水质的迅速下降和全球对水资源的需求日益增长,推动了对高性能水净化材料的追求。介绍民水中存在的污染物类型及其有效去除所面临的挑战。综述了近年来活性炭、碳纳米管、石墨烯及其复合材料等新型净水材料在净水方面取得的研究进展,并展望了净水材料的未来发展。
The rapidly decreasing quality of water and the growing global demand for water resource has driven the pursuit of high-performance purification materials.The main types of contaminants in water and the challenges associated with their effective removal were introduced.The research progress of novel materials for water purification with activated carbon,carbon nanotubes and graphene in recent years were reviewed.And the future development of water purification materials was also discussed.
[1] Liu R N,Yang W X,Liu Y H,et al.Research progress on heavy metal adsorption by fruit-shell biomass in water[J].Water Pollution and Treatment,2019,7(3):119-130.
[2] Yan Z L,Hou Z S,Tian Y L.Advances in wastewater treatment of waste metal cutting Fluid[J].Advanced Materials Research,2015,3818:573-577.
[3] 曾柏淞.工业废水处理方法研究进展[J].化学工程与装备,2020(9):257-258.
[4] Niu J,Kasuga I,Kurisu F.Effects of backwashing on granular activated carbon with ammonium removal potential in a full-Scale drinking water purification plant[J].Water,2018,10(12):1-8.
[5] 张莉.碳纳米管的吸附性能及对水中污染物的吸附[J].材料导报,2020,34(S1):72-77,85.
[6] Wang G L,Li G F,Huan Y Y,et al.Acrylic acid functionalized graphene oxide:high-efficient removal of cationic dyes from wastewater and exploration on adsorption mechanism[J].Chemosphere,2020,261:1-11.
[7] King D N,Donohue M J,Vesper S J,et al.Microbial pathogens in source and treated waters from drinking water treatment plants in the united states and implications for human health[J].Sci Total Environ,2016,562:987-995.
[8] Schoumans O F,Chardon W J,Bechmann M E,et al.Mitigation options to reduce phosphorus losses from the agricultural sector and improve surface water quality:a review[J].Sci Total Environ,2014,468:1255-1266.
[9] Wang H X,Xu J L,Liu X J,et al.Preparation of straw activated carbon and its application in wastewater treatment:a review[J].Journal of Cleaner Production,2020,283:124671-124677.
[10] Li Y,Du Q,Liu T,et al.Comparative study of methylene blue dye adsorption onto activated carbon,graphene oxide,and carbon nanotubes[J].Chem Eng Res Des,2013,91:361-368.
[11] Li L,Quinlivan P A,Knappe D R U.Effects of activated carbon surface chemistry and pore structure on the adsorption of organic contaminants from aqueous solution[J].Carbon,2002,40:2085-2100.
[12] Collins J,Ngo T,Qu D,et al.Spectroscopic investigations of sequential nitric acid treatments on granulated activated carbon:effects of surface oxygen groups on π density[J].Carbon,2013,57:174-183.
[13] Yin C Y,Aroua M K,Daud W M A W.Review of modififications of activated carbon for enhancing contaminant uptakes from aqueous solutions[J].Sep Purif Technol,2007,52:403-415.
[14] Yürüm A,Kocaba s-Ataklí Z Ö,Sezen M,et al.Fast deposition of porous iron oxide on activated carbon by microwave heating and arsenic(Ⅴ) removal from water[J].Chem Eng J,2014,242:321-332.
[15] Jegadeesan G B,Mondal K,Lalvani S B.Adsorption of Se(Ⅳ) and Se(Ⅵ) using copper-impregnated activated carbon and flfly ash-extracted char carbon[J].Water Air Soil Pollut,2015,226:1-12.
[16] Watson K,Farré M J,Knight N.Comparing a silver-impregnated activated carbon with an unmodifified activated carbon for disinfection by-product minimisation and precursor removal[J].Sci Total Environ,2016,542:672-684.
[17] Reed B E,Vaughan R,Jiang L.As(Ⅲ),As(Ⅴ),Hg,and Pb removal by Fe-oxide impregnated activated carbon[J].J Environ Eng,2000,126:869-873.
[18] Alslaibi T M,Abustan I,Ahmad M A,et al.A review:production of activated carbon from agricultural byproducts via conventional and microwave heating[J].J Chem Technol Biotechnol,2013,88:1183-1190.
[19] Andersson A,Laurent P,Kihn A,et al.Impact of temperature on nitrification in biological activated carbon (BAC) filters used for drinking water treatment[J].Water Research,2001,35(12):2923-2934.
[20] Kasuga I,Shimazaki D,Kunikane S.Influence of backwashing on the microbial community in a biofilm developed on biological activated carbon used in a drinking water treatment plant[J].Water Science and Technology,2007,55(8):173-180.
[21] Lou J C,Yang C Y,Chang C J,et al.Analysis and removal of assimilable organic carbon (AOC) from treated drinking water using a biological activated carbon fifilter system[J].J Environ Chem Eng,2014(2):1684-1690.
[22] Chu W H,Gao N,Yin D,et al.Ozone-biological activated carbon integrated treatment for removal of precursors of halogenated nitrogenous disinfection by-products[J].Chemosphere,2012,86:1087-1091.
[23] Qin W,Li W G,Zhang D Y,et al.Ammonium removal of drinking water at low temperature by activated carbon fifilter biologically enhanced with heterotrophic nitrifying bacteria[J].Environ Sci Pollut Res,2016,23:4650-4659.
[24] Lou J C,Chan H Y,Han J Y,et al.High removal of haloacetic acids from treated drinking water using bio-activated carbon method[J].Desalination and Water Treatment,2016,57(53):25627-25638.
[25] 裴烈飞,姜丽丽,侯新刚,等.纳米材料在重金属及有机物废水处理中的应用[J].中国冶金,2018,28(8):1-5.
[26] 魏栖梧,周磊,王忠兵.磁性多壁碳纳米管的制备及其在重金属水处理方面的应用[J].南昌航空大学学报(自然科学版),2020,34(2):45-50.
[27] 张莉.碳纳米管的吸附性能及对水中污染物的吸附:综述[J].材料导报,2020,34(S1):72-77,85.
[28] 赵秀朕,李娜娜,师艳丽,等.碳纳米管的改性及其在分离膜中的应用进展[J].功能材料,2015,46(S2):28-31.
[29] Marshall M W,Popa-Nita S,Shapter J G.Measurement of functionalised carbon nanotube carboxylic acid groups using a simple chemical process[J].Carbon,2006,44:1137-1141.
[30] Kumar A S K,Jiang S J,Tseng W L.Effective adsorption of chromium(Ⅵ)/Cr(Ⅲ) from aqueous solution using ionic liquid functionalized multiwalled carbon nanotubes as a super sorbent[J].J Mater Chem A,2015(3):7044-7057.
[31] Zhao Z Y,Xiong Z H.Removal of four nitrofurans drugs from aqueous solution by magnetic multi-wall carbon nanotubes[J].Fullerenes Nanotubes and Carbon Nanostructures,2015,23(7):640-648.
[32] Ihsanullah,Al-Khaldi F A,Abusharkh B,et al.Adsorptive removal of cadmium(Ⅱ) ions from liquid phase using acid modifified carbon-based adsorbents[J].J Mol Liq,2015,204:255-263.
[33] Gao H J,Zhao S Y,Cheng X Y,et al.Removal of anionic azo dyes from aqueous solution using magnetic polymer multi-wall carbon nanotube nanocomposite as adsorbent[J].Chemical Engineering Journal,2013,223:84-90.
[34] Ahamad T,Naushad M,Eldesoky G E,et al.Effective and fast adsorptive removal of toxic cationic dye (MB) from aqueous medium using amino-functionalized magnetic multiwall carbon nanotubes[J].Journal of Molecular Liquids,2019,282:154-161.
[35] Jame S A,Zhou Z.Electrochemical carbon nanotube fifilters for water and wastewater treatment[J].Nanotechnol Rev,2016(5):41-50.
[36] 牟铭,顾宝珊,王仕东,等.石墨烯及其复合材料在水处理中的研究进展[J].化工新型材料,2019,47(12):16-21.
[37] 宋文哲,石利泺.石墨烯在水处理中的应用[J].炭素技术,2019,38(1):41-45.
[38] Ma W,Zhu J,Wang Z,et al.Recent advances in preparation and application of laser-induced graphene in energy storage devices[J].Materials Today Energy,2020,18:100569.
[39] 逯娟.石墨烯的制备方法及其应用领域的研究进展[J].能源与环保,2020,42(5):78-81,93.
[40] Zhou H,Gao B,Zhou Y M,et al.Facile preparation of 3D GO/CNCs composite with adsorption performance towards [BMIM][Cl] from aqueous solution[J].Journal of hazardous materials,2017,337:27-33.
[41] Rao G Y,Zhang Q Y,Zhao H Li,et al.Novel titanium dioxide/iron(Ⅲ) oxide/graphene oxide photocatalytic membrane for enhanced humic acid removal from water[J].Chem Eng J,2016,302:633-640.
[42] Jiang H B,Yang Y R,Lin Z K,et al.Preparation of a novel bio-adsorbent of sodium alginate grafted polyacrylamide/graphene oxide hydrogel for the adsorption of heavy metal ion[J].Science of The Total Environment,2020,744:1-10.
[43] Chen Y Q,Chen L B,Bai H,et al.Graphene oxide-chitosan composite hydrogels as broad-spectrum adsorbents for water purifification[J].J Mater Chem A,2013,1:1992-2001.
[44] Kang X,Cheng Y Y,Wen Y,et al.Bio-inspired co-deposited preparation of GO composite loose nanofiltration membrane for dye contaminated wastewater sustainable treatment[J].Journal of Hazardous Materials,2020,400:1-11.
[45] Lin C F,Chung L H,Lin G Y,et al.Enhancing the efficiency of a forward osmosis membrane with a polydopamine/graphene oxide layer prepared via the modified molecular layer-by-layer method[J].ACS Omega,2020,5(30):18738-18745.
[46] Gao H,Sun Y,Zhou J,et al.Mussel-inspired synthesis of polydopamine-functionalized graphene hydrogel as reusable adsorbents for water purifification[J].ACS Appl Mater Interfaces,2013,5:425-432.
基金资助
国家自然科学基金(52062047,21763029);陕西省教育厅重点科学研究计划(重点实验室)项目(18JS124,20JS162,21JS043);陕西省科技厅项目(2019SF-273);榆林市科技局项目(CXY-2020-006-06,CXY-2020-005-04,CXY-2020-006-03)
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