苄基缩水甘油醚含量对环氧树脂耐热及阻尼性能的影响

张化哲1, 张均2, 张玉钢3, 谢贵堂1, 姜志国1,2, 赵静1*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 156 -159.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 156-159. DOI: 10.19817/j.cnki.issn1006-3536.2022.07.033
科学研究

苄基缩水甘油醚含量对环氧树脂耐热及阻尼性能的影响

    张化哲1, 张均2, 张玉钢3, 谢贵堂1, 姜志国1,2, 赵静1*
作者信息 +

Influence of the amount of benzyl glycidyl ether on the heat resistance and damping property of EP

  • Zhang Huazhe1, Zhang Jun2, Zhang Yugang3, Xie Guitang1, Jiang Zhiguo1,2, Zhao Jing1
Author information +
文章历史 +
PDF

摘要

以苄基缩水甘油醚为改性剂改性环氧树脂/甲基四氢苯酐固化体系,研究了改性剂含量对环氧树脂黏度及固化物力学性能、阻尼性能和热性能的影响。结果表明:改性剂的加入能够降低环氧树脂黏度,减小固化物交联密度,改善固化物韧性;固化物阻尼性能随改性剂含量的添加先增大后减小,改性剂用量为10%时,阻尼因子最大,为0.6355;固化物耐热性能和拉伸强度随改性剂含量的增加整体呈减小趋势,改性剂含量为5%~10%时,综合性能较好,此时起始分解温度(T5%)为361.8~358.2℃。

Abstract

The curing system of epoxy resin/methyl tetra hydrophenylanhydride (EP/MethPA) was modified by benzyl glycidyl ether.The effects of the amount of modifier on the viscosity of the resin system and the mechanical,damping and thermal properties of the cured product were investigated.The results shown that the addition of modifier can reduce the viscosity of the EP,and reduced the crosslinking density and improved the toughness of the cured EP.With increasing the amount of modifier,the damping property of cured EP improved firstly and decreased later.When the amount of modifier was 10%,the tanδ reached the highest that was 0.06355.The heat resistance and tensile strength decreased basically with increasing the amount of modifier.When the amount of modifier was 5%~10%,the cured EP showed well comprehensive performance.The starting decomposing temperature (T5%) was 361.8~358.2℃.

关键词

改性剂 / 环氧树脂 / 阻尼性能 / 耐热性能

Key words

modifier / epoxy resin / damping performance / heat resistant performance

引用本文

引用格式 ▾
苄基缩水甘油醚含量对环氧树脂耐热及阻尼性能的影响[J]. 化工新型材料, 2022, 50(7): 156-159 DOI:10.19817/j.cnki.issn1006-3536.2022.07.033

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Kawahara T,Yuuki A,Hashimoto K,et al.Immobilization of flame-retardant onto silica nanoparticle surface and properties of epoxy resin filled with the flame-retardant-immobilized silica[J].Reactive & Functional Polymers,2013,73(3):613-618.
[2] Jeon H R,Park J H,Shon M Y.Corrosion protection by epoxy coating containing multi-walled carbon nanotubes[J].Journal of Industrial & Engineering Chemistry,2013,19(3):849-853.
[3] Kumar K,Biju R,Nair C.Progress in shape memory epoxy resin[J].Reactive and Functional Polymers,2013,73(2):421-430.
[4] 李桂林.环氧树脂与环氧涂料[M].北京:化学工业出版社,2003.
[5] Auvergne R,Caillol S,David G,et al.Biobased thermosetting epoxy:present and future[J].Chemical Reviews,2014,114(2):1082-1115.
[6] Park S J,Jin F L,Lee J R.Thermal and mechanical properties of tetrafunctional epoxy resin toughened with epoxidized soybean oil[J].Materials Science & Engineering A,2004,374(1/2):109-114.
[7] Li Yuzhan,Badrinarayanan P,Kessler M R.Liquid crystalline epoxy resin based on biphenyl mesogen:thermal characterization[J].Polymer,2013,54(12):3017-3025.
[8] 孙宝华,陈姝囡,周晏云.稀释剂对TDE-85环氧树脂体系性能影响研究[J].纤维复合材料,2007,24(3):6-8.
[9] 李广琦,王联合,王美林,等.稀释剂用量对环氧固化物玻璃化温度的影响[J].热固性树脂,2010(5):32-33.
[10] Jin F L,Park S J.A review of the preparation and properties of carbon nanotubes-reinforced polymer composites[J].Carbon Letters,2011,12(2):273-278.
[11] 李山剑,邓双辉,冯云龙,等.活性稀释剂对环氧树脂结构和性能的影响[J].河北大学学报(自然科学版),2016,36(6):604-613.
[12] 石敏先,黄志雄,郦亚铭,等.活性稀释剂对环氧树脂阻尼性能的影响[J].粘接,2007(4):7-9.
[13] 林丽,张红,李远,等.热固性聚合物的交联密度测试方法研究进展[J].热固性树脂,2012,27(5):60-63.
AI Summary AI Mindmap
PDF

663

访问

0

被引

导航
相关文章

AI思维导图

/