荧光UiO-66系列功能材料的设计与应用

陈隆1, 胡丹1, 魏振2, 冯旭东1*, 任小敏1, 刘烨1

化工新型材料 ›› 2022, Vol. 50 ›› Issue (6) : 7 -13.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (6) : 7-13. DOI: 10.19817/j.cnki.issn1006-3536.2022.06.002
综述与专论

荧光UiO-66系列功能材料的设计与应用

    陈隆1, 胡丹1, 魏振2, 冯旭东1*, 任小敏1, 刘烨1
作者信息 +

Design and application of fluorescence UiO-66 series functional material

  • Chen Long1, Hu Dan1, Wei Zhen2, Feng Xudong1, Ren Xiaomin1, Liu Ye1
Author information +
文章历史 +
PDF

摘要

发光金属有机骨架(LMOFs)由于具有特定功能的金属位点、Lewis酸性/碱性位点、可修饰的多齿有机配体,以及丰富的π-π*电子跃迁系统,在荧光领域具有惊人的潜力。拥有良好热稳定性、化学稳定性、结构可修饰性的荧光UiO-66系列功能材料(UiO-66-Type)在荧光检测、药物递送、荧光生物成像等应用中表现出高灵敏性、高选择性、低信噪比、可回收利用等特点,具有传统荧光材料不可比拟的优势,以具有低荧光强度的UiO-66为出发点,分析并总结了各种功能化UiO-66-Type构筑荧光的策略,在构筑荧光策略的基础上对其在荧光领域的应用和存在的问题进行总结并展望,为各位读者提供新的思路和理论支撑。

Abstract

Luminescent Metal-organic Frameworks (LMOFs) have specific functions due to its metal sites,Lewis acid/basic sites,modifiable multidentate organic ligands,and abundant π-π* electronic transition systems,and have amazing potential in the field of fluorescence.A series of fluorescent UiO-66 functional materials (UiO-66-Type) with good thermal stability,chemical stability,and structural modifiable properties shown the high sensitivity,low signal noise,recyclability,and etc.in fluorescence detection,drug delivery and delivery,fluorescent biological imaging and other applications.Fluorescence UiO-66-Type had incomparable advantages than traditional fluorescent materials.The UiO-66-Type with low fluorescence intensity was taken as the starting point,analyzed and summarized the construction of various functional UiO-66-Type fluorescence strategies.Based on the construction of fluorescence strategies and its application in the field of fluorescence,the existing problems were summarized and prospected to provide readers with new ideas and theoretical support.

关键词

LMOFs / UiO-66 / 荧光复合材料 / 功能化 / 应用进展

Key words

LMOFs / UiO-66 / luorescent composite / functionalization / application progress

引用本文

引用格式 ▾
荧光UiO-66系列功能材料的设计与应用[J]. 化工新型材料, 2022, 50(6): 7-13 DOI:10.19817/j.cnki.issn1006-3536.2022.06.002

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Sun Y,Xu X,Zhao Y,et al.Luminescent metal organic frameworks-based chemiluminescence resonance energy transfer platform for turn-on detection of fluoride ion[J].Talanta,2020,209:120582.
[2] Cavka J H,Jakobsen S,Olsbye U,et al.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J].Journal of the American Chemical Society,2008,130(42):13850-13851.
[3] Dong J,Zhang X D,Xie X F,et al.Amino group dependent sensing properties of metal-organic frameworks:selective turn-on fluorescence detection of lysine and arginine[J].RSC Advances,2020,10(61):37449-37455.
[4] 刘丽丽.金属有机框架化合物NH2-UiO-66和Eu/Zr-MOFs的合成、结构及对有机小分子和F-离子的荧光传感作用[D].上海:上海师范大学,2016.
[5] Ruan B,Liu H L,Zhan X Q,et al.Effect of transition metal ions on luminescence of MOFs[J].MATEC Web of Conferences,2018,238:5004.
[6] Li Y P,Zhu X H,Li S N,et al.Highly selective and sensitive turn-off-on fluorescent probes for sensing Al3+ ions designed by regulating the excited-state intramolecular proton transfer process in metal-organic frameworks[J].ACS Applied Materials & Interfaces,2019,11(12):11338-11348.
[7] Du T,Jiang H,Wang X M.The effect of AIE and ACQ on MOFs' sensing performance[J].Inorganic Chemistry Communications,2019,107:107452.
[8] 殷雪梅.基于金属有机框架限域指示剂位移的荧光开启响应[D].上海:华东师范大学,2020.
[9] Zhu H,Huang J,Zhou Q,et al.Enhanced luminescence of NH2-UiO-66 for selectively sensing fluoride anion in water medium[J].Journal of Luminescence,2019,208:67-74.
[10] Zhu S Y,Yan B.Highly sensitive luminescent probe of aniline and trace water in organic solvents based on covalently modified lanthanide metal-organic frameworks[J].Industrial & Engineering Chemistry Research,2018,57(49):16564-16571.
[11] Hu Z G,Peng Y W,Kang Z X,et al.A modulated hydrothermal (MHT) approach for the facile synthesis of UiO-66-Type MOFs[J].Inorganic Chemistry,2015,54(10):4862-4868.
[12] Morris W,Doonan C J,Yaghi O M.Postsynthetic modification of a metal-organic framework for stabilization of a hemiaminal and ammonia uptake[J].Inorganic Chemistry,2011,50(15):6853-6855.
[13] Islamoglu T,Goswami S,Li Z Y,et al.Postsynthetic tuning of metal-organic frameworks for targeted applications[J].Accounts of Chemical Research,2017,50(4):805-813.
[14] Wang J H,Zhang Y,Li M,et al.Solvent-assisted metal metathesis:a highly efficient and versatile route towards synthetically demanding chromium metal-organic frameworks[J].Angewandte Chemie International Edition,2017,56(23):6478-6482.
[15] Campanelli M,Giacco T D,Angelis F D,et al.A solvent free synthetic route for cerium(Ⅳ) metal-organic frame-works with UiO-66 architecture and their photocatalytic application[J].Photocatalysis with Cerium based Metal Organic Frameworks,2019,11(48):45031-45037.
[16] 宫福昕.电化学法合成UIO-66-NH2及荧光检测性能研究[D].哈尔滨:哈尔滨理工大学,2019.
[17] Du Y,Li X,Lv X,et al.Highly sensitive and selective sensing of free bilirubin using metal-organic frameworks-based energy transfer process[J].ACS Applied Materials & Interfaces,2017,9(36):30925-30932.
[18] Wei J,Gong F,Sun X,et al.Rapid and low-cost electrochemical synthesis of UiO-66-NH2 with enhanced fluorescence detection performance[J].Inorganic Chemistry,2019,58(10):6742-6747.
[19] Hao J N,Yan B.A water-stable lanthanide-functionalized MOF as a highly selective and sensitive fluorescent probe for Cd2+[J].Chemical Communications,2015,51(36):7737-7740.
[20] Xu X Y,Yan B.Eu(Ⅲ) functionalized Zr-based metal-organic framework as excellent fluorescent probe for Cd2+ detection in aqueous environment[J].Sensors and Actuators B:Chemical,2016,222:347-353.
[21] Tang Y,Chen J,Wu H,et al.A highly fluorescent post-modified metal organic framework probe for selective,reversible and rapid carbon dioxide detection[J].Dyes and Pigments,2020,172:107798.
[22] Sk M,Nandi S,Singh R K,et al.Selective sensing of peroxynitrite by HF-based UiO-66-B(OH)2 metal-organic framework:applicability to cell imaging[J].Inorganic Chemistry,2018,57(16):10128-10136.
[23] Gao N,Huang J,Wang L Y,et al.Ratiometric fluorescence detection of phosphate in human serum with a metal-organic frameworks-based nanocomposite and its immobilized agarose hydrogels[J].Applied Surface Science,2018,459:686-692.
[24] Sun Z,Ling Y,Liu S G,et al.Metal-organic framework as a chemosensor based on luminescence properties for monitoring cetyltrimethylammonium bromide and its application in smartphones[J].Inorganic Chemistry,2019,58(13):8388-8395.
[25] 魏来,涂小进,徐宗,等.荧光碳点及其水凝胶的研究进展[J].化工新型材料,2020,48(2):232-236.
[26] Yang J M,Hu X W,Liu Y X,et al.Fabrication of a carbon quantum dots-immobilized zirconium-based metal-organic framework composite fluorescence sensor for highly sensitive detection of 4-nitrophenol[J].Microporous and Mesoporous Materials,2019,274:149-154.
[27] Wu J,Yan B.Visible detection of copper ions via fluorescent probe based on red carbon dots and zirconium metal-organic frameworks[J].Dalton Transactions,2017,46(43):15080-15086.
[28] Wang W,Wang L,Liu S,et al.Metal-organic frameworks@polymer composites containing cyanines for near-infrared fluorescence imaging and photothermal tumor therapy[J].Bioconjugate Chemistry,2017,28(11):2784-2793.
[29] 张艺.荧光探针在芳香类爆炸物检测中的研究进展[J].化工新型材料,2017,45(2):22-24.
[30] Zhu S Y,Yan B.A novel sensitive fluorescent probe of S2O2-8 and Fe3+ based on covalent post-functionalization of zirconium(Ⅳ) metal-organic framework[J].Dalton Transactions,2018,47(33):11586-11592.
[31] Nandi S,Biswas S.A diamino functionalized metal-organic framework for fluorometric recognition of free chlorine in environmental water samples[J].Microporous and Mesoporous Materials,2020,299:110116.
[32] Zhao X,Wang Y,Hao X,et al.Fluorescent molecule incorporated metal-organic framework for fluoride sensing in aqueous solution[J].Applied Surface Science,2017,402:129-135.
[33] Wang Q,Du X M,Zhao B,et al.A luminescent MOF as a fluorescent sensor for the sequential detection of Al3+ and phenylpyruvic acid[J].New Journal of Chemistry,2020,44(4):1307-1312.
[34] Takeuchi M,Takahashi T,Shodo R,et al.Comparison of autofluorescence with near-infrared fluorescence imaging between primary and secondary hyperparathyroidism[J].The Laryngoscope,2021,131(6):E2097-E2104.
[35] Zhang W,Wang X,Li P,et al.Evaluating hyperthyroidism-induced liver injury based on in situ fluorescence imaging of glutathione and phosphate via nano-MOFs sensor[J].Analytical Chemistry,2020,92(13):8952-8958.
[36] Zhu S,Wang S,Xia M,et al.Intracellular imaging of glutathione with MnO2 nanosheet@Ru(bpy)2+3-UiO-66 nanocomposites[J].ACS Applied Materials & Interfaces,2019,11(35):31693-31699.
[37] Wang L,Wang W,Zheng X,et al.Nanoscale fluorescent MOF@microporous organic polymers composites for enhanced intracellular uptake and bioimaging[J].Chemistry-A European Journa,2017,23(6):1379-1385.
[38] Tabatabaeian K,Simayee M,Fallah-Shojaie A,et al.N-doped carbon nanodots@UiO-66-NH2 as novel nanoparticles for releasing of the bioactive drug,rosmarinic acid and fluorescence imaging[J].DARU Journal of Pharmaceutical Sciences,2019,27(1):307-315.
[39] Fajal S,Samanta P,Dutta S,et al.Selective and sensitive recognition of Fe3+ ion by a Lewis basic functionalized chemically stable metal-organic framework (MOF)[J].Inorganica Chimica Acta,2020,502:119359.
[40] Tang Y L,Wu H F,Chen J M,et al.A highly fluorescent metal organic framework probe for 2,4,6-trinitrophenol detection via post-synthetic modification of UiO-66-NH2[J].Dyes and Pigments,2019,167:10-15.
[41] Zhang X,Hu Q,Xia T,et al.Turn-on and ratiometric luminescent sensing of hydrogen sulfide based on metal-organic frameworks[J].ACS Applied Materials & Interfaces,2016,8(47):32259-32265.
[42] Govindaraju S,Puthiaraj P,Lee M H,et al.Photoluminescent AuNCs@UiO-66 for ultrasensitive detection of mercury in water samples[J].ACS Omega,2018,3(9):12052-12059.
[43] Das A,Das S,Trivedi V,et al.A dual functional MOF-based fluorescent sensor for intracellular phosphate and extracellular 4-nitrobenzaldehyde[J].Dalton Transactions,2019,48(4):1332-1343.
[44] Yu H,Liu C,Li Y,et al.Functionalized metal-organic framework UiO-66-NH-BQB for selective detection of hydrogen sulfide and cysteine[J].ACS Applied Materials & Interfaces,2019,11(45):41972-41978.
[45] Tabatabaeian K,Simayee M,Fallah-Shojaie A,et al.N-doped carbon nanodots@UiO-66-NH2 as novel nanoparticles for releasing of the bioactive drug,rosmarinic acid and fluorescence imaging[J].DARU Journal of Pharmaceutical Sciences,2019,27(1):307-315.
[46] Chen J,Chen H,Wang T,et al.Copper ion fluorescent probe based on Zr-MOFs composite material[J].Analytical Chemistry,2019,91(7):4331-4336.
[47] Jia L,Guo S,Xu J,et al.A ratiometric fluorescent nano-probe for rapid and specific detection of tetracycline residues based on a dye-doped functionalized nanoscaled metal-organic framework[J].Nanomaterials,2019,9(7):976.

基金资助

科技创新服务能力建设-基本科研业务费(PXM2020-014213-000017);2020年研究生科研能力提升计划项目(19008020144);国家科技支撑计划(2014BAC28B01)

AI Summary AI Mindmap
PDF

962

访问

0

被引

导航
相关文章

AI思维导图

/