通过对几种性能较差的光催化材料进行复合来增加其催化性能是当前研究的主流,介绍了复合催化剂的研究现状,总结分析了复合催化剂的制备方法、应用及存在的问题,为今后制备性能更好的复合催化剂材料提供理论依据。
The mainstream of the current study on composite catalyst are compound several photocatalytic materials with performance poor to increase its catalytic performance.The current research status were introduced.The preparation method,the application and existing problems of the composite catalysts were analyzed and summarized.And for the future preparation of composite catalyst materials with better performances provided theoretical basis.
[1] Dong J Z,Ye J Z,Dessy A,et al.Enhancing photocatalytic activities of titanium dioxide via well-dispersed copper nanoparticles[J].Chemosphere,2018,204:193-201.
[2] Md T I,Jing H K,Yang T,et al.Fullerene stabilized gold nanoparticles supported on titanium dioxide for enhanced photocatalytic degradation of methyl orange and catalytic reduction of 4-nitrophenol[J].Journal of Environmental Chemical Engineering,2018,6(4):3827-3836.
[3] Liu B,Liu Sh,Meng L Y,et al.Microwave-hydrothermal synthesis and photocatalytic properties of biomass charcoal/TiO2 nanocomposites[J].Journal of Saudi Chemical Society.2018,22(5):509-518.
[4] Pardon N,Lilian T,Omobola O,et al.Visible active gold/carbon co-doped titanium dioxide photocatalytic nanoparticles for the removal of dyes in water[J].Materials Science in Semiconductor Processing,2018,76:25-30.
[5] Song Y F,Chen W,Zhao C C,et al.Metal-free nitrogen-doped mesoporous carbon for electroreduction of CO2 to ethanol[J].Angewandte Chemie International Edition,2017,56(36):10840-10844.
[6] Yan T,Sun M,Liu H Y,et al.Fabrication of hierarchical BiOI/Bi2MoO6 heterojunction for degradation of bisphenol A and dye under visible light irradiation[J].Journal of Alloys and Compounds,2015,634:223-231.
[7] Feng Y,Yan X,Liu C B,et al.Hydrothermal synthesis of CdS/Bi2MoO6 heterojunction photocatalysts with excellent visible-light-driven photocatalytic performance[J].Applied Surface Science,2015,353:87-94.
[8] Li H P,Liu J Y,Hou W G,et al.Synthesis and characterization of g-C3N4/Bi2MoO6 heterojunctions with enhanced visible light photocatalytic activity[J].Applied Catalysis B:Environmental.2014,160-161:89-97.
[9] 樊学萍,赵元娟,张登财.BiOI复合光催化剂的最新研究进展[J].山东大同大学学报,2018,34(1):8-12.
[10] 李远勋,吴林冬,常飞,等.锰锌铁氧体/硫化镉异质结的制备及其光催化降解磺胺甲噁唑的研究[J].化工新型材料,2020,09:202-206.
[11] 刘亚东,徐丽慧,王黎明,等.纳米CuS/RGO复合材料的制备及光催化性能研究[J].化工新型材料,2020,48(11):241-257.
[12] Ekaterina N G,Valeria V S,Yulia N O,et al.Composition and properties of TiO2 sol to produce a photocatalytic composite material[J].Key Engineering Materials,2020,6178:45-50.
[13] Tang Y N,Sun H,Shang Y X,et al.Spiky nanohybrids of titanium dioxide/gold nanoparicles for enhanced photocatalytic degradation and antibacterial property[J].Journal of Colloid And Interface Science,2019,535:516-523.
[14] 杨玉寒,杨小芹,庞军国,等.泡沫材料负载TiO2光催化剂的研究进展[J].化工新型材料,2020,49(11):294-299.
[15] 杨尚志,李海帅,牛作吉,等.TiO2基多元复合材料的合成及其对MPB的光催化降解性能研究[J].化工新型材料,2020,48(11):122-126.
[16] Shi H Y,Li N,Sun Zh X,et al.Interface mdification of titanium dioxide nanoparticles by titanium-substituted polyoxometalate doping for improvement of photoconductivity and gas sensing applications[J].Journal of Physics and Chemistry of Solids,2018,120:57-63.
[17] Green M,Liu Z,Smedley R,et al.Graphitic carbon nitride nanosheets for microwave absorption[J].Materials Today Physics,2018,5:78-86.
[18] Huang H W,Xiao K,He Y,et al.In situ assembly of BiOI@Bi12O17Cl2 p-n junction:charge induced unique front-lateral surfaces coupling heterostructure with high exposure of BiOI {001} active facets for robust and nonselective photocatalysis[J].Applied Catalysis B:EnvironmentalVolume,2016,199:75-86.
[19] Zuzana B,Eva P,Monika M,et al.N-doped titanium dioxide nanosheets:preparation,characterization and UV/visibl-light activity[J].Applied Catalysis B:Environmental,2018,232:397-408.
[20] Riccardo P,Dario B,MariaPia P,et al.Self-cleaning building materials:the multifaceted efects of titanium dioxide[J].Construction and Building Materials,2018,182:126-133.
[21] 邹秋林.BiVO4/石墨烯复合光催化剂制备及光催化活性[D].重庆:重庆大学,2015.
[22] 刘乃亮,庞波,理莎莎,等.BiVO4/rGO的水热控制合成及其光催化性能研究[J].功能材料,2017,10:10077-10081.
[23] 覃涛.钒酸铋/石墨烯复合光催化剂的制备及性能研究[D].长沙:中南大学,2014.
[24] Sun Y F,Qu B Y,Liu Q,et al.Highly efficient visible-light-driven photocatalytic activities in synthetic ordered monoclinic BiVO4 quantum tubes-graphene nanocomposites[J].Nanoscale,2012,12(4):3761-7.
[25] Wu H,Sun J X,Qi D X,et al.Photocatalytic removal of elemental mercury from flue gas using multi-walled carbon nanotubes impregnated with titanium dioxide[J].Fuel,2018,230:218-225.
[26] 钱晓峰,褚有群,李照华,等.MnOx/CNT的制备及其对氧还原反应的电催化性能研究[J].浙江工业大学学报,2012,40(4):365-368.
[27] 周阳,刘委明,胡仙超,等.纳米三氧化钨复合催化剂的制备及对甲醇电催化性能[J].物理化学学报,2013,29(7):1487-1493.
[28] 周阳,褚有群,刘委明,等.纳米三氧化钨修饰碳纳米管载铂催化剂对甲醇氧化的电催化性能[J].物理化学学报,2013,29(2):287-292.
[29] 徐丽,巩学海,盛鹏,等.三维石墨烯/碳纳米管复合材料及其超级电容器应用[J].功能材料,2016,S2:112-115.
[30] 王晓娟,毛信表,李国华,等.WC/TiO2纳米复合材料晶相形成机理及电催化性能[J].化工学报,2016,67(11):4873-4877.
[31] 童少平,沈佟栋,倪金雷,等.金红石TiO2催化臭氧化磺基水杨酸[J].浙江工业大学学报,2015,43(6):591-594.
[32] 范春亚.钒酸盐/石墨烯三维复合气凝胶的制备及其光催化性能研究[D].镇江:江苏大学,2017.
[33] 杨状,高星星,赵通林,等.复合材料BiVO4/ZnO光催化降解废水中的丁基黄药[J].金属矿山,2017,493(7):173-177.
[34] 汪银洲.可见光响应石墨烯铋基半导体复合光催化剂的制备及其性能研究[D].杭州:浙江大学,2015.
[35] 孙鹏程.三维纳米多孔类石墨烯碳材料的制备及其生物传感应用[D].杭州:浙江大学,2018.
[36] 杨晓桐.三维石墨烯复合钴酸铜微米花电极在锂空气电池中的应用[D].杭州:浙江大学,2018.
[37] 周凡琪.石墨烯杂化材料的光催化性能研究[D].上海:上海电力学院,2017.
[38] 杨翩翩,黄丽珍,李影影,等.掺氮碳化钨的制备及其电催化性能的研究[J].电化学,2018,24(1):63-71.
[39] 刘汉水,余夙,童少平,等.电化学氧化和臭氧预处理酸性化工废水的效能研究[J].电化学,2013,19(5):472-476.
[40] 蔡亭伟,丁颖,徐丽慧.三维石墨烯材料在污水处理中的研究进展[J].环境化学,2018,37(6):1282-1292.
[41] 汪珩.镍基纳米粒子修饰的三维石墨烯材料制备及在超级电容器中的应用[D].合肥:中国科学技术大学,2018.
[42] Qin T F,Wan Z Y,Wang Z L,et al.3D flexible O/N Co-doped graphene foams for supercapacitor electrodes with high volumetric and areal capacitances[J].Journal of Power Sources,2016,30(336):455-464.
[43] Huang Z F,Pan L,Zou J J,et al.Nanostructured bismuth vanadate-based materials for solar-energy-driven water oxidation:a review on recent progress[J].Nanoscale,2014,23(6):14044-14063.
[44] Meng F B,Wang H G,Huang F,et al.Graphene-based microwave absorbing composites:a review and prospective[J].Composites Part B:Engineering,2018,137:260-277.
基金资助
张家港市科技计划项目(ZKS1710);国家自然科学基金(52072180);江苏省研究生科研与实践创新计划项目(KYCX21_3461)