二氧化锡基锂电池负极纳米材料的制备及其研究进展

曾攀静, 丁梦钊, 平云霞, 张朝民*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 58 -61.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 58-61. DOI: 10.19817/j.cnki.issn1006-3536.2022.07.012
综述与专论

二氧化锡基锂电池负极纳米材料的制备及其研究进展

    曾攀静, 丁梦钊, 平云霞, 张朝民*
作者信息 +

Preparation and research progress of SnO2 based nanomaterial for anode in Li-ion battery

  • Zeng Panjing, Ding Mengzhao, Ping Yunxia, Zhang Chaomin
Author information +
文章历史 +
PDF

摘要

二氧化锡(SnO2)是一种具有高理论比容量、储量丰富、低成本的直接带隙半导体材料,也是取代商用锂离子电池(LIBs)石墨负极的潜在材料。介绍了SnO2的合成方法和结构特点,总结了其在LIBs中的相关应用,并分析了应用中存在的问题。指出对SnO2的研究应利用其高理论比容量的特点,通过制备各种纳米结构的SnO2,或与其他材料构建成复合物,从而获得高性能的LIBs负极材料。

Abstract

Tin dioxide(SnO2) is a direct band gap semiconductor material with high theoretical specific capacity,abundant reserves,and low price.It is also the potential material for replacing graphite anodes in commercial Li-ion batteries(LIBs).The synthesis methods and structural characteristics of SnO2 were introduced,the related applications in LIBs were summarized,and analyzed the problems existing in the application of SnO2 in LIB.It was pointed out that the research on SnO2 should make use of its high theoretical specific capacity,high-performance LIBs anode materials can be obtained by preparing various nanostructured SnO2,or constructing composites with other materials.

关键词

二氧化锡 / 负极材料 / 锂离子电池 / 比容量 / 纳米材料

Key words

tin dioxide / anode material / Li-ion battery / specific capacity / nanomaterial

引用本文

引用格式 ▾
二氧化锡基锂电池负极纳米材料的制备及其研究进展[J]. 化工新型材料, 2022, 50(7): 58-61 DOI:10.19817/j.cnki.issn1006-3536.2022.07.012

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Goodenough J B,Park K S.The Li-ion rechargeable battery:a perspective[J].J Am Chem Soc,2013,135:1167-1176.
[2] 索鎏敏,李泓.锂离子电池过往与未来[J].物理,2020,49(1):17-23.
[3] 严旭明,冯光炷,黄雪.锂离子电池负极材料的制备及应用进展[J].化工新型材料,2019(7):22-25.
[4] Sun L,Ma T T,Zhang J,et al.Double-shelled hollow carbon spheres confining tin as high-performance electrodes for lithium-ion batteries[J].Electrochimica Acta,2019,321:134672-134672.
[5] Oktaviano H S,Yamada K,Waki K.Nano-drilled multiwalled carbon nanotubes:characterizations and application for LIBs anode materials[J].J Mater Chem,2012,22(48):25167-25173.
[6] 闫晴,刘旭东,孙旭东,等.锂离子电池锡基负极材料的改性及研究进展[J].当代化工研究,2021,4:161-162.
[7] Yano A,Shikano M,Ueda A,et al.LiCoO2 degradation behavior in the high-voltage phase transition region and improved reversibility with surface coating[J].J Electrochem Soc,2016,164(1):A6116-A6122.
[8] Li P,Zhao G Q,Zheng X B,et al.Recent progress on silicon-based anode materials for practical lithium-ion battery applications[J].Energy Stor Mater,2018,15:422-446.
[9] 孙富,刘海君,倪玲,等.锂枝晶的生长理论模型及其抑制方法[J].科学通报,2021,66:1-4.
[10] Huang B,Pan Z,Su X,et al.Tin-based materials as versatile anodes for alkali (earth)-ion batteries[J].J Power Sources,2018,395:41-59.
[11] Liu L H,Xie F,Lyu J,et al.Tin-based anode materials with well-designed architectures for next-generation lithium-ion batteries[J].J Power Sources,2016,321:11-35.
[12] Kravchyk K,Protesescu L,Bodnarchuk M I,et al.Monodisperse and inorganically capped Sn and Sn/SnO2 nanocrystals for high-performance Li-ion battery anodes[J].J Am Chem Soc,2013,135(11):4199-4202.
[13] Retoux R,Brousse T,Schleich D M.High-resolution electron microscopy investigation of capacity fade in SnO2 electrodes for lithium-ion batteries[J].J Electrochem Soc,1999,146:2472-2476.
[14] Lee S W,Tsai P P,Chen H.Comparison study of SnO2 thin- and thick-film gas sensors[J].Sensor Actuat B-Chem,2000,67:122-127.
[15] Li N C,Martin C R.A high-rate,high-capacity,nanostructured Sn-based anode prepared using sol-gel template synthesis[J].J Electrochem Soc,2001,148:164-170.
[16] Jin Z.Application of nanocrystalline porous tin oxide thin film for CO sensing[J].Sensor Actuat B-Chem,1998,52:188-194.
[17] Liang Y,Fan J,Xia X H,et al.Synthesis and characterisation of SnO2 nano-single crystals as anode materials for lithium-ion batteries[J].Mater Lett,2007,61(22):4370-4373.
[18] Wang Y,Wu M,Jiao Z,et al.One-dimensional SnO2 nanostructures:facile morphology tuning and lithium storage properties[J].Nanotechnol,2009,20(34):1-7.
[19] Cen W,Yun Z,Mingyuan G,et al.Large-scale synthesis of SnO2 nanosheets with high lithium storage capacity[J].Chem Inform,2010,132:46-47.
[20] Chen S,Xin Y L,Zhou Y Y,et al.Branched CNT@SnO2 nanorods@carbon hierarchical heterostructures for lithium-ion batteries with high reversibility and rate capability[J].J Mater Chem A,2014,2(37):155-182.
[21] Kim C,Noh M,Choi M,et al.Critical size of a nano SnO2 electrode for Li-secondary battery[J].Cheminform,2005,36(38):3297-3301.
[22] Wang Y,Lee J Y,Zeng H C.Polycrystalline SnO2 nanotubes prepared via infiltration casting of nanocrystallites and their electrochemical application[J].Chem Mater,2005,17(15):3899-3903.
[23] Wang C,Zhou Y,Ge M Y.Large-scale synthesis of SnO2 nanosheets with high lithium storage capacity[J].J Am Chem Soc,2009,132(1):46-47.
[24] Chen J S,Cheah Y L,Chen Y T.SnO2 nanoparticles with controlled carbon nanocoating as high-capacity anode materials for lithium-ion batteries[J].J Phys Chem C,2009,113:20504-20508.
[25] Paek S M,Yoo E,Honma I.Enhanced cyclic performance and lithiumstorage capacity of SnO/graphene nanoporous electrodes withthree-dimensionally delaminated flexible structure[J].Nano Lett,2009,9:72-75.
[26] Gao M,Chen X,Pan H,et al.Ultrafine SnO2 dispersed carbon matrixcomposites derived by a sol-gel method as anode materials for lithium ionbatteries[J].Electrochim Acta,2010,55(28):9067-9074.
[27] Zhang B,Zheng Q,Huang Z,et al.SnO2-graphene-carbon nanotube mixture for anode material with improved rate capacities[J].Carbon,2011,49(13):4524-4534.
[28] Yu Y,Gu L,Wang C L,et al.Encapsulation of Sn@carbon nanoparticles in bamboo-like hollow carbon nanofibers as an anode material in lithium-based batteries[J].Angew Chem Int Ed,2009,121(35):6607-6611.
[29] Huang B,Yang J,Zou Y,et al.Sonochemical synthesis of SnO2/carbonnanotubes encapsulated in graphene sheets composites for lithium-ion batterieswith superior electrochemical performance[J].Electrochim Acta,2014,143(5):63-69.

基金资助

国家自然科学基金资助项目(61604094)

AI Summary AI Mindmap
PDF

639

访问

0

被引

导航
相关文章

AI思维导图

/