applied Surface Science,2016,389:1148-1155.
[5] Li M J,Chen F,Liu C B,et al.Electrospun fibrous PTFE supported ZnO for oil-water separation[J].Journal of Inorganic and Organometallic Polymers and Materials,2019,29(5):1738-1745.
[6] Huang Y,Xiao C,Huang Q,et al,Robust preparation of tubular PTFE/FEP ultrafine fibers-covered porous membrane by electrospinning for continuous highly effective oil/water separation[J].Journal of Membrane Science,2018,568:87-96.
[7] Wang S Q,Wang Y M,Zou Y C,et al.A self-adjusting PTFE/TiO2 hydrophobic double-layer coating for corrosion resistance and electrical insulation[J].Chemical Engineering Journal,2020,402:1-37.
[8] Gao M L,Wu X B,Gao P P,et al.Properties of hydrophobic carbon-PTFE composite coating with high corrosion resistance by facile preparation on pure Ti[J].Transactions of Nonferrous Metals Society of China,2019,29(11):2321-2330.
[9] Huang Q L,Huang Y,Xiao C F,et al.Electrospun ultrafine fibrous PTFE-supported ZnO porous membrane with self-cleaning function for vacuum membrane distillation[J].Journal of Membrane Science,2017,534:73-82.
[10] Cheng J X,Huang Q L,Huang Y,et al.Study on a novel PTFE membrane with regular geometric pore structures fabricated by near-field electrospinning,and its applications[J].Journal of Membrane Science,2020,603:1-10.
[11] Huang Q L,Xiao C F,Hu X Y,et al.Study on the effects and properties of hydrophobic poly(tetrafluoroethylene) membrane[J].Desalination,2011,277(1):187-192.
[12] Pang H L,Tian K X,Li Y P,et al.Super-hydrophobic PTFE hollow fiber membrane fabricated by electrospinning of Pullulan/PTFE emulsion for membrane deamination[J].Separation and Purification Technology,2020,118186:1-22.
[13] Lee M K,Park C,Jang T S,et al.Enhanced mechanical stability of PTFE coating on nano-roughened NiTi for biomedical applications[J].Materials Letters,2018,216:12-15.
[14] Xue C H,Li Y R,Zhang P,et al.Washable and wear-resistant superhydrophobic surfaces with self-cleaning propertyby chemical etching of fibers and hydrophobization[J].ACS Applied Materials & Interfaces,2014,6(13):10153-10161.
[15] Wang A T,Li X L,Hou T,et al.High efficiency,low resistance and high temperature resistance PTFE porous fibrous membrane for air filtration[J].Materials Letters,2021,295:1-4.
[16] 洪贤良,陈小晖,张建青,等.静电纺多级结构空气过滤材料的研究进展[J].纺织学报,2020,41(6):174-182.
[17] Qing W H,Shi X N,Deng Y J,et al.Robust superhydrophobic-superoleophilic polytetrafluoroethylene nanofibrous membrane for oil/water separation[J].Journal of MembraneScience,2017,540:354-361.
[18] Huang Q L,Huang Y,Gao S P,et al.Novel ultrafine fibrous poly(tetrafluoroethylene) hollow fiber membrane fabricated by electrospinning[J].Polymers,2018,10(5):1-9.
[19] Yu S W,Huang Q L,Cheng J X,et al.Pore structure optimization of electrospun PTFE nanofiber membrane and its application in membrane emulsification[J].Separationand Purification Technology,2020,251:1-8.
[20] Xiong J,Huo P F,Frank K.K.Fabrication of ultrafine fibrous polytetrafluoroethylene porous membranes by electrospinning[J].Journal of Materials Research,2011,24(9):2755-2761.
[21] Zhou T,Yao Y Y,Xiang R L,et al.Formation and characterization of polytetrafluoroethylene nanofiber membranes for vacuum membrane distillation[J].Journal of Membrane Science,2014,453:402-408.
[22] 陈慕荣,刘雪强,张华鹏,等.离心纺丝法制备PTFE/PVA复合微纳米纤维膜[J].浙江理工大学学报(自然科学版),2020(5):625-631.
[23] Huang Y,Huang Q L,Liu H,et al.Preparation,characterization,and applicationsof electrospun ultrafine fibrous PTFE porous membranes[J].Journal of Membrane Science,2017,523:317-326.

基金资助

国家自然科学基金(51865055;51561029);新疆自治区天山英才计划资助项目(201720025)

AI Summary AI Mindmap
PDF

633

访问

0

被引

导航
相关文章

AI思维导图

/