微纳米碳球具有比表面积大、流动性好、机械强度高等优点。为了扩展它的功能和应用领域,微纳米碳球被大量改性研究。微纳米碳球的改性方法包括元素掺杂和构建特殊形貌。元素引入方面包括非金属元素掺杂、金属元素掺杂、特殊官能团掺杂。碳球形貌有中空多孔结构和中空多层结构。其次,概述了微纳米碳球在各领域的最新应用,包括超级电容器、吸附物质、储存氢气、催化剂载体。最后指出了微纳米碳球改性时所面临的挑战和应用方向。
Micro-nano carbon spheres have the advantages of large specific surface area,good fluidity and high mechanical strength.In order to expand its functions and application fields,the carbon spheres have been extensively modified.The modification methods of the carbon spheres include element doping and construction of special morphology.Element introduction includes nonmetal element doping,metal element doping and special functional group doping.The methods to change the morphology of the carbon spheres include hollow porous structure and hollow multilayer structure.Secondly,the latest applications of the carbon spheres in various fields were summarized,Including supercapacitors,adsorbents,hydrogen storage and catalyst carriers.Finally,the challenges and application directions of the carbon spheres modification were pointed out.
[1] Cao G,Hao C,Gao X,et al.Carbon nanotubes with carbon blacks as cofillers to improve conductivity a stability[J].ACS Omega,2019,4(2):4169-4175.
[2] Oh T,Kim M,Park D,et al.Synergistic interaction and controllable active sites of nitrogen and sulfur co-doping into mesoporous carbon sphere for high performance oxygen reduction electrocatalysts[J].Applied Surface Science,2018,440:627-636.
[3] 刘涛.空心碳球基电极材料的制备与超级电容器性能的研究[D].武汉:武汉理工大学,2019.
[4] 王道军,王涛,周建华,等.有序介孔碳的微波快速合成和表面修饰及其负载性能[J].无机化学学报,2010,26(2):305-312.
[5] 何天稀,王文斌,王九,等.介孔碳球的制备及作为药物传输系统的应用[J].化学进展,2020,32(Z1):309-319.
[6] Du J,Liu L,Zhang Y,et al.Rich porous dual-shell carbon spheres by dissolution-reassembly with high performance in supercapacitor[J].Journal of Energy Storage,2020,29:101375.
[7] Chen A,Wang Y,Yu Y,et al.Nitrogen-doped hollow carbon spheres for supercapacitors[J].Journal of Materials Science,2016,52(6):3153-3161.
[8] 苏一博,汪长安.KMnO4与碳球反应制备不同形貌的δ-MnO2[J].稀有金属材料与工程,2018,47(S1):205-208.
[9] Li Y,Wang J,Fan S,et al.Nitrogen-doped hierarchically porous carbon spheres for low concentration CO2 capture[J].Journal of Energy Chemistry,2021,53:168-174.
[10] Bang J H.Hollow graphitic carbon spheres for Pt electrocatalyst support in direct methanol fuel cell[J].Electrochimica Acta,2011,56(24):8674-8679.
[11] Zhang C,Li J,Liu E,et al.Synthesis of hollow carbon nano-onions and their use for electrochemical hydrogen storage[J].Carbon,2012,50(10):3513-3521.
[12] Zhao J,Wang F,Zhang X,et al.Vibration damping of carbon nanotube assembly materials[J].Advanced Engineering Materials,2018,20(3):1700647.
[13] Jiang J,Fan Q,Zheng Z,et al.Nanostructured CoS2-decorated hollow carbon spheres:a performance booster for Li-ion/sulfur batteries[J].ACS Applied Energy Materials,2020,32(8):6447-6459.
[14] Xiao Y,Liu Y,Liu F,et al.Wearable pseudocapacitor based on porous MnO2 composite[J].Journal of Alloys and Compounds,2020,813(21):89-99.
[15] 强宏文.氮掺杂介孔中空碳纳米球及其复合物的制备与电化学性能的探究[D].合肥:合肥工业大学,2019.
[16] Ji S,Ma Y,Wang H,et al.Cage-like MnO2-Mn2O3 hollow spheres with high specific capacitance and high rate capability as supercapacitor material[J].Electrochimica Acta,2016,219(17):540-546.
[17] Bahdanchyk M,Hashempour M,Vicenzo A.Evaluation of the operating potential window of electrochemical capacitors[J].Electrochimica Acta,2020,332:135503.
[18] 陈景景.杂原子掺杂煤基多孔碳球的制备及其电容性能研究[D].乌鲁木齐:新疆大学,2019.
[19] 高洪成,王振旅,牛桂玲,等.碳纳米管/杂多酸/聚吡咯复合催化剂的制备及催化烯烃环氧化性能[J].高等学校化学学报,2017,38(7):1223-1228.
[20] 马红燕,王靖原,张越诚,等.以花生碳量子点为探针基于其荧光猝灭-恢复测定多巴胺的研究[J].光谱学与光谱分析,2020,40(4):1093-1098.
[21] 张业琼,丛野,张静,等.炭化对沥青基活性炭纤维的结构和超级电容器性能影响[J].无机化学学报,2018,34(8):1430-1436.
[22] Wang J G,Liu H,Sun H,et al.One-pot synthesis of nitrogen-doped ordered mesoporous carbon spheres for high-rate and long-cycle life supercapacitors[J].Carbon,2018,127:85-92.
[23] Wang F,Wang Y,Fang Y,et al.Synthesis of nitrogen-doped flower-like carbon microspheres from ureaformaldehyde resins for high-performance supercapacitor[J].Journal of Alloys and Compounds,2020,812:109-119.
[24] Hu F,Yang H,Wang C,et al.Co-N-doped mesoporous carbon hollow spheres as highly efficient electrocatalysts for oxygen reduction reaction[J].Small,2017,13(3):1602507.
[25] 江超,李君,陶令令,黄金萍.MnO2/碳纳米球电化学超级电容器电极材料的制备与性能研究[J].上海师范大学学报(自然科学版),2016,45(6):663-669.
[26] Shi X,Zhang S,Chen X,et al.Effect of iron oxide impregnated in hollow carbon sphere as symmetric supercapacitors[J].Journal of Alloys and Compounds,2017,726:466-473.
[27] 吴波,郑帼,刘旭钊,孙玉,等.高亲水性环氧树脂的制备及对碳纤维的表面处理[J].高等学校化学学报,2016,37(10):1891-1899.
[28] 孙振龙.溶剂诱导相分离法制备大粒径球形碳及其应用[D].上海:华东理工大学,2016.
[29] Guo J,Zheng P.Improving the capacitance of derived porous carbon by oxygen functional groups for supercapacitor[J].Materials Letters,2018,214:134-137.
[30] Zuliani J E,Tong S,Jia C Q,et al.Contribution of surface oxygen groups to the measured capacitance of porous carbon supercapacitors[J].Journal of Power Sources,2018,395:271-279.
[31] Qiu W,Zhao J,Song X,et al.One-step activation synthesized hierarchical porous carbon spheres from resorcinol-thiourea-formaldehyde for electrochemical capacitors[J].Industrial & Engineering Chemistry Research,2019,59(1):226-235.
[32] Sun Y,Xue J,Dong S,et al.Biomass-derived porous carbon electrodes for high-performance supercapacitors[J].Journal of Materials Science,2020,55(12):5166-5176.
[33] Du J,Liu L,Zhang Y,et al.Rich porous dual-shell carbon spheres by dissolution-reassembly with high performance in supercapacitor[J].Journal of Energy Storage,2020,29(3):375-383.
[34] He Y,Xiang K,Wang Y,et al.Scalable and controllable synthesis of multi-shell hollow carbon microspheres for high-performance supercapacitors[J].Carbon,2019,154:330-341.
[35] 张保海,罗民,杨顺,等.用金属生物大分子配合物前驱体制备多孔碳球及其电化学性能[J].高等学校化学学报,2018,39(2):310-318.
[36] Abbas S A,Forghani M,Anh S,et al.Carbon hollow spheres as electrochemical capacitors:mechanistic insights[J].Energy Storage Materials,2020,24:550-556.
[37] Li H,Miao Q,Chen Y,et al.Modified carbon spheres as universal materials for adsorption of cationic harmful substances (paraquat and dyes) in water[J].Microporous and Mesoporous Materials,2020,297:40-48.
[38] Tabatabaei Shirazani M,Bakhshi H,Rashidi A,et al.Starch-based activated carbon micro-spheres for adsorption of methane with superior performance in ANG technology[J].Journal of Environmental Chemical Engineering,2020,8(4):45-53.
[39] Wickramaratne N P,Jaroniec M.Activated carbon spheres for CO2 adsorption[J].ACS Applied Materials & Interfaces,2013,5(5):1849-1855.
[40] Jiang J,Gao Q,Zheng Z,et al.Enhanced room temperature hydrogen storage capacity of hollow nitrogen-containing carbon spheres[J].International Journal of Hydrogen Energy,2010,35(1):210-216.
[41] Wang Y,Ding Z,Li X,et al.Improved hydrogen storage properties of MgH2 by nickel@nitrogen-doped carbon spheres[J].Dalton Trans,2020,49(11):3495-3502.
[42] Tan L,Yang Y D,Li N,et al.Enhanced activity and stability of Co3O4-decorated nitrogen-doped carbon hollow sphere catalysts for microbial fuel cells[J].Catalysis Science & Technology,2017,7(6):1315-1323.
[43] Zhu Y,Gao C,Han Q,et al.Large-scale high-efficiency dye-sensitized solar cells based on a Pt/carbon spheres composite catalyst as a flexible counter electrode[J].Journal of Catalysis,2017,346:62-69.
[44] Sahiner N.Carbon spheres from lactose as green catalyst for fast hydrogen production via methanolysis[J].International Journal of Hydrogen Energy,2018,43(20):9687-9695.
基金资助
国家自然科学基金(31870564)