柔性导电纺织材料是指在纺织纤维材料中混入导电介质如金属纤维、碳纤维、石墨烯等制成的材料。这类材料具有质地轻、柔韧、可洗易折叠,及优良的化学稳定性等特性,在抗静电、柔性传感器、超级电容器、航天、医疗等领域有着广阔的应用前景,近年逐步成为研究热点。针对目前石墨烯基柔性导电纺织材料中导电纤维的制备方法、导电机理进行综述,并详细介绍石墨烯基复合物在柔性导电纺织材料中的应用研究进展。
Flexible conductive textile materials refer to materials made of textile fiber materials mixed with conductive media such as metal fibers,carbon fibers,graphene(rGO),etc.This kind of material is light,flexible,washable,easy to fold,and excellent chemical stability,etc.,so it has a wide application prospect in the fields of antistatic,flexible sensors,supercapacitors,aerospace,medical treatment and so on,which has gradually become a research hotspot in recent years.The preparation methods,conductive mechanism,and application of the materials were reviewed.The application of rGO-based composites in the materials was also introduced in detail.
[1] 丁长坤,程博闻,任元林,等.导电纤维的发展现状及应用前景[J].纺织科学研究,2006,17(3):25,32-39.
[2] 张清华,陈大俊.炭黑填充聚丙烯复合材料的制备及性能[J].高分子材料科学与工程,2004,20(3):213-215.
[3] 荣翔,钟智丽,张鹏,等.二维导电材料在柔性纺织传感器中的应用[J].天津纺织科技,2021(1):42-47.
[4] 胡雅琪,郭荣辉.导电纤维的研究进展[J].纺织科技进展,2017(9):1-5.
[5] 汤雅淇,桂宁遥,马岩.导电纤维的制备方法及应用[J].辽宁丝绸,2020(2):31,54-55.
[6] 王明序,许子傲,葛明桥,等.浅色导电纤维的发展及其最新应用[J].丝绸,2020,57(1):37-42.
[7] 翟娅茹,沈兰萍.导电纺织品的研究现状及发展[J].棉纺织技术,2019(2):81-84.
[8] 李瑶,陈婷婷,杨旭东.纺织用导电纤维及其应用[J].产业用纺织品,2010,28(4):32-35.
[9] 刘旭华,苗锦雷,曲丽君,等.用于可穿戴智能纺织品的复合导电纤维研究进展[J].复合材料学报,2021,38(1):1-16.
[10] 许荣鹏.导电纤维在复合型导电塑料中的应用[J].高科技纤维与应用,2007,32(1):28-31.
[11] Montazerian H,Rashidi A,Dalili A.et al.Graphene-coated spandex sensors embedded into silicone sheath for composites health monitoring and wearable applications[J].Small,2019,15(17),DOI:10.1002/smll.201804991.
[12] Karim N,Afroj S,Tan S,et al.Scalable production of graphene-based wearable E-textiles[J].ACS Nano,2017,11(12):12266-12275.
[13] 宋非,陈烨,柯福佑,等.石墨烯/碳纳米管涂层导电氨纶的制备及其性能研究[J].合成纤维工业,2020,43(1):1-6.
[14] Xiao C,Xiong X K,Sun J,et al.Preparation for graphene coated polyvinyl alcohol based conductive fiber containing silver nanowires[J].Key Engineering Materials,2019,807:171-175.
[15] Berendjchi A,Khajavi R,Yousefi A A,et al.Improved continuity of reduced graphene oxide on polyester fabric by use of polypyrrole to achieve a highly electro-conductive and flexible substrate[J].Applied Surface Science,2016,363:264-272.
[16] Lai X X,Guo R H,Xiao H Y,et al.Flexible conductive copper/reduced graphene oxide coated PBO fibers modified with poly(dopamine)[J].Journal of Alloys and Compounds,2019,788:1169-1176.
[17] Ni H,Li Y,Chen Z.Study on preparation and properties of luminescent polyamide fiber doped with graphene[J].Journal of Physics Conference Series,2020,1622(1):012038.
[18] Zhang X W,Ning S L,Ma Z K,et al.The structural properties of chemically derived graphene nanosheets/mesophase pitch-based composite carbon fibers with high conductivities[J].Carbon,2020,156:499-505.
[19] Kim S K,Kwon S N,Na S I.Stretchable and electrically conductive polyurethane-silver/graphene composite fibers prepared by wet-spinning process[J].Composites Part B,2019,167:573-581.
[20] 李新贵,曾剑峰,张炜,等.导电聚合物纳米纤维的成型[J].现代化工,2002,22(12):10-13,22.
[21] Ding W Y,Zhu H F,Lu L,et al.Three-dimensional layered Fe-NBC catalysts built by electrospinning and the comparison of different active species on oxygen reduction reaction performance[J].Journal of Alloys and Compounds,2020,848,DOI:10.1016/j.jallcom.2020.156605.
[22] 陈子阳,潘志娟.微流控纺丝及其在生物质纤维开发中的应用[J].现代丝绸科学与技术,2019,34(4):33-37.
[23] 李宇杰,霍曜,李迪,等.微流控技术及其应用与发展[J].河北科技大学学报,2014,35(1):11-19.
[24] Li Q,Cheng H,Wu X,et al.Enriched carbon dots/graphene microfibers towards high-performance micro-supercapacitors[J].Journal of Materials Chemistry A,2018,6(29):14112-14119.
[25] Zhang L,Tan Q L,Wang Y,et al.Wirelessly powered multi-functional wearable humidity sensor based on RGO-WS2 heterojunctions[J].Sensors and Actuators:B Chemical,2021,329:129077.
[26] Zhai W,Li X Y,Xia Q J,et al.Multi-functional and flexible helical fiber sensor for micro-deformation detection,temperature sensing and ammonia gas monitoring[J].Composites Part B:Engineering,2021,211:108621.
[27] 潘玮,黄素萍,龚静华.聚苯胺/涤纶导电纤维的制备及其织物抗静电性能研究[J].合成纤维,2002(1):30-32.
[28] 李亮,刘静芳,胡泽栋,等.涤纶织物的氧化石墨烯负载及其抗静电性能[J].纺织学报,2020,41(9):102-107.
[29] 陈阳,张占柱.石墨烯用于棉织物防静电整理的研究[J].棉纺织技术,2019,47(1):35-38.
[30] Xie X Y,Chen Z M,Xin B J.Ag/polyaniline/reduced graphene polyester conductive fabric with enhanced electromagnetic shielding performance[J].Journal of Physics:Conference Series,2021,1790(1):012072.
[31] 邹梨花,徐珍珍,孙妍妍,等.氧化石墨烯/聚苯胺功能膜对棉织物电磁屏蔽性能的影响[J].纺织学报,2019,40(8):109-116.
[32] Li X,Tang Y,Song J H,et al.Self-supporting activated carbon/carbon nanotube/reduced graphene oxide flexible electrode for high performance supercapacitor[J].Carbon,2018,129:236-244.
[33] Liao X,Dulle M,Sliva J,et al.High strength in combination with high toughness in robust and sustainable polymeric materials[J].Science,2019,366(6471):1376-1379.
[34] Qureshi Y,Tarfaoui M,Lafdi K K,et al.Real-time strain monitoring performance of flexible Nylon/Ag conductive fiber[J].Sensors and Actuators A:Physical,2019,295:612-622.
[35] Hufenus R,Gooneie A,Sebastian T,et al.Antistatic fibers for high-visibility workwear:challenges of melt-spinning industrial fibers[J].Materials,2020,13(11):2645.
[36] Wang W,Li W Y,Gao C C,et al.A novel preparation of silver-plated polyacrylonitrile fibers functionalized with antibacterial and electromagnetic shielding properties[J].Applied Surface Science,2015,342:120-126.
[37] 谢晓旭,王彦,诸静,等.基于夹心结构的碳纳米管/石墨烯复合柔性导电纤维的制备及其应用[J].现代化工,2020,40(10):188-191.
[38] Zhang M W,Hou Ch Y,Halder Arnab,et al.Graphene papers:smart architecture and specific functionalization for biomimetics,electrocatalytic sensing and energy storage[J].Materials Chemistry Frontiers,2017,1(1):37-60.
[39] 曾玮宸,刘茜.基于导电纤维的柔性传感器研究进展[J].传感器与微系统,2021,40(1):1-4,8.
基金资助
浙江省自然科学基金青年基金项目(LQ18E030006);浙江省纱线材料成形与复合加工技术研究重点实验室开放基金项目(MTC-2020-23);上海工程技术大学产学研项目[(19)FZ-015]