花状纳米粒子因形貌独特、比表面积大、粗糙度高等优点,能与聚合物形成良好的界面结合而制备综合性能优异的纳米复合材料。总结了近10年来国内外有关花状纳米粒子的合成方法及在聚合物中的应用,介绍了其对聚合物的催化性能、耐热性、阻燃特性以及分离吸附的影响,并分析了相关作用机理。
Flower-like nanoparticles have many advantages of unique morphologies,high specific areas and great roughness,which have gained much attention because they can form good interfaces with polymers to yield high-performance polymeric nanocomposites.The research progresses of synthesis methods in preparing the flower-like nanoparticles during the past decade and their application in polymeric nanocomposites was reviewed.The influence of flower-like nanoparticles on the catalytic capacity,thermal resistance,flame retardancy,as well as separation and adsorption abilities of polymeric nanocomposites were introduced in detail,and finally analyzed the mechanisms.
[1] 吴振玉,李奉杰,李村,等.不同形貌ZnO@PANI纳米复合材料的制备及光催化性质[J].无机化学学报,2013,29(10):2091-2098.
[2] Laurenti M,Grochowicz M,Dragoni E,et al.Biodegradable and drug-eluting inorganic composites based on mesoporous zinc oxide for urinary stent applications[J].Materials (Basel),2020,13(17):3821.
[3] Deng Y,Li J,Nian H,et al.Design and preparation of shape-stabilized composite phase change material with high thermal reliability via encapsulating polyethylene glycol into flower-like TiO2 nanostructure for thermal energy storage[J].Applied Thermal Engineering,2017,114:328-336.
[4] Vafaeifard M,Ibrahim S,Wong K T,et al.Novel self-assembled 3D flower-like magnesium hydroxide coated granular polyurethane:implication of its potential application for the removal of heavy metals[J].Journal of Cleaner Production,2019,216:495-503.
[5] Chen L,Liu W,Wang P,et al.Facile fabrication of robust and healable superhydrophobic cotton fabric with flower-like Ni(OH)2@ODA micro-nanoparticles[J].Cellulose,2020,28(1):581-592.
[6] Gholamian F,Salavati-Niasari M,Ghanbari D,et al.The effect of flower-like magnesium hydroxide nanostructure on the thermal stability of cellulose acetate and acrylonitrile-butadiene-styrene[J].Journal of Cluster Science,2012,24(1):73-84.
[7] Ghanbari D,Salavati-Niasari M,Sabet M.Preparation of flower-like magnesium hydroxide nanostructure and its influence on the thermal stability of polyvinyl acetate and polyvinyl alcohol[J].Composites Part B:Engineering,2013,45(1):550-555.
[8] Zhao W,Cheng Y,Li Z,et al.Improvement in fire-retardant properties of polypropylene filled with intumescent flame retardants,using flower-like nickel cobaltate as synergist[J].Journal of Materials Science,2020,56(3):2702-2716.
[9] Nie S,Jin D,Xu Y,et al.Effect of a flower-like nickel phyllosilicate-containing iron on the thermal stability and flame retardancy of epoxy resin[J].Journal of Materials Research and Technology,2020,9(5):10189-10197.
[10] Li Y,Zhu L.Preparation and characterization of novel poly (vinylidene fluoride) membranes using flower-like Bi2WO6 for membrane distillation[J].Journal of the Taiwan Institute of Chemical Engineers,2017,80:867-874.
[11] Zhu C,Wang B,Wang W,et al.A facile method for crystallizing flower-like CuS on the surface of PBO fiber[J].Materials Letters,2020,258:126652.
[12] Sun C,Song G,Chen L,et al.Three dimensional flower-like magnetic polyethyleneimine@MoS2 composites for highly efficient removal of Cr(Ⅵ) and Pb(Ⅱ) ions[J].Journal of Colloid and Interface Science,2020,580:550-560.
[13] Xu N,Hu L,Zhang Q,et al.Significantly enhanced dielectric performance of poly(vinylidene fluoride-co-hexafluoropylene)-based composites filled with hierarchical flower-like TiO2 particles[J].ACS Applied Materials & Interfaces,2015,7(49):27373-27381.
[14] Jian G,Meng Q,Jiao Y,et al.Enhanced performances of triboelectric nanogenerators by filling hierarchical flower-like TiO2 particles into polymethyl methacrylate film[J].Nanoscale,2020,12(26):14160-14170.
[15] Kapusuz D.Reinforcing epoxy with Ag-decorated flower-like TiO2 nanoparticles:structure and photocatalytic performance[J].Applied Physics A,2020,126(10):766.
[16] He M,Zhou Y,Huang T,et al.Flower-like CoS hierarchitectures@polyaniline organic-inorganic heterostructured composites:preparation and enhanced microwave absorption performance[J].Composites Science and Technology,2020,200:108403.
[17] Dong F,Xie H,Zheng Q,et al.Superhydrophobic polysilsesquioxane/polystyrene microspheres with controllable morphology:from raspberry-like to flower-like structure[J].RSC Advances,2017,7(11):6685-6690.
[18] Zendegi-Shiraz A,Sarafraz-Yazdi A,Es'haghi Z.Polyethylene glycol grafted flower-like cupric nano oxide for the hollow-fiber solid-phase microextraction of hexaconazole,penconazole,and diniconazole in vegetable samples[J].Journal of Separation Science,2016,39(16):3137-3144.
[19] Khan M Z,Baheti V,Militky J,et al.Self-cleaning properties of polyester fabrics coated with flower-like TiO2 particles and trimethoxy (octadecyl)silane[J].Journal of Industrial Textiles,2019,50(4):543-565.
[20] Manivannan K,Sivakumar M,Cheng C C,et al.An effective electrochemical detection of chlorogenic acid in real samples:flower-like ZnO surface covered on PEDOT∶PSS composites modified glassy carbon electrode[J].Sensors and Actuators B:Chemical,2019,301:127002.
[21] Zhang X,Si Y,Mo J,et al.Robust micro-nanoscale flowerlike ZnO/epoxy resin superhydrophobic coating with rapid healing ability[J].Chemical Engineering Journal,2017,313:1152-1159.
[22] Lorwanishpaisarn N,Kasemsiri P,Srikhao N,et al.Fabrication of durable superhydrophobic epoxy/cashew nut shell liquid based coating containing flower-like zinc oxide for continuous oil/water separation[J].Surface and Coatings Technology,2019,366:106-113.
[23] Seçkin T,Kıvılcım N,Köytepe S.Synthesis of triazine-based polyimide nanocomposites with flower-like ZnO by microwave-assisted solvothermal technique[J].Polymer-Plastics Technology and Engineering,2013,52(13):1368-1375.
[24] Zhang Y,Wang Q,Ye W C,et al.Pd micro-nanoparticles electrodeposited on graphene/polyimide membrane for electroca-talytic oxidation of formic acid[J].Transactions of Nonferrous Metals Society of China,2015,25(9):2986-2993.
[25] Kou H,Jia L,Wang C.Electrochemical deposition of flower-like ZnO nanoparticles on a silver-modified carbon nanotube/polyimide membrane to improve its photoelectric activity and photocatalytic performance[J].Carbon,2012,50(10):3522-3529.
[26] 郑伟杰,郑玉婴,陈健,等.纳米花状MnO2/PPS功能复合滤料的制备及其NH3-SCR脱硝性能研究[J].高分子学报,2017(11):1806-1815.
[27] Lee Y Y,Li H Y,Chiu S J,et al.Redox reaction mediated direct synthesis of hierarchical flower-like CuO spheres anchored on electrospun poly(vinylidene difluoride) fiber surfaces at low temperatures[J].RSC Advances,2015,5(121):100228-100234.
[28] Pereda C,Actis D G,Mendoza Zélis P,et al.Tillandsia aeranthos flower-like magnetic nanostructures confined into polyvinyl alcohol beads[J].Journal of Applied Polymer Science,2020,138(16):50261.
[29] Jaseela P K,Kuruvilla M,Williams L,et al.Excellent protection of mild steel in sodium chloride solution for a substantial period of time using a hybrid nanocoating of poly vinyl alcohol and titania[J].Arabian Journal of Chemistry,2020,13(8):6921-6930.
基金资助
国家自然科学基金(51775001)
PDF
