MXenes/聚合物复合材料在超级电容器中的研究进展

阳文娟, 郭为民*, 沈思静, 尹俊, 秦利平, 刘新梅, 乐志文

化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 38 -42.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (7) : 38-42. DOI: 10.19817/j.cnki.issn1006-3536.2022.07.008
综述与专论

MXenes/聚合物复合材料在超级电容器中的研究进展

    阳文娟, 郭为民*, 沈思静, 尹俊, 秦利平, 刘新梅, 乐志文
作者信息 +

Progress on MXenes/polymer composite for supercapacitor application

  • Yang Wenjuan, Guo Weimin, Shen Sijing, Yin Jun, Qin Liping, Liu Xinmei, Yue Zhiwen
Author information +
文章历史 +
PDF

摘要

MXenes是二维类石墨烯材料中的新成员,具有良好的导电性、导热性和力学性能等优点。但是,其在充放电过程容易坍塌和堆叠,这对其使用寿命有很大影响。通过将导电聚合物插入MXenes片层间,有利于保持MXenes的片层状结构,而且可增加MXenes的电容量和导电速率,因此,MXenes/聚合物复合材料是一种性能优异的超级电容器电极材料。主要介绍了MXenes及其MXenes/聚合物复合材料的性能和制备,讨论了MXenes/聚合物复合材料在超级电容器的应用研究进展,并展望了复合材料在超级电容器上的研究前景。

Abstract

MXenes is a new member of 2D graphene-like materials,and has the advantage for high electrical conductivity,thermal conductivity and mechanical properties.But it is prone to collapse and stack during charging and discharging in supercapacitor,which greatly affects its operating life.Insertion of conductive polymer into the lamellae of MXenes is conducive to maintaining the lamellae structure of MXenes,and increasing the capacitance and conduction rate of MXenes.Therefore,the MXenes/polymer composite is a kind of higher performance electrode material for supercapacitor.The properties and preparation of MXenes and MXenes/polymer composites were introduced,and discussed the application progress of the composite for supercapacitors.The prospect of the composite for supercapacitors was also prospected.

关键词

MXenes/聚合物复合材料 / 超级电容器 / 应用

Key words

MXene/polymer composite / supercapacitor / application

引用本文

引用格式 ▾
MXenes/聚合物复合材料在超级电容器中的研究进展[J]. 化工新型材料, 2022, 50(7): 38-42 DOI:10.19817/j.cnki.issn1006-3536.2022.07.008

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Chen X Y,Zhao Y Y,Li L Z,et al.MXene/polymer nanocomposites:preparation,properties,and applications[J].Polymer Reviews,2020,61(1):80-115.
[2] Naguib M,Mochalin V N,Barsoum M W,et al.25th anniversary article:MXenes:a new family of two-dimensional materials[J].Advanced Materials,2014,26:992-1005.
[3] Zheng S H,Zhang C F,Zhou F,et al.Ionic liquid pre-intercalated MXenefilms for ionogel-based flexible micro-supercapacitors with high volumetric energy density[J].Journal of Materials Chemiatry A,2019,16(7):9478-9485.
[4] Kurtoglu M,Naguib M,Gogotsi Y,et al.First principles study of two-dimensional early transition metal carbides[J].MRS Communications,2012,2(4):133-137.
[5] Borysiuk V N,Mochalin V N,Gogotsi Y.Bending rigidity of two-dimensional titanium carbide (MXene) nanoribbons:a molecular dynamics study[J].Computational Materials Science,2018,143:418-424.
[6] Boota M,Anasori B,Voigt C,et al.Pseudocapacitive electrodes produced by oxidant-free polymerization of pyrrole between the Layers of 2D titanium carbide (MXene)[J].Advanced Materials,2016,28(7):1517-1522.
[7] Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2[J].Advanced Materials,2011,23(37):4248-4253.
[8] Gao L F,Li C,Huang W C,et al.MXene/Polymer membranes:synthesis,properties,and emerging applications[J].Chemisty Materials,2020,32(5):1703-1747.
[9] Mashtalir O,Naguib M,Dyatkin B,et al.Kinetics of aluminum extraction from Ti3AlC2 in hydrofluoric acid[J].Materials Chemistry Physics,2013,139(1):147-152.
[10] Urbankowski P,Anasori B,Makaryan T,et al.Synthesis of two-dimensional titanium nitride Ti4N3 (MXene)[J].Nanoscale,2016,8(22):11385-11391.
[11] Li T F,Yao L L,Liu Q L,et al.Fluorine-free synthesis of high-purity Ti3C2Tx(T=—OH,—O) via alkali treatment[J].AngewandteChemie International Edition,2018,57(21):6115-6119.
[12] 王一博,李腾飞,李明明,等.二维材料MXene制备及其在电催化领域的研究进展[J].电源技术,2020,44(5):781-784,790.
[13] Wu W L,Wei D,Zhu J F,et al.Enhanced electrochemical performances of organ-like Ti3C2 Mxenes/polypyrrole composites as supercapacitors electrode materials[J].Ceramics International,2019,45(6):7328-7337.
[14] Jian X,He M,Chen L,et al.Three-dimensional carambola-like MXene/polypyrrole composite produced by one-step co-electrodeposition method for electrochemical energy storage[J].Electrochimica Acta,2019,318:820-827.
[15] Wang D Z,Lin Y,Hu D W,et al.Multifunctional 3D-MXene/PDMS nanocomposites for electrical,thermal and triboelectric applications[J].Composites Part A-Applide Scienceand Manufacturing,2020,130:105754.
[16] Zheng L,Ren C E,Zhao M Q,et al.Flexible and conductive MXene films and nanocomposites with high capacitance[J].Proceedings of the National Academy of Sciencesof the United Statesof America,2014,111(47):16676-16681.
[17] Chen H Y,Ginzburg V V,Yang J,et al.Thermal conductivityof polymer-based composites:fundamentals and applications[J].Progress in Polymer Scienc,2016,59:41-85.
[18] Balandin A A.Thermal properties of graphene and nanostructured carbon materials[J].Nature Materials,2011,10(8):569-581.
[19] Wu X M,Lian M,Wang Q G.A high-performance asymmetric supercapacitorsbased on hydrogen bonding nanoflower-like polypyrrole and NiCo(OH)2electrode materials[J].ElectrochimActa,2019,295:655-661.
[20] Chen J,Huang X Y,Sun B,et al.Vertically aligned and interconnected boron nitride nanosheets for advanced flexible nanocomposite thermalinterface materials[J].ACS Applied Materials & Interfaces,2017,9(36):30909-30917.
[21] Lin Z H,Yang Y,Wu J M,et al.BaTiO3 nanotubes-based flexible and transparent nanogenerators[J].The Journal of Physical Chemistry Letters,2012,3(23):3599-3604.
[22] Wu W L,Wang C W,Zhao C H,et al.Facile strategy of hollow polyaniline nanotubes supported on Ti3C2-MXene nanosheets for high-performance symmetric supercapacitors[J].Journal of Colloid and Interface Science,2020,580:601-613.
[23] Zhang C F,Ma Y L,Zhang X T,et al.Two-dimensional transition metal carbides and nitrides (MXenes):synthesis,properties,and electrochemical energy storage applications[J].Energy & Environmental Materials,2020,3(1):29-55.
[24] Si J Y,Tawiah B,Sun W L,et al.Functionalization of MXenenanosheets for polystyrene towards high thermal stability and flame retardant properties[J].Polymers,2019,11(6):976.
[25] Wu W L,Niu D J,Zhu J F,et al.Organ-like Ti3C2 Mxenes/polyaniline composites by chemical grafting as high-performance supercapacitors[J].Journal of Electroanalytical Chemistry,2019,847:113203.
[26] Pech D,Brunet M,Durou H,et al.Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon[J].Nature Nanotechnology,2010,5(9):651-654.
[27] Poonam,Sharma K,Arora A,et al.Review of supercapacitors:materials and devices[J].Journal of Energy Storage,2019,21:801-825.
[28] Zang X B,Wang J L,Qin Y J,et al.Enhancing capacitance performance of Ti3C2Tx MXene as electrode materials of supercapacitor:from controlled preparation to composite structure construction[J].Nano-Micro Letters,2020,12(1):77.
[29] Rakhi R B,Ahmed B,Anjum D,et al.Directchemical synthesis of MnO2 nanowhiskers on transitionmetal carbide surfaces for supercapacitor applications[J].ACS Applied Materials & Interfaces,2016,8(29):18806-18814.
[30] Guo M,Liu C,Zhang Z,et al.Flexible Ti3C2Tx@Al electrodes with ultrahigh areal capacitance:insitu regulation of interlayer conductivity and spacing[J].Advanced FunctionalMaterials,2018,28(37):1803196.
[31] Naguib M,Mashtalir O,Lukatskaya M R,et al.One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes[J].Chemical Communications (Cambridge,England),2014,50(56):7420-7423.
[32] Wang H R,Li L,Zhu C C,et al.In situ polymerized Ti3C2Tx/PDA electrode with superior areal capacitance for supercapacitors[J].Journal of Alloys and Compounds,2018,778:858-865.
[33] Weng L,Qi F Y,Min Y G.The Ti3C2Tx MXene coated metal mesh electrodes for stretchable supercapacitors[J].Materials Letters,2020,278:128235.
[34] Qin L Q,Tao Q Z,Ahmed E G,et al.High-performance ultrathin flexible solid-state supercapacitors based on solution processable Mo1.33C MXene and PEDOT∶PSS[J].Advanced Functional Materials,2018,28(2):1703808.

基金资助

国家自然科学基金(21661007)资助;广西研究生教育创新计划(YCSW2021312)

AI Summary AI Mindmap
PDF

693

访问

0

被引

导航
相关文章

AI思维导图

/