海藻酸钠复合材料吸附污染物研究进展

聂发辉, 吴道, 黄慧倩

化工新型材料 ›› 2022, Vol. 50 ›› Issue (6) : 307 -312.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (6) : 307-312. DOI: 10.19817/j.cnki.issn1006-3536.2022.06.061
开发与应用

海藻酸钠复合材料吸附污染物研究进展

    聂发辉, 吴道, 黄慧倩
作者信息 +

Research progress on sodium alginate composite adsorption

  • Nie Fahui, Wu Dao, Huang Huiqian
Author information +
文章历史 +
PDF

摘要

海藻酸钠水溶液能与金属离子发生交联反应形成海藻酸钙凝胶,该凝胶是与其他常见吸附剂形成复合吸附剂的理想骨架,有利于对水溶液中污染物的去除,但关于海藻酸钠复合材料吸附污染物的综述较少。从海藻酸钠及其复合物、磁性海藻酸钠、磁性海藻酸钠复合物等三方面简要介绍了国内外研究学者对海藻酸钠复合材料的制作过程、海藻酸钠复合材料吸附的影响因素以及复合吸附剂对污染物的吸附性能,分析认为带磁性的海藻酸钠复合吸附剂具有吸附多种污染物、易从水溶液中脱离等优点,是未来吸附剂研究的热点。

Abstract

Sodium alginate solution can crosslink with divalent metal ions to form calcium alginate gel.The gel is ideal framework for forming composite adsorbents with other common adsorbents.It is benneficial to remove contaminants from aqueous solution.However,there are few reviews on the adsorption of pollutants by sodium alginate composites.The preparation process of sodium alginate composite materials by domestic and foreign researchers was briefly introduced from three aspects:sodium alginate and complex,magnetic sodium alginate complex,the influence factors of sodium alginate composite and its adsorption property to pollutants.It was concluded that the the magnetic sodium alginate composite adsorbent had the advantages of absorbing a variety of pollutants and being easy to be separated from aqueous solution.

关键词

海藻酸钠 / 磁性海藻酸钠复合材料 / 吸附 / 重金属离子

Key words

sodium alginate / magnetic sodium alginate composite / adsorption / heavy metal ion

引用本文

引用格式 ▾
海藻酸钠复合材料吸附污染物研究进展[J]. 化工新型材料, 2022, 50(6): 307-312 DOI:10.19817/j.cnki.issn1006-3536.2022.06.061

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 高小龙.农田土壤重金属污染的危害及修复技术浅谈[J].农家参谋,2019(19):44.
[2] 杨艳红.土壤重金属污染的危害以及防治措施[J].环境与发展,2019,31(9):62-64.
[3] 李忠霞,仙米西努尔·克里木,希热娜依·铁里瓦尔地,等.谈农田土壤重金属污染情况及修复技术[J].环境与发展,2019,31(8):52-54.
[4] 徐德良.土壤重金属污染治理与修复方法[J].环境与发展,2019,31(6):46-47.
[5] 闫岩,杜雯雯.浅谈土壤重金属的治理方法和研究展望[J].科学技术创新,2019(13):185-186.
[6] 王爽,许国根,贾瑛,等.海藻酸钠凝胶球处理有机废水的研究进展[J].应用化工,2018,47(12):2715-2718.
[7] 于长江,颜杨婕,凌玉,等.海藻酸钠复合吸附材料研究进展[J].海南师范大学学报(自然科学版),2017,30(2):154-160.
[8] Wilkinson S C,Goulding K H,Robinson P K.Mercury accumulation and volatilization in immobilized algal cell systems[J].Biotech Letter,1989,11(12):861-864.
[9] Song D,Park S J,Kang H W,et al.Recovery of lithium(I),strontium(Ⅱ),and lanthanum(Ⅲ) using Ca-alginate beads[J].Journal of Chemical & Engineering Data,2013,58(9):2455-2464.
[10] Zhou Q,Lin X,Li B,et al.Fluoride adsorption from aqueous solution by aluminum alginate particles prepared via electrostatic spinning device[J].Chemical Engineering Journal,2014,256(6):306-315.
[11] Gao Q J,Wang X,Wang H X,et al.Sulfhydryl-modified sodium alginate film for lead-ion adsorption[J].Materials Letters,2019,254(25):149-153.
[12] 胡鹏,牛静,薛首峰,等.生物质碳负载铁-钴磁性复合材料的合成及在染料废水处理中的应用[J].化工新型材料,2018,46(4):220-223.
[13] Do X H,Lee B K.Removal of Pb2+ using a biochar-alginate capsule in aqueous solution and capsule regeneration[J].Journal of Environmental Management,2013,131(75):375-382.
[14] 杜淑雯,周浩,彭玉倩,等.海藻酸钠固定化污泥基生物质炭对铜的吸附性能研究[J].环境工程,2017,35(2):37-42.
[15] Xiao Z,Zhang L,Wu L,et al.Adsorptive removal of Cu(Ⅱ) from aqueous solutions using a novel macroporous bead adsorbent based on poly(vinyl alcohol)/sodium alginate/KMnO4 modified biochar[J].Journal of the Taiwan Institute of Chemical Engineers,2019,102:110-117.
[16] Joz M H,Babaei A,Arab B Z,et al.Investigating the best strategy to diminish the toxicity and enhancethe antibacterial activity of graphene oxide by chitosan addition[J].Carbohydrate Polymers,2019,225(25):115-125.
[17] 周腾智.氧化石墨烯/海藻酸钠双网络凝胶球对水中锑的吸附特性研究[D].湘潭:湖南科技大学,2018.
[18] Fan J,Shi Z,Lian M,et al.Mechanically strong graphene oxide/sodium alginate/polyacrylamide nanocomposite hydrogel with improved dye adsorption capacity[J].Journal of Materials Chemistry A,2013,1(25):7433-7443.
[19] 马强.稀土离子配位制备海藻酸钠凝胶和层状纳米薄膜[D].南京:东南大学,2017.
[20] 尹海洋.海藻酸钠/稀土高分子凝胶球的制备及其对染料吸附性能的研究[D].呼和浩特:内蒙古师范大学,2019.
[21] Abou T M F,Hegazy D E,Ismail S A.Radiation synthesis,characterization and dye adsorption of alginate-organopHilic montmorillonite nanocomposite[J].Carbohydrate Polymers,2012,87(3):2263-2269.
[22] He F,Zhou Q,Wang L,et al.Fabrication of a sustained release delivery system for pesticides using interpenetrating polyacrylamide/alginate/montmorillonite nanocomposite hydrogels[J].Applied Clay Science,2019,183:105347.
[23] Wu Y,Mimura H,Niibori Y,et al.Study on adsorption behavior of cesium using ammonium tungstopHospHate(AWP)-calcium alginate microcapsules[J].Science China Chemistry,2012,55(9):1719-1725.
[24] 李克腾.海藻酸钠基复合吸附材料的制备及其吸附重金属离子的研究[D].安庆:安庆师范大学,2019.
[25] 李琰君,吴尧伟,杨阿三,等.海藻酸钠基吸附材料对铁离子的吸附动力学研究[J].化学工程,2019,47(7):10-14.
[26] 王志伟.海藻酸钠—聚谷氨酸凝胶树脂吸附稀土、重金属离子的研究[D].郑州:河南农业大学,2015.
[27] 韦学玉,刘志刚,万耀强,等.磁性壳聚糖纳米材料对水中Cu(Ⅱ)吸附性能的研究[J].华东交通大学学报,2017,34(4):129-134.
[28] Yang L,Zhang Y,Liu X,et al.The investigation of synergistic and competitive interaction between dye Congo red and methyl blue on magnetic MnFe2O4[J].Chemical Engineering Journal,2014,246:88-96.
[29] 孔岩,韩志勇,庄媛,等.磁性高分子复合水凝胶的制备及其对水中铜离子的吸附性能[J].环境科学学报,2018,38(3):1001-1009.
[30] 陈晨,李北罡.磁性海藻酸铈凝胶球的制备、表征及其吸附应用[J].稀土,2019,40(4):71-79.
[31] Yang C,Shih M,Chiu H,et al.Magnetic pycnoporus sanguineus-loaded alginate composite beads for removing dye from aqueous solutions[J].Molecules,2014,19(6):8276-8288.
[32] Li X,Qi Y,Li Y,et al.Novel magnetic beads based on sodium alginate gel crosslinked by zirconium(Ⅳ) and their effective removal for Pb2+ in aqueous solutions by using a batch and continuous systems[J].Bioresource Technology,2013,142(9):611-619.
[33] 江湛如.磁性海藻酸铁介孔碳微球的合成及其吸附水体中砷、锑的研究[D].长沙:湖南农业大学,2018.
[34] Idris A,Ismail N S M,Hassan N,et al.Synthesis of magnetic alginate beads based on maghemite nanoparticles for Pb(Ⅱ) removal in aqueous solution[J].Journal of Industrial and Engineering Chemistry,2012,18(5):1582-1589.
[35] Edathil A A,Alhseinat E,Banat F.Removal of heat stable salts from industrial lean methyldiethanolamine using magnetic alginate/iron oxide hydrogel composite[J].International Journal of Greenhouse Gas Control,2019,83:117-127.
[36] Fuks L,Herdzik-Koniecko I,Polkowska-Motrenko H,et al.Novel procedure for removal of the radioactive metals from aqueous wastes by the magnetic calcium alginate[J].International Journal of Environmental Science and Technology,2018,15(12):2657-2668.
[37] 韦学玉,刘志刚,万耀强,等.磁性壳聚糖纳米材料对水中Cu(Ⅱ)吸附性能的研究[J].华东交通大学学报,2017,34(4):129-136.
[38] Tao H C,Li S,Zhang L,et al.Magnetic chitosan/sodium alginate gel bead as a novel composite adsorbent for Cu(Ⅱ) removal from aqueous solution[J].Environmental Geochemistry and Health,2019,41(1):297-308.
[39] Wang S,Lu Y,Ouyang X,et al.Fabrication of chitosan-based MCS/ZnO@Alg gel microspHeres for efficient adsorption of As(V)[J].International Journal of Biological Macromolecules,2019,139:886-895.
[40] 武庭瑄.海藻酸钠/聚乙烯醇/氧化石墨烯磁性微球去除水中阳离子染料的研究[C].北京:中国化学会第29届学术年会摘要集——第27分会:多孔功能材料,2014.
[41] Sharif A,Khorasani M,Shemirani F.Nanocomposite bead (NCB) based on bio-polymer alginate caged magnetic grapHene oxide synthesized for adsorption and preconcentration of lead(Ⅱ) and copper(Ⅱ) ions from urine,saliva and water samples[J].Journal of Inorganic and Organometallic Polymers and Materials,2018,28(6):2375-2387.
[42] Wu Z,Deng W,Zhou W,et al.Novel magnetic polysaccharide/grapHene oxide@Fe3O4 gel beads for adsorbing heavy metal ions[J].Carbohydrate Polymers,2019,216:119-128.
[43] Li C,Lu J,Li S,et al.Synthesis of magnetic microspHeres with sodium alginate and activated carbon for removal of methylene blue[J].Materials,2017,10(1):84-97.
[44] De Castro Alves L,Yáñez-Vilar S,Piñeiro-Redondo Y,et al.Novel magnetic nanostructured beads for cadmium(Ⅱ) removal[J].Nanomaterials,2019,9(3):356-370.
[45] Bayat M,Javanbakht V,Esmaili J.Synthesis of zeolite/nickel ferrite/sodium alginate bionanocomposite via a co-precipitation technique for efficient removal of water-soluble methylene blue dye[J].International Journal of Biological Macromolecules,2018,116(23):607-619.
[46] Ahmadpoor F,Shojaosadati S A,Mousavi S Z.Magnetic silica coated iron carbide/alginate beads:synthesis and application for adsorption of Cu(Ⅱ) from aqueous solutions[J].International Journal of Biological Macromolecules,2019,128:941-947.

基金资助

江西省教育厅科学技术研究项目(GJJ90340)

AI Summary AI Mindmap
PDF

699

访问

0

被引

导航
相关文章

AI思维导图

/