氧化石墨烯/生物基壳聚糖复合材料的制备及研究

梁姣利

化工新型材料 ›› 2022, Vol. 50 ›› Issue (4) : 188 -190.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (4) : 188-190. DOI: 10.19817/j.cnki.issn1006-3536.2022.04.038
科学研究

氧化石墨烯/生物基壳聚糖复合材料的制备及研究

    梁姣利
作者信息 +

Preparation and research of GO/CS bio-based composite

  • Lang Jiaoli
Author information +
文章历史 +
PDF

摘要

通过氧化法制备了氧化石墨烯(GO),将GO与壳聚糖(CS)混合制备了GO/CS复合材料,并通过 FT-IR、XRD、TGA和力学实验对其结构、热力学稳定性及力学性能进行测试。测试结果表明,GO被成功制备;GO上的—COOH与CS上的—NH2发生酰胺反应生成—NHCO—,形成较强的界面结合力,GO的加入改善了CS的热稳定性,并且拉伸强度和杨氏模量均有所提高。

Abstract

Graphene oxide(GO) was prepared by oxidation method,and prepared GO/chitosan(CTS) bio-based composite by mixing GO withCTS.Its structure and thermodynamic stability were tested through IR,XRD,TGA.And the mechanical properties were tested.GO test results shown that GO was successfully prepared.Composite material test results shown that —COOH on GO reacted with —NH2 on CTS to form —NHCO— which was a strong interface bond.The addition of GO improved the thermal stability of CTS,and improved the tensile strength and Young's modulus.

关键词

氧化石墨烯 / 壳聚糖 / 复合材料

Key words

graphene oxide / chitosan / composite material

引用本文

引用格式 ▾
氧化石墨烯/生物基壳聚糖复合材料的制备及研究[J]. 化工新型材料, 2022, 50(4): 188-190 DOI:10.19817/j.cnki.issn1006-3536.2022.04.038

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 曹小倩,王新威,王新灵,等.基于氧化石墨烯的锂硫电池用聚乙烯隔膜的改性[J].功能高分子学报,2017,30(3):341-346.
[2] Bi H C,Xie X,Yin K B,et al.Graphene:spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents[J].Advanced Functional Materials,2012,22(21):4421-4425.
[3] Zhang X P,Liu D,Yang L,et al.Self-assembled three-dimensional graphene-based materials for dye adsorption and catalysis[J].Journal of Materials Chemistry A,2015,3(18):10031-10037.
[4] Krieger R I,Dinoff T M.Malathion deposition,metabolite clearance,and cholinesterase status of date dusters and harvesters in California[J].Arch Environ Contam Toxicol,2000,38(4):546-553.
[5] Macquarrie D J,Hardy J J E.Applications of functionalized chitosan in catalysis[J].Ind Eng Chem Res,2005,44(23):8499-8520.
[6] Kumar M,Kumar M,Majeti N,et al.Review:a review of chitin and chitosan applications[J].Chemical Reviews,2000,36(11):6017-6084.
[7] 魏燕红,孙芙蓉,杨季雨,等.轻质可压缩壳聚糖/石墨烯复合气凝胶的制备与性能[J].高分子材料科学与工程,2018,34(5):149-154.
[8] Han D,Yan L.Supramolecular hydrogel of chitosan in the presence of graphene oxide nanosheets as 2D cross-linkers[J].ACS Sustainable Chemistry & Engineering,2013,2(2):296-300.
[9] Yang X,Zhang X,Ma Y,et al.Superparamagnetic graphene oxide-Fe3O4 nanoparticles hybrid for controlled targeted drug carriers[J].Journal of Materials Chemistry,2009,19(18):2710-2714.
[10] 魏燕红,孙芙蓉,杨季雨,等.轻质可压缩壳聚糖/石墨烯复合气凝胶的制备与性能[J].高分子材料科学与工程,2018,34(5):149-154.
[11] Marcano D C,Kosynkin D V,Berlin J M,et al.Correction to improved synthesis of graphene oxide[J].ACS Nano,2018,12(2):2078-2078.
[12] Marcano D C,Kosynkin D V,Berlin J M,et al.Improved synthesis of graphene oxide[J].ACS Nano,2010,4(8):4806-4814.
[13] 赵茜,邱东方,王晓燕,等.壳聚糖/氧化石墨烯纳米复合材料的形态和力学性能研究[J].化学学报,2011,69(10):1259-1263.
[14] Li S D,Zhang C H,Dong J J,et al.Effect of cupric ion on thermal degradation of quaternized chitosan[J].Carbohydrate Polymers,2010,81(2):182-187.
[15] López F A,Mercê A L R,Alguacil F J,et al.A kinetic study on the thermal behaviour of chitosan[J].Journal of Thermal Analysis & Calorimetry,2008,91(2):633-639.
[16] Chrissafis K,Paraskevopoulos K M,Pavlidou E,et al.Thermal degradation mechanism of HDPE nanocomposites containing fumed silica nanoparticles[J].Thermochimica Acta,2009,485(1-2):65-71.
[17] 陈元庆,张大伟,顾继友.功能化氧化石墨烯/壳聚糖纳米复合材料的制备及力学性能研究[J].材料导报B,2015,29(6):71-75.

基金资助

伊犁师范大学污染物化学与环境治理重点实验室开放课题(2017HJYB10)

AI Summary AI Mindmap
PDF

634

访问

0

被引

导航
相关文章

AI思维导图

/