水污染问题已威胁到全球生态环境和人类健康,大量有机污染物的排放给全球水治理带来了巨大挑战,并且传统处理方法并不能有效去除部分有机污染物。近年来,金属-有机框架(MOFs)的研究为水中有机污染物的去除带来了新思路。综述了有关MOFs吸附去除水中有机污染物的研究和应用进展,旨在为基于MOFs的废水处理提供参考。
The problem of water pollution has threatened the global ecological environment and human health,emission of a large amount of organic pollutants has brought great challenges to global water governance,and traditional treatment methods cannot effectively remove some organic pollutants.In recent years,the research on metal-organic frameworks (MOFs) has brought new ideas for the removal of organic pollutants in water.The research and application progress on the adsorption and removal of organic pollutants in water by MOFs were reviewed,and aimed at provide a reference for the wastewater treatment based on MOFs.
[1] Yan J,Peng J,Lai L,et al.Activation CuFe2O4 by hydroxylamine for oxidation of antibiotic sulfamethoxazole[J].Environmental Science & Technology,2018,52(24):14302-14310.
[2] 窦容妮.金属—有机框架及其功能化纤维膜对三氯生的去除研究[D].广州:华南理工大学,2018.
[3] Kuppler R J,Timmons D J,Fang Q,et al.Potential applications of metal-organic frameworks[J].Coordination Chemistry Reviews,2009,253(23/24):3042-3066.
[4] Wu Gege,Ma Jiping,Li Shuang,et al.Cationic metal-organic frameworks as an efficient adsorbent for the removal of 2,4-dichlorophenoxyacetic acid from aqueous solutions[J].Environmental Research,2020,186:109542.
[5] Wang J,Li M,Li D.An exceptionally stable and water-resis-tant metal-organic framework with hydrophobic nanospaces for extracting aromatic pollutants from water[J].Chemistry-A European Journal,2014,20(38):12004-12008.
[6] Hasan Z,Choi E,Jhung S H.Adsorption of naproxen and clofibric acid over a metal-organic framework MIL-101 functionalized with acidic and basic groups[J].Chemical Engineering Journal,2013,219:537-544.
[7] Lin Z,Zheng H,Zeng Y,et al.Effective and selective adsorption of organoarsenic acids from water over a Zr-based metal-organic framework[J].Chemical Engineering Journal,2019,378:122196.
[8] 崔巍,张卫,刘淋,等.功能化金属有机骨架材料对水中痕量磺胺氯哒嗪的吸附行为及其机理[J].环境化学,2020,39(1):80-88.
[9] Quan X,Sun Z,Xu J,et al.Construction of an aminated MIL-53(Al)-functionalized carbon nanotube for the efficient removal of bisphenol AF and metribuzin[J].Inorg Chem,2020,59(5):2667-2679.
[10] Yılmaz E,Sert E,Atalay F S.Synthesis,characterization of a metal organic framework:MIL-53(Fe) and adsorption mechanisms of methyl red onto MIL-53(Fe)[J].Journal of the Taiwan Institute of Chemical Engineers,2016,65:323-330.
[11] 任丹,李碟,黄昭露,等.水热炭化对吸附处理染料废水产生的废活性炭的再生效果[J].环境科学研究,2021,34(2):365-371.
[12] 马生花,马芙莲,解玉龙.BiOI/ZIF-8复合材料的制备及光催化性能[J].硅酸盐通报,2020,39(9):2993-3000.
[13] 王朋涛.纳米颗粒强化微生物对偶氮染料的降解机理研究[D].南京:南京林业大学,2019.
[14] Yang S,Chang Y,Wang H,et al.Folding/aggregation of graphene oxide and its application in Cu2+ removal[J].Journal of Colloid and Interface Science,2010,351(1):122-127.
[15] Sun Y,Chen M,Liu H,et al.Adsorptive removal of dye and antibiotic from water with functionalized zirconium-based metal organic framework and graphene oxide composite nanomaterial Uio-66-(OH)2/GO[J].Applied Surface Science,2020,525:146614.
[16] 孟祖超,刘斌,李成希,等.金属-有机骨架复合材料Cu-1,3,5-苯三甲酸/氧化石墨烯对亚甲基蓝的吸附性能研究[J].化工新型材料,2018,46(11):225-229.
[17] Wang Ruimeng,Liu Long,Sidra S,et al.Engineering pH-switchable UiO-66 via in-situ amino acid doping for highly selective adsorption of anionic dyes[J].Chemical Engineering Journal,2020,395:124958.
[18] Dong X,Lin Y,Ma Y,et al.N-contaning UiO-67 derived multifunctional hybrid materials as highly effective adsorbents for removal of Congo red[J].Inorganica Chimica Acta,2020,510:119748.
[19] Yang Q,Ren S,Zhao Q,et al.Selective separation of methyl orange from water using magnetic ZIF-67 composites[J].Chemical Engineering Journal,2018,333:49-57.
[20] Tan F,Liu M,Li K,et al.Facile synthesis of size-controlled MIL-100(Fe) with excellent adsorption capacity for methy-lene blue[J].Chemical Engineering Journal,2015,281:360-367.
[21] Blair B D,Crago J P,Hedman C J,et al.Pharmaceuticals and personal care products found in the Great Lakes above concentrations of environmental concern[J].Chemosphere,2013,93(9):2116-2123.
[22] Dou Rongni,Zhang Junya,Chen Yuancai,et al.High efficiency removal of triclosan by structure-directing agent modified mesoporous MIL-53(Al)[J].Environmental Science and Pollution Research,2017,24(9):8778-8789.
[23] Kabtamu D M,Wu Y,Li F.Hierarchically porous metal-organic frameworks:synthesis strategies,structure(s),and emerging applications in decontamination[J].Journal of Hazardous Materials,2020,397:122765.
[24] Ma J,Li S,Wu G,et al.Preparation of magnetic metal-organic frameworks with high binding capacity for removal of two fungicides from aqueous environments[J].Journal of Industrial and Engineering Chemistry,2020,90:178-189.
[25] Song J Y,Ahmed I,Seo P W,et al.UiO-66-type metal-organic framework with free carboxylic acid:versatile adsorbents via H-bond for both aqueous and nonaqueous phases[J].ACS Applied Materials & Interfaces,2016,8(40):27394-27402.
[26] Azhar M R,Abid H R,Sun H,et al.Excellent performance of copper based metal organic framework in adsorptive removal of toxic sulfonamide antibiotics from wastewater[J].J Colloid Interface Sci,2016,478:344-352.
[27] Zhao Rui,Ma Tingting,Zhao Shuai,et al.Uniform and stable immobilization of metal-organic frameworks into chitosan matrix for enhanced tetracycline removal from water[J].Chemical Engineering Journal,2020,382:122893.
[28] Li Kan,Li Jingjing,Zhao Ni,et al.Removal of tetracycline in sewage and dairy products with high-stable MOF[J].Molecules,2020,25(6):1312.
[29] Ahmed I,Bhadra B N,Lee H J,et al.Metal-organic framework-derived carbons:preparation from ZIF-8 and application in the adsorptive removal of sulfamethoxazole from water[J].Catalysis Today,2018,301:90-97.
[30] Bhadra B N,Yoo D K,Jhung S H.Carbon-derived from metal-organic framework MOF-74:a remarkable adsorbent to remove a wide range of contaminants of emerging concern from water[J].Applied Surface Science,2020,504:144348.
[31] Seo P W,Bhadra B N,Ahmed I,et al.Adsorptive removal of pharmaceuticals and personal care products from water with functionalized metal-organic frameworks:remarkable adsorbents with hydrogen-bonding abilities[J].Scientific Reports,2016,6(1):34462.
[32] Mithun S,Ji Y S,Sung H J.Adsorption of organic arsenic acids from water over functionalized metal-organic frameworks[J].Journal of Hazardous Materials,2017,335:162-169.
[33] Vinod K G,Imran A,Suhas,et al.Adsorption of 2,4-D and carbofuran pesticides using fertilizer and steel industry wastes[J].Journal of Colloid and Interface Science,2006,299(2):556-563.
[34] Liu G,Li L,Xu D,et al.Metal-organic framework preparation using magnetic graphene oxide-beta-cyclodextrin for neonicotinoid pesticide adsorption and removal[J].Carbohydr Polym,2017,175:584-591.
[35] Feng D,Xia Y.Comparisons of glyphosate adsorption properties of different functional Cr-based metal-organic frameworks[J].J Sep Sci,2018,41(3):732-739.
[36] Yang Qingfeng,Wang Jing,ZhangWentao,et al.Interface engineering of metal organic framework on graphene oxide with enhanced adsorption capacity for organophosphorus pesticide[J].Chemical Engineering Journal,2017,313:19-26.
[37] Njoku V O,Foo K Y,Hameed B H.Microwave-assisted preparation of pumpkin seed hull activated carbon and its application for the adsorptive removal of 2,4-dichlorophenoxyacetic acid[J].Chemical Engineering Journal,2013,215-216:383-388.
[38] Li S,Fan F,Sha C,et al.Preparation of UiO-66-NH2 and UiO-66-NH2/sponge for adsorption of 2,4-dichlorophenoxyacetic acid in water[J].Ecotoxicology and Environmental Safety,2020,194:110440.
[39] Wetherill Y B,Akingbemi B T,Kanno J,et al.In vitro molecular mechanisms of bisphenol A action[J].Reprod Toxicol,2007,24(2):178-198.
[40] 王硕,庄太凤.双酚A对新生儿的健康危害[J].环境化学,2020,39(9):2404-2412.
[41] Qin F X,Jia S Y,Liu Yong,et al.Adsorptive removal of bisphenol A from aqueous solution using metal-organic frameworks[J].Desalination and Water Treatment,2015,54(1):93-102.
[42] Pan Y,Li Z,Zhang Z,et al.Adsorptive removal of phenol from aqueous solution with zeolitic imidazolate framework-67[J].Journal of Environmental Management,2016,169:167-173.
[43] Bhadra B N,Ahmed I,Jhung S H.Remarkable adsorbent for phenol removal from fuel:functionalized metal-organic framework[J].Fuel,2016,174:43-48.
基金资助
江苏省双创团队[(2018)2017]