离子交换膜是燃料电池、液流电池及电渗析技术的核心部件,应用过程中存在电导率低和化学稳定性差等问题。利用无机材料自身良好的性能和表面修饰,引入离子交换膜基质是一种有效的方法。碳纳米材料具有尺寸可控、比表面积大、环境友好等特点,是优良的无机填料。综述了添加低维碳纳米材料的离子交换杂化膜的制备方法、类型和应用现状,指出不同低维碳纳米材料在离子交换杂化膜制备过程中面临的问题,并对未来离子交换杂化膜的研究方向进行了展望。
Ion exchange membrane is the core component of fuel cell,flow battery,electrodialysis and other technologies.However,there are problems such as low conductivity and poor chemical stability during the application of ion membranes.Taking advantage of the good properties and surface modification of inorganic materials,the introduction of inorganic materials into the ion exchange membrane matrix is an effective method.Carbon nanomaterials have the characteristics of controllable size,large specific surface,and environmental friendliness.They are a class of excellent inorganic fillers.In order to prepare high-performance ion exchange membranes,the preparation types and applications of low-dimensional carbon nanomaterials doped ion exchange hybrid membranes in recent years were reviewed.It was pointed out that different low-dimensional carbon nanomaterials were used in the preparation of ion exchange hybrid membranes.Facing problems,and looking forward to the future research directions for improving the performance of ion exchange hybrid membranes.
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基金资助
国家自然科学基金(21878118;21978109)
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