Polyaspartic acid (PASP) was introduced into polyacrylamide/polypyrrole (PAAm/PPy) conductive hydrogel by using acrylamide(AM) as monomer and N,N-methylene bisacrylamide(MBA) as crosslinking agent.The effects of content of PASP on the mechanicalproperties and electrical conductivity of the hydrogel were systematically investigated.The introduction of PASP not only improved the conductive properties of the hydrogel,but also effectively improved its mechanical properties.The hydrogel showed the best comprehensive performance when the content of PASP was 10%.The electrical conductivity was up to 1.19S/m,the elongation at break increased from 110% to 633%,and the tensile strength improved from 55kPa to 117.5kPa.The gauge factor(GF) was up to 1.88 at the strain to be 400%.The strain sensors based on the hydrogel demonstrated reliable monitor of repeated large strains and subtle vibrations,including the movements of finger joints and throat.
[1] 彭军,李津,李伟,等.柔性可拉伸应变传感器研究进展与应用[J].化工新型材料,2018,46(11):39-43.
[2] Li L,Lou Z,Chen D,et al.Recent advances in flexible/stretchable supercapacitors for wearable electronics[J].Small,2018,14(43):1702829.
[3] Yamada T,Hayamizu Y,Yamamoto Y,et al.A stretchable carbon nanotube strain sensor for human-motion detection[J].Nature Nanotechnology,2011,6(5):296-301.
[4] Shi G,Zhao Z H,Pai J H,et al.Highly sensitive,wearable,durable strain sensors and stretchable conductors using graphene/silicon rubber composites[J].Advanced Functional Materials,2016,26(42):7614-7625.
[5] Chortos A,Liu J,Bao Z.Pursuing prosthetic electronic skin[J].Nature Materials,2016,15(9):937-950.
[6] Chou H H,Nguyen A,Chortos A,et al.A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing[J].Nature Communications,2015,6(1):5997-6038.
[7] Trung T Q,Ramasundaram S,Hwang B U,et al.An all-elastomeric transparent and stretchable temperature sensor for body-attachable wearable electronics[J].Advanced Materials,2015,28(3):502-509.
[8] Yan C,Wang J,Kang W,et al.Highly stretchable piezoresistive graphene-nanocellulose nanopaper for strain sensors[J].Advanced Materials,2014,26(13):2022-2027.
[9] Dagdeviren C,Su Y,Joe P,et al.Conformable amplified lead zirconate titanate sensors with enhanced piezoelectric response for cutaneous pressure monitoring[J].Nature Communications,2014,5(1):4764-4767.
[10] Gong S,Schwalb W,Wang Y,et al.A wearable and highly sensitive pressure sensor with ultrathin gold nanowires[J].Nature Communications,2014,5(1):838-843.
[11] Wang C,Xia K,Wang H,et al.Advanced carbon materials for flexible and wearable sensors[J].Science China Materials,2017,60(11):1026-1062.
[12] Darabi M A,Khosrozadeh A,Wang Q,et al.Gum sensor:a stretchable,wearable,and foldable sensor based on carbon nanotube/chewing gum membrane[J].ACS Applied Materials & Interfaces,2015,7(47):26195-205.
[13] Wang C,Li X,Gao E,et al.Carbonized silk fabric for ultrastretchable,highly sensitive,and wearable strain sensors[J].Advanced Materials,2016,28(31):6640-6648.
[14] Xu Y,Sheng K,Li C,et al.Self-assembled graphene hydrogel via a one-step hydrothermal process[J].ACS Nano,2010,4(7):4324-30.
[15] Zhai D,Liu B,Shi Y,et al.Highly sensitive glucose sensor based on Ptnanoparticle/polyaniline hydrogel heterostructures[J].ACS Nano,2013,7(4):3540-3546.
[16] Chen H Y,Shen H P,Wu C H,et al.Core-shell composite latexes derived from PEDOT∶PSS dispersion and the preparation of conductive,flexible and transparent films[J].Journal of Materials Chemistry C,2013,1(34):5351.
[17] Shi Y,Pan L,Liu B,et al.Nanostructured conductive polypyrrole hydrogels as high-performance,flexible supercapacitor electrodes[J].Journal of Materials Chemistry A,2014,2(17):6086-6091.
[18] Kim J H,Chang M S,Jeon Y S,et al.Synthesis and characterization of poly(aspartic acid) derivatives conjugated with various amino acids[J].Journal of Polymer Research,2011,18(5):881-890.
[19] Nakato T,Tomida M,Suwa M,et al.Preparation and characterization of dodecylamine-modified poly(aspartic acid) as a biodegradable water-soluble polymeric material[J].Polymer Bulletin,2000,44(4):385-391.
[20] Nakato T,Yoshitake M,Matsubara K,et al.Relationships between Structure and Properties of Poly(aspartic acid)s[J].Macromolecules,1998,31(7):2107-2113.
[21] 李琼,胡灯,赵彦生,等.水体系中制备改性聚天冬氨酸/聚丙烯酸复合吸水性树脂[J].化工新型材料,2017,45(4):113-115.
[22] Yang S,Lu N.Gauge factor and stretchability of silicon-on-polymer strain gauges[J].Sensors,2013,13(7):8577-8594.
基金资助
山西省重点研发项目(201803D121034);山西省应用基础研发项目(201801D221073)