离子液体具有独特的物理化学性质,如不易燃、热稳定性好、阴阳离子可设计等。其在氧化石墨烯复合材料的制备中可以代替有机溶剂,绿色环保又安全。氧化石墨烯具备石墨烯卓越的力学、电学、热学等性能,其表面的大量含氧官能团也为它的发展提供了很多可能。通过离子液体对氧化石墨烯功能化改性制备复合材料,可应用于催化、电化学等方面。主要针对咪唑类离子液体在氧化石墨烯复合材料制备过程中的应用进行综述。
Ionic liquid has unique physical and chemical properties,such as non-flammable,good thermal stability,cation and anion can be designed.It can replace organic solvents in the preparation of graphene oxide(GO) composite materials,green and safe.GO has excellent properties of graphene,such as graphene,electricity,thermal and so on,its surface of a large number of oxygen-containing functional groups for its development provides a lot of possibilities,through the ionic liquid for its functional modified preparation of the corresponding composite materials and applied to catalytic,electrochemical and so on.The following was mainly review for the application of imidazolium ionic liquid in the preparation process of GO composite materials.
[1] Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] 朱宏文,段正康,张蕾,等.氧化石墨烯的制备及结构研究进展[J].材料科学与工艺,2017,25(6):82-88.
[3] 赵磊,杨红梅,刘畅,等.辛硫醇改性氧化石墨烯在润滑脂中的摩擦学性能研究[J].润滑与密封,2020,45(2):7-11.
[4] 曹思梦,岳晨阳,苏桂田,等.离子液体的种类和制备方法[J].山东化工,2020,49(18):57-59.
[5] Guo C X,Lu Z S,Lei Y,et al.Ionic liquid-graphene composite for ultratrace explosive trinitrotoluene detection[J].Electrochemistry Communications,2010,12(9):1237-1240.
[6] Liu Y,Wu G,Pang X,et al.Isobutane alkylation with 2-butene in novel ionic liquid/solid acid catalysts[J].Fuel,2019,252:316-324.
[7] Yusuf N Y M,Masdar M S,Isahak W N R W,et al.Impregnated carbon-ionic liquid as innovative adsorbent for H2/CO2 separation from biohydrogen[J].International Journal of Hydrogen Energy,2018,44:3414-3424.
[8] Liu K X,Wang Z Y,Shi L Y,et al.Ionic liquids for high performance lithium metal batteries-ScienceDirect[J].Journal of Energy Chemistry,2020,59(2):320-333.
[9] 杨胜凯,王春风,张松娜,等.基于离子液体的石墨烯及其复合物制备的研究进展[J].中国科学:化学,2016,46(12):1277-1291.
[10] 陈松丛,韩峰,刘建华.离子液体共价键功能化氧化石墨烯负载催化材料催化反应研究进展[J].分子催化,2018,32(4):382-396.
[11] Hao Y,Cui Y,Peng J,et al.Preparation of graphene oxide/cellulose composites in ionic liquid for Ce(Ⅲ) removal[J].Carbohydrate Polymers,2019,208:269-275.
[12] Nguyen V H,Shim J J.Ionic liquid mediated synthesis of graphene-TiO2 hybrid and its photocatalytic activity[J].Materials Science and Engineering B,2013,180:38-45.
[13] Ghasemi S,Setayesh S R,Yangjeh A H,et al.Assembly of CeO2-TiO2 nanoparticles prepared in room temperature ionic liquid on graphene nanosheets for photocatalytic degradation of pollutants[J].Journal of Hazardous Materials,2012,199-200:170-178.
[14] Barik B,Kumar A,Nayak P S,et al.Ionic liquid assisted mesoporous silica-graphene oxide nanocomposite synthesis and its application for removal of heavy metal ions from water[J].Materials Chemistry and Physics,2019,239:122028.
[15] Shi Y C,Chen S S,Feng J J,et al.Dicationic ionic liquid mediated fabrication of Au@Pt nanoparticles supported on reduced graphene oxide with highly catalytic activity for oxygen reduction and hydrogen evolution[J].Applied Surface Science,2018,441(31):438-447.
[16] Wang S,Zhang Y,Ma H L,et al.Ionic-liquid-assisted facile synthesis of silver nanoparticle-reduced graphene oxide hybrids by gamma irradiation[J].Carbon,2013,55:245-252.
[17] 石瑞丽,陶菡,张义明,等.离子液体与纳米材料协同电催化的新型生物传感器研究进展[J].化工新型材料,2010,38(9):19-22.
[18] 黄国家,陈志刚,李茂东,等.石墨烯和氧化石墨烯的表面功能化改性[J].化学学报,2016,74(10):789-799.
[19] Kowsari E,Chirani M R.High efficiency dye-sensitized solar cells with tetra alkyl ammonium cation-based ionic liquid functionalized graphene oxide as a novel additive in nanocomposite electrolyte[J].Carbon,2017,118:384-392.
[20] Shi H L,Wang R Y,Lou M R,et al.A novel Pt/pyridine ionic liquid polyoxometalate/rGO tri-component hybrid and its enhanced activities for methanol electrooxidation[J].Electrochimica Acta,2018,294:93-101.
[21] Zhang S H,Chen X M,Liu G S,et al.A novel sensing platform based on ionic liquid integrated carboxylic-functionalized graphene oxide nanosheets for honokiol determination[J].Electrochimica Acta,2015,155:45-53.
[22] Wong A,Tiago,Silva A,et al.Electrochemical sensor based on graphene oxide and ionic liquid for ofloxacin determination at nanomolar levels[J].Talanta,2016,161:333-341.
[23] Ogunleye D T,Akpotu S O,Moodley B.Adsorption of sulfamethoxazole and reactive blue 19 using graphene oxide modified with imidazolium based ionic liquid[J].Environmental Technology & Innovation,2020,17:100616.
[24] Lawal I A,Lawal M M,Akpotu S,et al.Non-covalent graphene oxide functionalized ionicliquid:theoretical,isotherm,kinetics and regeneration studies on the adsorption of pharmaceuticals[J].Industrial & Engineering Chemical Reseach,2020,59(11):4945-4957.
[25] Li M Y,Yang C L,Yan Y H,et al.An integrated solid phase extraction with ionic liquid-thiol-graphene oxide as adsorbent for rapid isolation of fipronil residual in chicken eggs[J].Journal of Chromatography A,2020,1631:461568.
[26] Jia H,Chen X,Liu C Y,et al.Ultrafine palladium nanoparticles anchoring graphene oxide-ionic liquid grafted chitosan self-assembled materials:the novel organic-inorganic hybrid catalysts for hydrogengeneration in hydrolysis of ammonia borane[J].International Journal of Hydrogen Energy,2018;43(27):12081-12090.
[27] Jia H,Zhu Y,Song X,et al.Magnetic graphene oxide-ionic liquid grafted chitosan composites anchored Pd(0) nanoparticles:a robust heterogeneous catalyst with enhanced activity and superior reusability for hydrogen generation from ammonia borane[J].International Journal of Hydrogen Energy,2018,43(43):19939-19946.
[28] B Raut A,S Shende V,Sasaki B,et al.Reductive amination of levulinic acid to N-substituted pyrrolidones over RuCl3 metal ion anchored in ionic liquid immobilized on graphene oxide[J].Journal of Catalysis,2020,383:206-214.
[29] Gan C l,Liang T,Li W,et al.Amine-terminated ionic liquid modified graphene oxide/copper nanocomposite toward efficient lubrication[J].Applied Surface Science,2019,491:105-115.
[30] 张燕,张敏,陈妹琼,等.基于[C10-mim+]Br-固定HRP于Au/石墨烯复合材料电极表面的新型H2O2酶生物传感器[J].化工新型材料,2014,42(3):24-26.
[31] Zambare R S,Nemade P R.Ionic liquid-modified graphene oxide sponge for hexavalent chromium removal from water[J].Colloids and Surfaces A Physicochemical and Engineering Aspects,2021,609:125657.
[32] Huang G J,Isfahani A P,Muchtar A,et al.Pebax/ionic liquid modified graphene oxide mixed matrix membranes for enhanced CO2 capture[J].Journal of Membrane Science,2018,565:370-379.
[33] Yan Y,Cui N,Liu F,et al.Ionic liquid induced electrostatic self-assemble of reduced graphene oxide for high-performance all-solid-state flexible symmetric supercapacitor[J].Journal of Alloys and Compounds,2018,776:22-30.
[34] Zhou N,Li J H,Chen H,et al.A functional graphene oxide-ionic liquid composites/gold nanoparticles sensing platform for ultrasensitive electrochemical detection of Hg2+[J].Analyst,2012,138(4):1091-1108.
[35] Damlin P,Suominen M,Heinonen M,et al.Non-covalent modification of graphene sheets in PEDOT composite materials by ionic liquids[J].Carbon,2015(93):533-543.
[36] Shabani-Nooshabadi M,Roostaee M,Tahernejad-Javazmi F.Graphene oxide/NiO nanoparticle composite-ionic liquid modified carbon paste electrode for selective sensing of 4-chlorophenol in the presence of nitrite[J].Journal of Molecular Liquids,2016,219:142-148.
[37] Ramesh K,Siboro S A P,Kim D W,et al.Ultrasound-accelerated covalent-functionalization of reduced graphene oxide with imidazolium-based poly(ionic liquid)s by Diels-Alder click reaction for supercapacitors[J].Reactive and Functional Polymers,2020,152:104605.
[38] Bag S,Samanta A,Bhunia P,et al.Rational functionalization of reduced graphene oxide with imidazolium-based ionic liquid for supercapacitor application[J].International Journal of Hydrogen Energy,2016,41:22134-22143.
[39] Mohamadi M,Kowsari E,Haddadi-Asl V,et al.Highly-efficient microwave absorptivity in reduced graphene oxide modified with PTA@ imidazolium based dicationic ionic liquid and fluorine atom[J].Composites Science and Technology,2020,188:107960.
基金资助
河北省高等学校科学技术研究项目(ZD2021420)
PDF
