纳米氧化铜作为各种反应的催化剂及催化剂的主要活性成分,其与聚合物复合制成纳米杂化纤维,经高温煅烧过程制备出纳米多孔氧化铜,在传感材料、电催化材料、热电材料以及医学等领域具有广泛的应用潜力。分析了静电纺丝制备氧化铜纳米纤维过程中参数影响和所合成纳米材料结构及形貌的影响规律,归纳和总结了氧化铜纳米材料的制备方法以及对纳米氧化铜的改性,指出了静电纺丝法制备氧化铜纳米杂化材料存在的问题,并提出了一种新型氧化铜纳米杂化材料修饰电极的方法。
Nano-copper oxide is used as catalyst for various reactions and the main active component of the catalyst.It is composited with polymers to make nano-hybrid fibers,and nano-porous copper oxide is prepared by high-temperature calcination.It is used in sensing and electrocatalytic materials,thermoelectric materials and medicine,and have a wide range of potential applications.The influence of parameters in the preparation of the nanofibers by electrospinning and the impact of the structure and morphology of the synthesized nanomaterials were analyzed.Additionally,the preparation and the modification of the nanomaterials were summarized.The problems existing in the preparation of copper oxide nano-hybrid materials by spinning method were presented,and proposed new approach for modifying electrodes with the materials.
[1] Waris A,Din M,Ali A,et al.A comprehensive review of green synthesis of copper oxide nanoparticles and their diverse biomedical applications[J].Inorganic Chemistry Communications,2021,123(5):108369.
[2] Park H.Fabrication of lanthanum copper oxide nanofibers by electrospinning[D].Florida:University of Florida,2005.
[3] Du A,Zhou B,Shen J,et al.Monolithic copper oxide aerogel via dispersed inorganic sol-gel method[J].Journal of Non-Crystalline Solids,2009,355(3):175-181.
[4] Pendashteh A,Mousavi M F,Rahmanifar M S.Fabrication of anchored copper oxide nanoparticles on graphene oxide nanosheets via an electrostatic coprecipitation and its application as supercapacitor[J].Electrochimica Acta,2013,88(2):347-357.
[5] Fan J,Dai Y,Li Y,et al.Low-temperature,highly selective,gas-phase oxidation of benzyl alcohol over mesoporous K-Cu-TiO2 with stable copper(I) oxidation state[J].Journal of the American Chemical Society,2009,131(43):15568-15569.
[6] Morton W J.Method of dispersing fluids:US705691A[P].1902-07-29.
[7] Anton F.Process and apparatus for preparing artificial threads:US975504[P].1934-10-02.
[8] Kim G,Lee S,Michler G,et al.Nanostructured pure anatase titania tubes replicated from electrospun polymer fiber templates by atomic layer deposition[J].Chemistry of Materials,2008,20(9):3085-3091.
[9] Lee J P,Choi S,Cho S,et al.Fabrication of carbon nanofibers decorated with various kinds of metal oxides for battery applications[J].Energies,2021,14(5):1-10.
[10] 刘文胜,杨波平,马运柱,等.超细氧化铝基陶瓷纤维的静电纺丝制备[J].中南大学学报:自然科学版,2018,49(2):300-306.
[11] 付泽浩,向阳,马传国,等.FeOOH纳米粒子协同聚偏氟乙烯电纺纤维膜插层增强碳纤维复合材料层间断裂韧性[J].复合材料学报,2022,39(4):1582-1591.
[12] Cai Y,Wang W,Chen Z,et al.Formation of copper oxide nanowires and nanoparticles via electrospinning[J].Science China Technological Sciences,2015,58(4):612-616.
[13] Wang B,Luo L,Ding Y,et al.Synthesis of hollow copper oxide by electrospinning and its application as a nonenzymatic hydrogen peroxide sensor[J].Colloids and Ssurfaces B:Biointerfaces,2012,97:51-56.
[14] Dacquin J,Dujardin C,Granger P.Surface reconstruction of supported Pd on LaCoO3:consequences on the catalytic properties in the decomposition of N2O[J].Journal of Catalysis,2008,253(1):37-49.
[15] Lee J E,Bera S,Choi Y S,et al.Size-dependent plasmonic effects of M and M@SiO2 (M=Au or Ag) deposited on TiO2 in photocatalytic oxidation reactions[J].Applied Catalysis B:Environmental,2017,214:15-22.
[16] Shimada M,Yamamoto T,Takahashi Y,et al.Dispersion of nano-materials in polymer composite materials[J].MATEC Web of Conferences,2021,333:11003.
[17] Wu S,Li F,Zhang L,et al.Enhanced field emission properties of CuO nanoribbons decorated with Ag nanoparticles[J].Materials Letters,2016,171(15):220-223.
[18] He M,Wang Y,Wang H,et al.A one-step sol-gel route derived Ag-CuO film as a novel solar selective absorber[J].Solar Energy Materials and Solar Cells,2016,144:264-272.
[19] Mahmoudian M R,Basirun W J,Alias Y.Synthesis of 3D hierarchical Ag/CuO nanostructures in the presence of l-histidine and their application[J].Journal of Alloys and Compounds,2017,699:803-811.
[20] 张雪影,田陆.一种氧化铜/四氧化三钴复合材料及其制备方法和应用:CN111364126A[P].2020-07-03.
[21] Hosseini S R,Ghasemi S,Kamali-Rousta M.Preparation of CuO/NiO composite nanofibers by electrospinning and their application for electro-catalytic oxidation of hydrazine[J].Journal of Power Sources,2017,343(1):467-476.
[22] Vijayakumar G N.Electrical and optical characterization of copper oxide/calcium oxide nanocomposite fibers[J].Journal of Nanoscience & Nanotechnology,2014,14(4):3117-3122.
[23] 田亮亮.银/氧化铜纳米带/泡沫铜复合电极的制备及其在双氧水电化学传感器中的应用[J].现代化工,2020,40(12):127-131.
[24] Alizadeh T,Mirzagholipur S.A Nafion-free non-enzymatic amperometric glucose sensor based on copper oxide nanoparticles-graphene nanocomposite[J].Sensors and Actuators B:Chemical,2014,198:438-447.
基金资助
河南省工程技术研究中心(豫科2016-221号-高新35);第三批智汇郑州1125·聚才计划——创新紧缺人才(郑政[2018]-45号-15);2023年度河南省高等学校重点科研项目(教办科技(2022)150号);华北水利水电大学2021年大学生创新创业训练计划项目([2021XB011])
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