利用相变材料合理、高效、清洁利用绿色能源(自然环境中的热能)开发自调温沥青路面,综述分析了微胶囊相变材料(MCPCM)的国内外研究现状。MCPCM用于主动调温沥青路面可有效提高沥青路面的高低温性能,重点综述MCPCM在沥青混合料和沥青路面中的研究应用现状,并指出MCPCM在制备和应用方面存在的问题、解决方法和发展前景。
Phase change material(PCM) have the characteristics of reasonable,efficient and clean utilization of green energy (heat energy in natural environment).Based on this,researchers develop self regulating asphalt pavement.PCM and microencapsulated phase change materials (MCPCM) were introduced.The research status of MCPCM at home and abroad was summarized and analyzed.MCPCM is used to actively adjust the temperature of asphalt pavement,which can effectively improve the high and low temperature performance of asphalt pavement.The research and application status of MCPCM in asphalt mixture and asphalt pavement were focused on.The problems,solutions and development prospects of MCPCM in preparation and application were also pointed out.
[1] Nazir H,Batool M,Osorio F J B,et al.Recent developments in phase change materials for energy storage applications:a review[J].International Journal of Heat and Mass Transfer,2019,129,491-523.
[2] 何丽红,杨帆,王浩,等.相变材料在沥青混合料中的研究进展[J].化工新型材料,2017,45(5):220-222.
[3] Alva S G,Lin Y X,Liu L,et al.Synthesis,characterization and applications of microencapsulatedphase change materials in thermal energy storage:a review[J].Energy and Buildings,2017,144,276-294.
[4] Mohaddes F,Islam S,Shanks R,et al.Modification and evaluation of thermal properties of melamine-formaldehyde/n-eicosane microcapsules for thermo-regulation applications[J].Applied Thermal Engineering,2014,71(1):11-15.
[5] Zhang X,Tao X,Yick K,et al.Structure and thermal stability of microencapsulated phase-change materials[J].Colloid and Polymer Science,2004,282(4):330-336.
[6] Zhang H,Wang X.Synthesis and properties of microencapsulated n-octadecane with polyurea shells containing different soft segments for heat energy storage and thermal regulation[J].Solar Energy Materials & Solar Cells,2009,93(8):1366-1376.
[7] Zhang H,Wang X.Fabrication and performances of microencapsulated phase change materials based on n-octadecane core and resorcinol-modified melamine-formaldehyde shell[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2009,332(2-3):129-138.
[8] Ai Y,Jin Y,Sun J,et al.Microencapsulation of n-hexadecane as phase change material by suspension polymerization[J].e-Polymers,2007,7(1):98.
[9] Ma Y,Xie Q,Wang X,et al.Synthesis and characterization of microencapsulated phase change materials with comb-like acrylic co-polymer shell as thermal energy storage materials[J].Solar Energy,2019,179:410-423.
[10] Suzuki T,Mizowaki T,Okubo M.Versatile synthesis of high performance,crosslinked polymer microcapsules with encapsulated n-hexadecane as heat storage materials by utilizing microsuspension controlled/living radical polymerization (ms CLRP) of ethylene glycol dimethacrylate with the SaPSeP method[J].Polymer,2016,106:182-188.
[11] Al-Shannaq R,Kurdi J,Al-Muhtaseb S,et al.Supercooling elimination of phase change materials (PCMs) microcapsules[J].Energy,2015,87:654-662.
[12] Zou D,Liu X,He R,et al.High thermal response rate and super low supercooling degree microencapsulated phase change materials (MEPCM) developed by optimizing shell with various nanoparticles[J].International Journal of Heat and Mass Transfer,2019,140:956-964.
[13] Chaiyasat P,Noppalit S,Okubo M,et al.Do encapsulated heat storage materials really retain their original thermal properties?[J].Physical Chemistry Chemical Physics:PCCP,2015,17(2):1053-1059.
[14] 王宝辉,张学佳,纪巍,等.表面活性剂环境危害性分析[J].化工进展,2007,26(9):1263-1268.
[15] Wang H,Wang J P,Wang X,et al.Preparation and properties of microencapsulated phase change materials containing two-phase core materials[J].Industrial & Engineering Chemistry Research,2013,52(41):14706-14712.
[16] Chaiyasa P,Noppali S,Okubo M,et al.Innovative synthesis of high performance poly(methylmethacrylate) microcapsules with encapsulated heat storage material by microsuspension iodine transfer polymerization (ms ITP)[J].Solar Energy Materials & Solar Cells,2016,157:996-1003.
[17] Chaiyasat P,Ogino Y,Suzuki T,et al.Influence of Water domain formed in hexadecane core inside cross-linked capsule particle on thermal properties for heat storage application)[J].Colloid and Polymer Science,2008,286:753-759.
[18] Pholsrimuang P,Ngernchuklin P,Chaiyasat P.Preparation of high performance copolymer microcapsule encapsulated heat storage material without supercooling[J].Polymer-Plastics Technology and Materials,2019,58(17):1863-1874.
[19] 曹同玉,刘庆普,胡金生.聚合物乳液合成原理性能及应用[M].北京:化学工业出版社,2007.
[20] 冯哲,虎东霞,赵龙,等.相变材料在道路工程中的研究现状综述[J].材料导报,2015,29(25):144-147.
[21] 李文虎,何丽红,朱洪洲,等.PEG/SiO2相变颗粒对沥青混合料储热及高温性能的影响[J].公路交通科技,2015,32(4):16-20.
[22] 何丽红,李菁若,曹长斌,等。EG/SiO2定形相变材料在沥青及水泥环境中应用的可行性[J].新型建筑材料,2013,40(8):28-31.
[23] 谭忆秋,边鑫,单丽岩,等.路面用潜热材料的制备与调温性能研究[J].建筑材料学报,2013,16(2):354-359.
[24] Ryms M,Denda H,Jasku P.Thermal stabilization and permanent deformation resistance of LWA/PCM-modified asphalt road surfaces[J].Construction and Building Materials,2017,142:328-341.
[25] 叶少华.相变微胶囊的制备及其在沥青中的应用[D].哈尔滨:哈尔滨工业大学,2018.
[26] 王亚川.十四烷/三聚氰胺甲醛树脂相变微胶囊制备及改性沥青性能研究[D].西安:长安大学,2017.
[27] Kakar M R,Refaa Z,Worlitschek J,et al.Thermal and rheological characterization of bitumen modified with microencapsulated phase change materials[J].Construction and Building Materials,2019,215:171-179.
[28] Moises B,Kakar M R,Refaa Z,et al.Modification of asphalt mixtures for cold regions using microencapsulated phase change materials[J].Scientific Reports,2019,9:20342.
[29] Li F,ASCE A M,Zhou S,et al.Preparation of low-temperature phase change materials microcapsules and its application to asphalt pavement[J].Journal of Materials in Civil Engineering,2018,30(11):04018303.
基金资助
石家庄市重点研发计划项目(201160144A)