石蜡/聚丙烯定型相变储能材料的泄漏率和定型能力的研究

陈雪芳1, 门明燃1, 李强1, 王自强1, 潘鑫2, 马剑英1, 曹春雷1*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 137 -141.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 137-141. DOI: 10.19817/j.cnki.issn1006-3536.2022.07.029
科学研究

石蜡/聚丙烯定型相变储能材料的泄漏率和定型能力的研究

    陈雪芳1, 门明燃1, 李强1, 王自强1, 潘鑫2, 马剑英1, 曹春雷1*
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Study on leakage rate and shaping ability of paraffin/PP FSPCMs for energy storage

  • Chen Xuefang1, Men Mingran1, Li Qiang1, Wang Ziqiang1, Pan Xin2, Ma Jianying1, Cao Chunlei1
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摘要

采用3种不同类型增容剂乙烯-α-辛烯高共聚物(POE)、三元乙丙橡胶(EPDM)和苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚物(SEBS)改善石蜡/聚丙烯(PP)定型相变材料(FSPCMs)的性能,讨论3种增容剂的用量对储能相变材料泄漏率和定型能力的影响,并通过扫描电镜(SEM)对相变材料的微观结构进行表征。结果表明:当FSPCMs中石蜡含量高达70%(wt,质量分数,下同),增容剂含量为20%时,48h后定型相变材料的泄漏率最低,POE、EPDM和SEBS这3种类型的FSPCMs泄漏率分别3.77%、4.46%和1.41%,比相同石蜡含量的纯PP/石蜡定型相变材料的泄漏率分别降低了3.68倍、3.1倍和9.84倍。定型相变材料的定型能力随着增容剂含量的增加而降低,定型能力最好的是POE-FSPCMs。SEM结果表明3种增容剂中与PP相容性最好的是POE,与石蜡相容性最好的是SEBS。

Abstract

The properties of form-stable phase change materials (FSPCMs) were improved by compatibilizers:POE,EPDM and SEBS.The effects of compatibilizers on leakage rate and shaping ability of FSPCMs were discussed.The microstructure of FSPCMs were characterized by scanning electron microscope (SEM).The leakage rate test results showed that the FSPCMs leakage rate with 70% (wt%,weight fraction,the same below) paraffin content and 20% compatibilizer content were lowest after 48 hours.FSPCMs lowest leakage rates of POE,EPDM and SEBS were 3.77%,4.46% and 1.41%,respectively,which were 3.68,3.1 and 9.84 times lower than that of PP/paraffin with the same paraffin content.The shaping ability of FSPCMs decreased with increasing of compatibilizer content,and POE-FSPCMs had the best shaping ability.SEM results showed that POE had the best compatibility with PP and SEBS had the best compatibility with paraffin among three compatibilizers.

关键词

定型相变材料 / 增容剂 / 泄漏率 / 定型能力 / 微观结构

Key words

form-stable phase change material / compatibilizer / leakage rate / shaping ability / microstructure

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石蜡/聚丙烯定型相变储能材料的泄漏率和定型能力的研究[J]. 化工新型材料, 2022, 50(7): 137-141 DOI:10.19817/j.cnki.issn1006-3536.2022.07.029

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参考文献

[1] Yang Y,Wu W,Fu S,et al.Study of a novel ceramsite-based shape-stabilized composite phase change material (PCM) for energy conservation in buildings[J].Construction and Building Materials,2020,246:118479.
[2] Zalba B,Marin J M,Cabeza L F,et al.Review on thermal energy storage with phase change:materials,heat transfer analysis and applications[J].Applied Thermal Engineering,2003,23(3):251-283.
[3] 邓军,何骞,刘长春,等.相变冷却服发展趋势[J].科技导报,2017,35(21):107-114.
[4] As A,Vvt B,Crc A,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable and Sustainable Energy Reviews,2009,13(2):318-345.
[5] Asinger F.Paraffins:chemistry and technology[M].Paraffins:Chemistry and Technology,1968.
[6] Khadiran T,Hussein M Z,Zainal Z,et al.Encapsulation techniques for organic phase change materials as thermal energy storage medium:a review[J].Solar Energy Materials and Solar Cells,2015.
[7] Bidgoli M A,Hayaty M.Fabrication and characterization of nanoencapsulated epoxy resin/crosslinked PMMA shells with in situ polymerization via phase inversion emulsion (PIE) method[J].Journal of Applied Polymer Science,2019,137(23):48793.
[8] Li B,Liu T,Hu L,et al.Fabrication and properties of microencapsulated paraffin@SiO2 phase change composite for thermal energy storage[J].ACS Sustainable Chemistry & Engineering,2013,1(3):374-380.
[9] Zhang X X,Fan Y F,Tao X M,et al.Crystallization and prevention of supercooling of microencapsulated n-alkanes[J].Journal of Colloid and Interface Science,2005,281(2):299-306.
[10] Inaba H,Tu P.Evaluation of thermophysical characteristics on shape-stabilized paraffin as a solid-liquid phase change material[J].Heat & Mass Transfer,1997,32(4):307-312.
[11] Chen F,Wolcott M.Polyethylene/paraffin binary composites for phase change material energy storage in building:a morphology,thermal properties,and paraffin leakage study[J].Solar Energy Materials and Solar Cells,2015,137:79-85.
[12] Chen F,Wolcott M P.Miscibility studies of paraffin/polyethylene blends as form-stable phase change materials[J].European Polymer Journal,2014,52:44-52.
[13] Krupa I,Miková G,Luyt A S.Polypropylene as a potential matrix for the creation of shape stabilized phase change materials[J].European Polymer Journal,2007,43(3):895-907.
[14] Li Liping,Wang Gang,Guo Chuigen.Influence of intumescent flame retardant on thermal and flame retardancy of eutectic mixed paraffin/polypropylene form-stable phase change materials[J].Applied Energy,2016,162:428-434.
[15] 程金旭,张凯,杨文彬,等.三元乙丙橡胶/石蜡弹性定形相变材料的制备及性能表征[J].高分子材料科学与工程,2017,33(10):160-163,169.
[16] Zhang Q,Zhao Y,Feng J.Systematic investigation on shape stability of high-efficiency SEBS/paraffin form-stable phase change materials[J].Solar Energy Materials & Solar Cells,2013,118:54-60.
[17] Luo C Y,Zuo J D.Property of POE,EVA and EPDM encapsulating paraffin as form stable phase change materials[J].Material Research Innovations,2013,17(S1):58-61.
[18] 周琦,王勇,邱桂学.PP/POE及PP/EPDM共混改性研究[J].塑料科技,2007(7):46-49.
[19] 李树白,姚培,刘媛.PP/POE共混物形态结构与逾渗分析[J].塑料科技,2017(11):10-15.
[20] 王立娟,王华,王焱鹏.POE改性共聚聚丙烯的性能[J].合成树脂及塑料,2020,37(3):15-18.
[21] 杨娇娥,丁雪佳,朱姝玥.POE和SEBS对PP韧性以及光学性能的影响[J].塑料,2018,47(4):25-29.
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