用于FDM的PBAT/纳米CaCO3复合材料的制备及性能探究

阴梦啸, 汪艳*, 李春晖, 郑银松, 陶永祥

化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 110 -113.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 110-113. DOI: 10.19817/j.cnki.issn1006-3536.2022.07.023
新材料与新技术

用于FDM的PBAT/纳米CaCO3复合材料的制备及性能探究

    阴梦啸, 汪艳*, 李春晖, 郑银松, 陶永祥
作者信息 +

Study on preparation and performance of PBAT/nano-CaCO3 composite material for FDM

  • Yin Mengxiao, Wang Yan, Li Chunhui, Zheng Yinsong, Tao Yongxiang
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摘要

采用熔融共混法将聚己二酸/对苯二甲酸丁二酯(PBAT)与纳米碳酸钙(纳米CaCO3)复合,研究了纳米CaCO3含量对复合材料力学性能、热性能和熔体流动性的影响。结果表明:添加纳米CaCO3能够改善复合材料的拉伸性能并提高其维卡软化温度,拉伸强度在纳米CaCO3添加量为10%时最佳,比纯PBAT的拉伸强度提高了19.14%。将添加10%纳米CaCO3的复合材料拉丝,然后以不同打印温度和打印速度进行熔融沉积(FDM)打印。当打印温度为220℃,打印速度为20mm/s时,打印试样的综合拉伸性能最佳。

Abstract

Poly (butylene adipate-co-terephthalate) (PBAT) was compounded with nanometer calcium carbonate (nano-CaCO3) by melt blending.The effects of nano-CaCO3 content on the mechanical properties,thermal properties and melt fluidity of the composites were studied.The results shown that the addition of nano-CaCO3 can improve the tensile properties and Vicat softening temperature of the composites.The tensile strength was the best when the nano-CaCO3 content was 10%,which was 19.14% higher than that of pure PBAT.The composite with 10% nano-CaCO3 was drawn and then printed by FDM at different printing temperature and printing speed.When the printing temperature was 220℃ and the printing speed was 20mm/s,the comprehensive tensile properties of the printed samples were the best.

关键词

熔融共混 / 聚己二酸/对苯二甲酸丁二酯 / 纳米碳酸钙 / 熔融沉积

Key words

melt blending / poly (butylene adipate-co-terephthalate) / nanometer calcium carbonate / fused deposition molding

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用于FDM的PBAT/纳米CaCO3复合材料的制备及性能探究[J]. 化工新型材料, 2022, 50(7): 110-113 DOI:10.19817/j.cnki.issn1006-3536.2022.07.023

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基金资助

广东省企业重点实验室项目“3D打印聚合物及复合材料”(2018B030323001);武汉工程大学第十二届研究生教育创新基金(CX2020154)

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