金属有机骨架(MOFs)材料是一种结构可设计、高比表面积的多孔材料,已知成功合成的MOFs种类已经多达2000多种。但MOFs材料大多存在固有缺陷,在一定程度上限制了其在光催化领域的广泛应用。UIO-67的合成对于MOFs稳定性的研究具有重要意义,与大部分MOFs材料相比,UIO-67系列有着更出色的热稳定性、化学稳定性及发达的微孔结构。首先介绍了UIO-67理想状态下的结构特征,并通过与同系列的UIO-66及UIO-68结构上的对比,阐述了其营造缺陷结构的催化机理。其次,对UIO-67系列材料在光催化领域进行了分类介绍,综述了近年UIO-67系列材料在光催化裂解水制氢、光催化还原CO2及光催化降解有机污染物方面的应用。最后提出UIO-67系列材料及功能化衍生物在光催化应用中面临的挑战和发展趋势。
Metal-organic framework (MOFs) materials are the porous materials and known for their designable structure and high specific surface area.It is known that more than 2,000 types of MOFs have been successfully synthesized.However,most of the MOFs materials have inherent defects,which limits the wide application of MOFs in the field of photocatalysis to a certain extent.The synthesis of the UIO-67 is of great significance to the stability research of MOFs.Compared to the most MOFs,the UIO-67 series offer better thermal stability,chemical stability,and have better-developed microporous structures.The structural characteristics of the UIO-67 in an ideal state were firstly introduced,and expounded its catalytic mechanism for creating defect structure through a comparison with the same series of UIO-66 and UIO-68.Secondly,the classification of the UIO-67 series materials in the field of photocatalysis were systematically described.Their applications in photocatalytic cracking of water to hydrogen production,photocatalytic reduction of CO2 and photocatalytic degradation of organic pollutants were comprehensively reviewed.Finally,the challenges and development trends of UIO-67 series materials and their functional derivatives in photocatalytic applications were identified.
[1] Zhao X L,Zhang L,Bai J G,et al.A copper-based metal-organic framework for ratiometric detection of hydrogen sulfide with high sensitivity and fast response[J].Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy,2020,56:14633-14641.
[2] 于吉行,俞俊,薛晓雅,等.金属有机骨架UIO-66在催化领域的应用[J].化工进展,2019,38(1):144-151.
[3] Petit C.Present and future of MOF research in the field of adsorption and molecular separation[J].Curr Opin Chem Eng,2018,20:132-142.
[4] Zhu J,Xia T,Cui Y,et al.Heme-copper assembly mediated reductive coupling of nitrogen monoxide (·NO)[J].Solid State Chem,2019,270:317-323.
[5] Adham A,Robertson C M,Alexander S,et al.Cu(Ⅰ)Cu(Ⅱ)BTC,a microporous mixed-valence MOF via reduction of HKUST-1[J].RSC Adv,2016,6(11):8902-8905.
[6] Rani R,Deep A,Mizaikoff B,et al.Enhanced hydrothermal stability of Cu MOF by post synthetic modification with amino acids[J].Vacuum,2019,164:449-457.
[7] Reddy A J M,Katari N K,Nagaraju P,et al.ZIF-8,Zn(NA) and Zn(INA) MOFs as chemical selective sensor of ammonia,formaldehyde and ethanol gases[J].Materials Chemistry and Physics,2019,241:122357.
[8] Uzak D,Atheer A,Vesen A,et al.Reduced graphene oxide/Pt nanoparticles/Zn-MOF-74 nanomaterial for a glucose biosensor construction[J].Electroanalysis,2019,31:1-11.
[9] Xie L,Yang Z,Xiong W,et al.Construction of MIL-53(Fe) metal-organic framework modified by silver phosphate nanoparticles as a novel Z-scheme photocatalyst:visible-light photocatalytic performance and mechanism investigation[J].Appl Surf Sci,2019,465(28):103-115.
[10] An Y,Li H,Liu Y,et al.Photoelectrical,photophysical and photocatalytic properties of Al based MOFs:MIL-53(Al) and MIL-53-NH2(Al)[J].J Sold State Chem,2016,233:194-198.
[11] Micha K,Leszczyński,Arkadiusz,et al.Straightforward synthesis of single-crystalline and redox-active Cr(Ⅱ)-carboxylate MOFs[J].Inorg Chem,2018,57(9):4803-4806.
[12] Wang L,Jin P X,Duan S H,et al.In-situ incorporation of copper(Ⅱ) porphyrin functionalized zirconium MOF and TiO2 for efficient photocatalytic CO2 reduction[J].Sci Bull,2019,64(13):926-933.
[13] Leng F C,Liu H,Ding M,et al.Boosting photocatalytic hydrogen production of porphyrinic MOFs:the metal location in metalloporphyrin matters[J].ACS Cata,2018,8(5):4583-4590.
[14] 陈乃华,王紫艳,杨玉香,等.UIO-67 MOFs构建硝酸根离子电化学传感器的研究[J].福建师范大学学报,2019,35(5):46-54.
[15] Chernikova,Valeriya,Yassine,et al.Highly sensitive and selective SO2 MOF sensor:the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode[J].J Mater Chem A,2018,6(12):5550-5554.
[16] 尹洪伟,郭丽芳,张文磊,等.镍基MOF电极材料物理超声改性及电化学性能[J].微纳电子技术,2020,5:372-378.
[17] Sumer Z,Keski S.Adsorption and membrane-based CH4/N2 separation performances of MOFs[J].Ind Eng Chem Res,2017,56(30):8713-8722.
[18] Fan W,Wang X,Xu B,et al.Amino-functionalized MOFs with high physicochemical stability for efficient gas storage/separation,dye adsorption and catalytic performance[J].J Mater Chem A,2018,6(47):24486-24495.
[19] Tarnowicz-Ligus S,Augustyniak A,Trzeciak A M.Incorporation of PdCl2P2 complexes in Ni-MOF for catalyzing heck arylation of functionalized olefins[J].Eur J Inorg Chem,2019,2019:39-40.
[20] Latha G,Devarajan N,Suresh P.Framework copper catalyzed oxidative synthesis of quinazolinones:a benign approach using Cu3(BTC)2 MOF as an efficient and reusable catalyst[J].Chemistry Select,2020,5(32):10041-10047.
[21] Chen D T,Bi J R,Wu J,et al.Zirconium based nano metal-organic framework UIO-67-NH2 with high drug loading for controlled release of camptothecin[J].J Inorg Organomet Polym Mater,2020,30(2):573-579.
[22] Cavka J H,Jakobsen S,Olsbye U,et al.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J].J Am Chem Soc,2008,130(42):13850-13851.
[23] 王茀学,王崇臣,王鹏,等.UIO系列金属-有机骨架的合成方法与应用[J].无机化学学报,2017,33(5):713-737.
[24] Chen Y Z,Zhang R,Jiao L,et al.Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit[J].Coord Chem Rev,2018,362(2018):1-23.
[25] 苏卫,唐梓桓,郑洋,等.MOFs及其衍生物在锂硫电池正极中的应用[J].辽宁石油化工大学学报,2020(4):59-69.
[26] Yang Q,Guillerm V,Ragon F,et al.CH4 storage and CO2 capture in highly porous zirconium oxide based metal-organic frameworks[J].ChemComm,2012,48(79):9831-9833.
[27] Chavan S,Vitillo J G,Gianolio D,et al.H2 storage in isostructural UIO-67 and UIO-66 MOFs[J].Phys Chem Chem Phys,2012,14(5):1614-1626.
[28] Goesten G M,Bekkum V,Kapteijn,et al.Sulfation of metal-organic frameworks:opportunities for acid catalysis and proton conductivity[J].Gascon Catal,2011,281:177-187.
[29] Mcguirk C M,Katz M J,Stern C L,et al.Turning on catalysis:incorporation of a hydrogen-bond-donating squaramide moiety into a Zr metal-organic framework[J].J Am Chem Soc,2015,137(2):919-925.
[30] Ko N,Hong J,Sung S,et al.A significant enhancement of water vapour uptake at low pressure by amine-functionalization of UIO-67[J].Dalton Trans,2015,44(5):2047-51.
[31] Decoste J B,Peterson G W,Jasuja H,et al.Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit[J].J Mater Chem,2013,1(18):5642-5650.
[32] Mondloch J E,Katz M J,Planas N,et al.Are Zr6- based MOFs water stable？Linker hydrolysis vs.capillary-force-driven channel collapse[J].ChemComm,2014,50(64):8944.
[33] Taddei M.When defects turn into virtues:the curious case of zirconium-based metal-organic frameworks[J].Coord Chem Rev,2017,343(1):1-24.
[34] Shearier E,Cheng P F,Bao J,et al.Surface defection reduces cytotoxicity of Zn(2-methylimidazole)2 (ZIF-8) without compromising its drug delivery capacity[J].RSC Adv,2016,6(5):4128-4135.
[35] Cai G R,Jiang H L.A modulator-induced defect-formation strategy to hierarchically porous metal-organic frameworks with high stability[J].Angew Chem Int Edit,2017,56(2):563-567.
[36] Zhang D W,Zhao J,Liu Q L,et al.Synthesis and luminescence properties of CsPbX3@UIO-67 composites toward stable photoluminescence convertors[J].Inorg Chem,2019,56(2):1690-1696.
[37] Sun S,Liao P,Zeng L,et al.UIO-67 metal-organic gel material deposited on photonic crystal matrix for photoelectrocatalytic hydrogen production[J].RSC Adv,2020,10(25):14778-14784.
[38] Zhang R Z,Huang Y Q,Wei Z,et al.Effect of particle size distribution of UIO-67 nano/microcrystals on the adsorption of organic dyes from aqueous solution[J].CrystEngComm,2018,20(38):1-20.
[39] Ruan B,Liu H L,Xie L,et al.The Fluorescence property of zirconium-based MOFs adsorbed sulforhodamine B[J].J Fluoresc,2020,30(3):427-435.
[40] Liu L J,Xia L,Wu C X,et al.Zirconium(Ⅳ)-based metal organic framework (UIO-67) as efficient sorbent in dispersive solid phase extraction of plant growth regulator from fruits coupled with HPLC fluorescence detection-ScienceDirect[J].Talanta,2016,154:23-30.
[41] Xu S Y,Kong H,Zhang R H.UIO-67-Ru-catalyzed oxidative cross-coupling for constructing β-acetylamino acrylosulfones[J].Tetrahedron Lett,2020,61(11):151629.
[42] Lu C X,Zhan G P,Chen K,et al.Anchoring Zn-phthalocyanines in the pore matrices of UIO-67 to improve highly the photocatalytic oxidation efficiency[J].Appl Catal B-Environ,2020,279(15):119350.
[43] Santiago-Portillo A,Baldovi H G,Carbonell E,et al.Ruthenium(Ⅱ) tris (2,2′-bipyridyl) complex incorporated in UIO-67 as photoredox catalyst[J].J Phys Chem C,2018,122(51).
[44] Maza W A,Ahrenholtz S R,Epley C C,et al.Solvothermal growth and photophysical characterization of a ruthenium(Ⅱ) tris(2,2′-bipyridine)-doped zirconium UIO-67 metal organic framework thin film[J].J Phys Chem A,2014,118(26):14200-14210.
[45] Maza W A,Haring A J,Ahrenholtz S R,et al.Ruthenium-polypyridyl zirconium metal-organic frameworks as a new class of sensitized solar cells[J].Chem Sci,2015,7(1):719-727.
[46] Zhu J,Maza W A,Morris A J.Light-harvesting and energy transfer in ruthenium(Ⅱ)-polypyridyl doped zirconium(Ⅳ) metal-organic frameworks:a look toward solar cell applications[J].J Photoch Photobio A,2017,344(1):64-77.
[47] Ma J,Yan B.Multi-component luminescence responsive Eu3+/Tb3+ hybrids based with metal-organic frameworks and zeolites A[J].Spectrochim Acta A,2019,220(5):117107.
[48] Chen R,Zhang J,Chelora J,et al.Ruthenium(Ⅱ) complex incorporated UIO-67 metal-organic frameworks nanoparticles for enhanced two-photon fluorescence imaging and photodynamic cancer therapy[J].ACS Appl Mater Interfaces,2017,9(7):5699-5708.
[49] Dong X,Zhao G,Liu L,et al.Ultrasensitive competitive method-based electrochemiluminescence immunosensor for diethylstilbestrol detection based on Ru(bpy)2+3,as luminophor encapsulated in metal-organic frameworks UIO-67[J].Biosens Bioelectron,2018,110(1):201-206.
[50] Li J,Yuan S,Qin J S,et al.Fluorescence enhancement in solid state by isolating perylene fluorophores in metal-organic frameworks[J].ACS Appl Mater Interfaces,2020.
[51] Luo J,Liu B S,Zhang X R,et al.A new fluorescent sensor constructed by Eu3+ post-functionalized metal-organic framework for sensing Ag+ with high selectivity and sensitivity in aqueous solution-ScienceDirect[J].J Mol Struc-theochem,2021,1227(5):129518.
[52] Cláudia G S,Corma A,Hermenegildo G.Metal-organic frameworks as semiconductors[J].J Mater Chem,2010,20(16):3141-3156.
[53] Wang J L,Wang C,Lin W.Metal-organic frameworks for light harvesting and photocatalysis[J].ACS Catal,2012,2(12):2630-2640.
[54] Zeng L,Guo X,He C,et al.Metal-organic frameworks:versatile materials for heterogeneous photocatalysis[J].ACS Catal,2016,6(11):7935-7947.
[55] Wang C,Xie Z,Dekrafft K E,et al.Doping metal organic frameworks for water oxidation,carbon dioxide reduction,and organic photocatalysis[J].Chem Soc,2011,133(34):13445-13454.
[56] Deenadayalan M S,Sharma N,Verma P K,et al.Visible-light-assisted photocatalytic reduction of nitroaromatics by recyclable Ni(Ⅱ)-porphyrin metal-organic framework (MOF) at RT[J].Inorg Chem,2016,55(11):5320-5327.
[57] Dhakshinamoorthy A,Asiri A M,Hermenegildo G.Metal-organic framework (MOF) compounds:photocatalysts for redox reactions and solar fuel production[J].Angew Chem Int Edit,2016,55(18):5414-5445.
[58] Alvaro M,Carbonell E,Ferrer B,et al.Semiconductor behavior of a metal-organic framework (MOF)[J].Chem,2007,13:5106.
[59] Tachikawa T,Choi J R,Fujitsuka M,et al.Photoinduced charge-transfer processes on MOF-5 nanoparticles:elucidating differences between metal-organic frameworks and semiconductor metal oxides[J].J Phys Chem A,2008,112(36):14090-14101.
[60] Benseghir Y,Lemarchand A,Duguet M,et al.Co-immobilization of a Rh catalyst and a keggin polyoxometalate in the UIO-67 Zr-based metal-organic framework:in depth structural characterization and photocatalytic properties for CO2 reduction[J].J Am Chem Soc,2020,142(20):9428-9438.
[61] Liu L,Zhang F,Zhang J,et al.Interfacial assembly and hydrolysis for synthesizing a TiO2/metal-organic framework composite[J].Soft Matter,2017,13(48):9174-9178.
[62] Liao W M,Zhang J H,Wang Z,et al.Post-synthetic exchange (PSE) of UIO-67 frameworks with Ru/Rh half-sandwich units for visible-light-driven H2 evolution and CO2 reduction[J].J Mater Chem A,2018,6(24):1-10.
[63] Gao X,Guo B,Guo C,et al.Zirconium-based metal-organic framework for efficient photocatalytic reduction of CO2 to CO:the influence of doped metal ions[J].ACS Appl Mater Interfaces,2020,12(21):24059-24065.
[64] Chen Y Z,Zhang R,Jiao L,et al.Metal-organic framework-derived porous materials for catalysis[J].Coord Chem Rev,2018,362:1-23.
[65] 安阳.系列金属有机骨架材料的设计、制备及光催化分解水性能的研究[D].济南:山东大学,2019.
[66] Cui Z,Fan T,Chen L,et al.Encapsulation of ultrafine Pd nanoparticles within the shallow layers of UIO-67 for highly efficient hydrogenation reactions[J].Sci China Chem,2021,64:109-115.
[67] Hou C C,Li T T,Cao S,et al.Incorporation of a [Ru(dcbpy)(bpy)2]2+ photosensitizer and a Pt(dcbpy)Cl2 catalyst into metal-organic frameworks for photocatalytic hydrogen evolution from aqueous solution[J].J Mater Chem A,2015,3(19):10386-10394.
[68] Bu Y,Li F,Zhang Y,et al.Immobilizing CdS nanoparticles and MoS2/RGO on Zr-based metal-organic framework 12-tungstosilicate@UIO-67 toward enhanced photocatalytic H2 evolution[J].RSC Adv,2016,6(46):40560-40566.
[69] Wang J,Zhang J,Peh S B,et al.Dimensional impact of metal-organic frameworks in catalyzing photo-induced hydrogen evolution and cyanosilylation reactions[J].ACS Appl Energy Mater,2018,2(1):298-304.
[70] Cao C S,Wang J,Yu X,et al.Photodegradation of seven bisphenol analogues by Bi5O7I/UIO-67 heterojunction:relationship between the chemical structures and removal efficiency[J].Appl Catal B-Environ,2020,277(15):119222.
[71] Amador R N,Michäel C,Meyer D.Sorption and photodegradation under visible light irradiation of an organic pollutant by a heterogeneous UIO-67-Ru-Ti MOF obtained by post-synthetic exchange[J].RSC Adv,2016,7(7):195.
[72] Dong X,Lin Y,Ma Y,et al.Ce-doped UIO-67 nanocrystals with improved adsorption property for removal of organic dyes[J].RSC Adv,2019,9(47):27674-27683.
基金资助
国家自然科学基金(21702087)
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