化工新型材料

化工新型材料 ›› 2022, Vol. 50 ›› Issue (8) : 19-24. DOI: 10.19817/j.cnki.issn1006-3536.2022.08.004

综述与专论

三维石墨烯制备方法及其导热复合材料应用进展

作者信息 +

Research progress on preparation of 3D rGO and its application in thermal conductivity composite

Liu Jiayuan, Tang Bo, Ji Li, Dai Yuanzhe, Liu Ke, Gao Ying

Author information +

文章历史 +

Received
2021-05-07
Issue Date	Revised Date
2022-08-29	2021-05-07

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摘要

石墨烯是一种以碳原子sp²杂化组成的二维新型材料,其特殊的六边形蜂窝状结构具有很多优异的物理特性,在热界面材料(TIMs)领域具有广阔的应用前景。三维石墨烯(3DGNs)具有固有的连续结构,相比二维石墨烯填料可以更高效地提高聚合物的导热系数。近年来,三维导热填料得到了广泛的关注,3DGNs复合导热材料也成为研究热点。介绍了3DGNs的主要制备方法,阐述了3DGNs与多种填料协同在导热复合材料中的应用,并对3DGNs复合导热材料的发展方向进行了展望。

Abstract

Graphene(rGO) is 2D material composed of carbon atom sp² hybridization.Its special hexagonal honeycomb structure has many excellent physical properties,and it has road application prospect in the field of thermal interface material (TIM).Three-dimensional graphene (3D rGO) has inherently continuous structure and can improve the thermal conductivity of the polymer more efficiently than 2D rGO fillers.In recent years,3D thermal conductivity filler has received extensive attention,and 3D rGO composite thermal conductivity material has also become hot research topic.The main preparation methods of 3D rGO were reviewed,and described the application of 3D rGO and various fillers in thermal conductivity composites.Finally,the development direction of 3D rGO composite thermal conductive materials was prospected.

关键词

三维石墨烯 / 热界面材料 / 制备方法 / 热性能

Key words

3D rGO / TIM / preparation method / thermal performance

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三维石墨烯制备方法及其导热复合材料应用进展[J]. 化工新型材料, 2022, 50(8): 19-24 DOI:10.19817/j.cnki.issn1006-3536.2022.08.004

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Lee C,Wei X,Kysar J W,et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,321(5887):385-388.
[2] Balandin A A,Ghosh S,Bao W,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[3] Stoller M D,Park S,Zhu Y,et al.Graphene-based ultracapacitors[J].Nano Letters,2008,8(10):3498-3502.
[4] Shahil K M F,Balandin A A.Graphene-multilayer graphene nanocomposites as highly efficient thermal interface materials[J].Nano Letters,2012,12(2):861-867.
[5] Song Y,Yu J,Yu L,et al.Enhancing the thermal,electrical,and mechanical properties of silicone rubber by addition of graphene nanoplatelets[J].Materials & Design,2015,88(25):950-957.
[6] Barbour A G,Carter C J,Burman N,et al.Tandem insertion sequence-like elements define the expression site for variable antigen genes of Borrelia hermsii[J].Infection & Immunity,1991,59(1):390-397.
[7] Xu Y,Sheng K,Li C,et al.Self-assembled graphene hydrogel via a one-step hydrothermal process[J].ACS Nano,2010,4(7):4324-4330.
[8] Sheng K X,Xu Y X,Li C,et al.High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide[J].New Carbon Materials,2011,26(1):9-15.
[9] Li J H,Zhao S F,Zhang G P,et al.A facile method to prepare highly compressible three-dimensional graphene-only sponge[J].Journal of Materials Chemistry A,2015,3(30):15482-15488.
[10] Hu H,Zhao Z B,Wan W B,et al.Ultralight and highly compressible graphene aerogels[J].Advanced Materials,2013,25(15):2219-2223.
[11] 赵梁成.三维石墨烯/聚氨酯复合材料的制备与特性[J].精细化工,2018,35(11):1848-1852,1858.
[12] Zhang L,Chen G,Hedhili M N,et al.Three-dimensional assemblies of graphene prepared by a novel chemical reduction-induced self-assembly method[J].Nanoscale,2012,4(22):7038-7045.
[13] Li Y,Chen J,Huang L,et al.Highly compressible macroporous graphene monoliths via an improved hydrothermal process[J].Advanced Materials,2014,26(28):4789-4793.
[14] Liu J,Liu Y,Zhang H B,et al.Superelastic and multifunctional graphene based aerogels by interfacial reinforcement with graphitized carbon at high temperatures[J].Carbon,2018,132:95-103.
[15] Xin G,Yao T,Sun H,et al.Highly thermally conductive and mechanically strong graphene fibers[J].Science,2015,349(6252):1083-1087.
[16] Chen Z,Ren W,Gao L,et al.Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nature Materials,2011,10(6):424-428.
[17] Ning G Q,Fan Z J,Wang G,et al.Gram-scale synthesis of nanomesh graphene with high surface area and its application in supercapacitor electrodes[J].Chemical Communications,2011,21(47):5976-5978.
[18] Pettes M T,Ji H,Ruoff R S,et al.Thermal transport in three-dimensional foam architectures of few-layer graphene and ultrathin graphite[J].Nano Letters,2012,12(6):2959-2964.
[19] Ji H,Sellan D P,Pettes M T,et al.Enhanced thermal conductivity of phase change materials with ultrathin-graphite foams for thermal energy storage[J].Energy & Environmental Science,2014,7(3):1185-1192.
[20] Zhang X F,Yeung K K,Gao Z L,et al.Exceptional thermal interface properties of a three-dimensional graphene foam[J].Carbon,2014,66(1):201-209.
[21] Yang J,Qi G Q,Bao R Y,et al.Hybridizing graphene aerogel into three-dimensional graphene foam for high-performance composite phase change materials[J].Energy Storage Materials,2018,13:88-95.
[22] Liu Z,Chen Y,Li Y,et al.Graphene foam-embedded epoxy composites with significant thermal conductivity enhancement[J].Nanoscale,2019,11(38):17600-17606.
[23] Zhang Q,Feng Z,Medarametla S P,et al.3D printing of graphene aerogels[J].Small,2016,12(40):2193-2204.
[24] Tang X,Zhou H,Cai Z,et al.Generalized 3D printing of graphene-based mixed-dimensional hybrid aerogels[J].ACS Nano,2018,12(4):3502-3511.
[25] Xiao H,Xie P,Qiu S J,et al.Ultrathin-graphite foam with high mechanical resilience and electroconductibility fabricated through morphology-controlled solid-state pyrolysis of polyaniline foam[J].Carbon,2018,139:648-655.
[26] Samad Y A,Li Y Q,Schiffer A,el al.Graphene foam developed with a novel two-step technique for low and high strains and pressure-sensing applications[J].Small,2015,11(20):2380-2385.
[27] Qin M,Xu Y,Cao R,et al.Thermal conductivity:efficiently controlling the 3D thermal conductivity of a polymer nanocomposite via a hyperelastic double-continuous network of graphene and sponge[J].Advanced Functional Materials,2018,28(45):1870234.
[28] Li T L,Hsu L C.Enhanced thermal conductivity of polyimide films via a hybrid of micro-and nano-sized boron nitride[J].The Journal of Physical Chemistry B,2010,114(20):6825-6829.
[29] Yang S Y,Lin W N,Huang Y L,et al.Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites[J].Carbon,2011,49(3):793-803.
[30] Tang L,He M,Na X,et al.Functionalized glass fibers cloth/spherical BN fillers/epoxy laminated composites with excellent thermal conductivities and electrical insulation properties[J].Composites Communications,2019,16:5-10.
[31] Li C,Zeng X L,Tan L Y,et al.Three-dimensional interconnected graphene microsphere as fillers for enhancing thermal conductivity of polymer[J].Chemical Engineering Journal,2019,368:79-87.
[32] 孙颖颖,陈林,杜小泽,等.三维石墨烯/环氧树脂复合材料导热特性研究[J].化工新型材料,2018,46(2):83-86.
[33] 安磊,刘琦,陈立飞,等.碳纳米管与三维石墨烯协同提高导热硅脂的热性能[J].上海第二工业大学学报,2020,37(1):35-41.
[34] Tang B,Wang Z W,Huang W Q,et al.RGO and three-dimensional graphene networks Co-modified TIMs with high performances[J].Nanoscale Research Letters,2017,12(1):527.
[35] Wu Z,Xu C,Ma C,et al.Synergistic effect of aligned graphene nanosheets in graphene foam for high-performance thermally conductive composites[J].Advanced Materials,2019,31(19):1900199.
[36] 安钧洳,王成君,刘芳,等.多孔材料在相变领域的研究进展[J].化工新型材料,2020,48(4):5-9,16.
[37] Li W Q,Qu Z G,He Y L,et al.Experimental study of a passive thermal management system for high-powered lithium ion batteries using porous metal foam saturated with phase change materials[J].Journal of Power Sources,2014,255(1):9-15.
[38] Hussain A,Tso C Y,Chao C.Experimental investigation of a passive thermal management system for high-powered lithium ion batteries using nickel foam-paraffin composite[J].Energy,2016,115:209-218.
[39] Xiao X,Zhang P,Li M.Preparation and thermal characterization of paraffin/metal foam composite phase change material[J].Applied Energy,2013,112:1357-1366.
[40] Liu Y J,Lu J Y,Cui Y B.Improved thermal conductivity of epoxy resin by graphene-nickel three-dimensional filler[J].Carbon Resources Conversion,2020,3:29-35.
[41] Hussain A,Abidi I H,Tso C Y,et al.Thermal management of lithium ion batteries using graphene coated nickel foam saturated with phase change materials[J].International Journal of Thermal Sciences,2017,124:23-35.
[42] 穆静静,赵悦菊,滕济林,等.导热绝缘高分子材料研究与制备[J].电子世界,2016(11):91.
[43] 李侃社,王琪.导热高分子材料研究进展[J].功能材料,2002,33(2):136-141.
[44] Osman A,Elhakeem A,Kaytbay S,et al.Thermal,electrical and mechanical properties of graphene/nano-alumina/epoxy composites[J].Materials Chemistry and Physics,2020,257:123809.
[45] Ren J,Li Q,Yan L,et al.Enhanced thermal conductivity of epoxy composites by introducing graphene@boron nitride nanosheets hybrid nanoparticles[J].Materials & Design,2020,191:108663.