随着雷达探测技术的发展以及电磁污染的日益严重,研制高效、轻质的电磁波吸收材料具有重要意义。碳纳米管具有吸收强、频带兼容性好、形态结构可控、质量轻、导电性可调等优点,是最具发展潜力的吸波材料之一。综述了碳纳米管/高分子有机物复合吸波材料、碳纳米管/磁性金属复合吸波材料、碳纳米管/铁氧体复合吸波材料以及碳纳米管/其他碳系吸波材料的制备方法和吸波性能,并对碳纳米管复合吸波材料未来的发展方向进行了展望。
With the development of radar detection technology and the increasingly serious electromagnetic pollution,it is of great significance to develop efficient and lightweight electromagnetic wave absorbing materials.Carbon nanotubes (CNTs) have the advantages of strong absorption,good frequency band compatibility,controllable morphology and structure,light weight and adjustable conductivity.They are one of the most potential microwave absorbing materials.The preparation methods and absorbing properties of CNTs/polymer organic composite absorbing materials,CNTs/magnetic metal composite absorbing materials,CNTs/ferrite composite absorbing materials and CNTs/other carbon based composite absorbing materials were reviewed.And the future development direction of CNTs composite absorbing materials was prospected.
[1] Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56-56.
[2] Sun X,Bao W,Lv Y,et al.Synthesis of high quality single-walled carbon nanotubes by arc discharge method in large scale[J].Materials Letters,2007,61(18):3956-3958.
[3] 袁艳红,柯磊,杨党强.两种不同制备方法的多壁碳纳米管光学性质的对比[J].光子学报,2013,42(6):645-648.
[4] 陈长鑫,陈文哲.脉冲激光轰击镍-石墨/乙醇固液界面原位生长碳纳米管[J].机械工程材料,2005,29(5):64-67.
[5] Takizawa M,Bandow S,Torii T,et al.Effect of environment temperature for synthesizing single-wall carbon nanotubes by arc vaporization method[J].Chemical Physics Letters,1999,302(1/2):146-150.
[6] Watts P C P,Hsu W K,Barnes A,et al.High permittivity from defective multiwalled carbon nanotubes in the X-band[J].Advanced Materials,2003,15(7/8):600-603.
[7] 金宇龙.新型碳纳米管吸波材料研究进展及展望[J].材料导报:纳米与新材料专辑,2015,29(S2):19-22.
[8] Peng Z,Peng J,Yu O.Microwave absorbing properties of hydrogen plasma in single wall carbon nanotubes[J].Physics Letters A,2006,359(1):56-60.
[9] 孙晓刚,程利,杜国平.阵列式碳纳米管雷达波吸收性能研究[J].人工晶体学报,2009,38(5):1114-1118.
[10] Zhang W,Xiong H,Wang S,et al.Electromagnetic characte-ristics of carbon nanotube film materials[J].Chinese Journal of Aeronautics,2015,28(4):1245-1254.
[11] Zhang Y,Zhou W,Chen H,et al.Facile preparation of CNTs microspheres as improved carbon absorbers for high-efficiency electromagnetic wave absorption[J].Ceramics International,2021,47(7):10013-10018.
[12] 李哲,王文龙,张梦,等.碳纳米管材料低频电磁参数及吸波产热特性[J].化工学报,2019,70(S1):28-34.
[13] 宁亮,王贤明,韩建军,等.碳材料在导电涂料和隐身涂料领域的研究进展[J].中国涂料,2016,31(6):40-45.
[14] 王奇,张昭环.碳纳米管的吸波性能研究[J].辽宁化工,2015,44(12):1432-1434.
[15] 刘平安.碳纳米管/聚苯胺复合物的制备及其吸波性能的研究[J].功能材料,2015,46(18):18088-18091.
[16] Wang H,Meng F,Huang F,et al.Interface modulating CNTs@PANi hybrids by controlled unzipping of the walls of CNTs to achieve tunable high-performance microwave absorption[J].ACS Applied Materials and Interfaces,2019,11(12):12142-12153.
[17] 赵新宇,谷雨晨,邱帅,等.PLA/CNTs复合材料的3D打印制备及其电磁屏蔽性能研究[J].塑料科技,2020,48(5):21-24.
[18] 权斌,黄啸谷,陆孝驰,等.一种碳纳米管基宽频电磁波吸收蜂巢超材料及其制备方法:中国,112209733A[P/OL].2021-01-12[2021-04-09].https://pss-system.cponline.cnipa.gov.cn/retrieveList？prevPageTit=chagngui.
[19] 张增富,罗国华,范壮军,等.不同结构碳纳米管的电磁波吸收性能研究[J].物理化学学报,2006,22(3):296-300.
[20] Wilson M,Madden P A.Growth of ionic crystals in carbon nanotubes[J].Journal of the American Chemical Society,2001,123(9):2101-2102.
[21] Sarkar D,Bhattacharya A,Nandy P,et al.Enhanced broadband microwave reflection loss of carbon nanotube ensheathed Ni-Zn-Co-ferrite magnetic nanoparticles[J].Materials Letters,2014,120(1):259-262.
[22] Lu M M,Cao W Q,Shi H L,et al.Multi-wall carbon nanotubes decorated with ZnO nanocrystals:mild solution-process synthesis and highly efficient microwave absorption properties at elevated temperature[J].Journal of Materials Chemistry A,2014,2(27):10540-10547.
[23] 赵廷凯,张红燕,朱若星,等.碳纳米管包覆空心羟基铁粉的制备及其磁性能[J].稀有金属材料与工程,2016,45(8):2165-2168.
[24] 葛超群,汪刘应,刘顾.碳纳米管/平面各向异性羰基铁复合材料的液相共混法制备及其电磁性能[J].复合材料学报,2018,35(7):1912-1920.
[25] Yin Y,Liu X,Wei X,et al.Magnetically aligned Co-C/MWCNTs composite derived from MWCNTs interconnected zeolitic imidazolate frameworks for lightweight and highly efficient electromagnetic wave absorber[J].ACS Applied Materials & Interfaces,2017,9(36):30850-30861.
[26] Shu R,Li W,Wu Y,et al.Nitrogen-doped Co-C/MWCNTs nanocomposites derived from bimetallic metal-organic frameworks for electromagnetic wave absorption in the X-band[J].Chemical Engineering Journal,2019,362:513-524.
[27] Bai Y,Wang J,Lu S,et al.Ni deposited onto MWCNTs buckypapers for improved broadband EMI shielding[J].Journal of Materials Science Materials in Electronics,2018,29(16):15034-15041.
[28] 燕佳欣,吴建华,时君友,等.雷达吸波涂层材料的研究进展[J].表面技术,2020,49(5):155-169.
[29] Hou C L,Li T H,Zhao T K,et al.Electromagnetic wave absorbing properties of multi-wall carbon nanotube/Fe3O4 hybrid materials[J].New Carbon Materials,2013,28(3):184-190.
[30] Lu Shaowei,Xu Weikai,Xiong Xuhai,et al.Preparation,magnetism and microwave absorption performance of ultra-thin Fe3O4/carbon nanotube sandwich buckypaper[J].Journal of Alloys and Compounds,2014,606:171-176.
[31] Wang M,Ji G,Zhang B,et al.Controlled synthesis and microwave absorption properties of Ni0.6Zn0.4Fe2O4/PANI composite via an in-situ polymerization process[J].Journal of Magnetism Magnetic Materials,2015,377:52-58.
[32] 朱昊,张燕,朱欣欣,等.软磁化BaM的高频电磁波吸收性能[J].精细化工,2017,34(11):1208-1212.
[33] Singh S K,Akhtar M J,Kar K K.Hierarchical carbon nanotube-coated carbon fiber:ultra lightweight,thin,and highly efficient microwave absorber[J].ACS Applied Materials & Interfaces,2018,10(29):24816-24828.
[34] 贾琨,李克训,张泽奎,等.石墨烯/碳纳米管复合材料的微波吸收性能研究[J].功能材料,2018,49(2):2136-2140.
[35] Kong L,Yin X,Xu H,et al.Powerful absorbing and lightweight electromagnetic shielding CNTs/RGO composite[J].Carbon,2019,145:61-66.
[36] 蔡泽,张丰发,布和巴特尔,等.三维结构铁氧体/碳复合材料制备及其电磁波吸收特性[J].化学工程师,2020,34(11):18-21.
基金资助
国家自然科学基金(21664009)
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