Polyaniline (PANI) particles were prepared by using block copolymer polystyrene-b-poly(N-isopropylacrylamide) [PS111-b-PNIPAMx(x=30,60,84)] as template.The size and size distribution of PANI particles were effectively controlled by adjusting the hydrophilic segment length of the template.Structural characterization was done by FT-IR and UV-Vis.The morphology and electrochemical properties of the products were characterized by granularity test,cyclic voltammetry,chronopotentiometry and electrochemical impedance measurements.The results shown that the particle size of PANI was below 145nm and the distribution index was small,indicating that the particle size is uniform.When the hydrophilic segment length of the template was 84,the electrochemical performance of PANI was the best,and the discharge specific capacitance can reach 1117.67F/g at current density of 1A/g.
[1] Van Nguyen A,Christian Kuss.Review—conducting polymer-based binders for lithium-ion batteries and beyond[J].J Electrochem Soc,2020,167:65501.
[2] 赵文元,王亦军.功能高分子材料化学[M].北京:化学工业出版社,1996.
[3] Li Xingui,Huang Meirong,Duan Wei,et al.Novel multifunctional polymers from aromatic diamines by oxidative polymerizations[J].Chemical Review,2002,102(9):2925-3030.
[4] Wang Zilong,Guo Rui,Li Gaoren,et al.Polyaniline nanotube arrays as high-performance flexible electrodes for electrochemical energy storage devices[J].J Mater Chem,2012,22:2401-2404.
[5] Ian Wyman W,Liu Guojun.Micellar structures of linear triblock terpolymers:three blocks but many possiblities[J].Polymer,2013,54(8):1950-1978.
[6] Sanjoy Mondal,Utpal Rana,Sudip Malik.Graphene quantum dot-doped polyaniline nanofiber as high performance supercapacitor electrode materials[J].Chem Commun,2015,51:12365-12368.
[7] 王琳.基于两亲性嵌段共聚物构筑导电聚合物微/纳米结构及其应用[D].乌鲁木齐:新疆师范大学,2019.
[8] 任俊英,安利俊.原位聚合法制备聚苯胺纳米材料及其性能研究[J].化工新型材料,2020,48(4):136-148.
[9] 王琳,张艳慧,阿孜古丽·木尔赛力木,等.pH诱导调节聚联苯胺亚微米棒的形态与性能[J].华东师范大学学报(自然科学版),2019,2019(2):164-173.
[10] Wang Lin,Arzugul Muslim,Dilhumar Turdi,et al.Controllable length adjustment of polyaniline particle with temperature sensitive block copolymer as template[J].Polym Adv Technol,2021,32(1):411-419.
[11] 田晓冬,前田宁.N-异丙基丙烯酰胺共聚物的合成及温敏性[J].高分子材料科学与工程,2010,26(4):29-32.
[12] Vahid Mottaghitalab,Geoffrey Spinks M,Gordon Wallace G.The influence of carbon nanotubes on mechanicaland electrical properties of polyaniline fibers[J].Synth Met,2005,152:77-80.
[13] 王靖,柯少勇,黄贤坤,等.锂离子电池电极颗粒分布对电化学性能影响的分析[J].化工进展,2018,37(7):171-177.
[14] 刘永强,邵水源,杜珣涛.聚苯胺／改性活性炭复合电极材料的制备及其电容性能研究[J].化工新型材料,2020,48(3):91-95.
[15] Zhao Zixin,Arzugul Muslim,Abida Abdunazar,et al.Preparation of polybenzidine submicrorods with controllable morphology using poly (ethylene oxide)-b-polystyrene as a template and its electrochemical properties[J].Journal of Macromolecular Science:Part A,2017,54:727-734.
[16] Balamurugan Devadas,Toyoko Imae.An effect of carbon dots on conducting polymers for energy storage applications[J].ACS Sustain Chem Eng,2018,6:127-134.
[17] Rahul Diggikar S,Deshmukh S P,Tukaram Thopate S,et al.Performance of polyaniline nanofibers (PANI NFs) as PANI NFs-silver (Ag) nanocomposites (NCs) for energy storage and antibacterial applications[J].ACS Omega,2019,4:5741-5749.
[18] 申振,戴亚堂,张欢,等.微孔炭/聚苯胺纳米线复合材料的制备及其电化学电容性能[J].精细化工,2012,29(12):1181-1185;1211.
[19] Shalini Kulandaivalu,Zulkarnain Zainal,Yusran Sulaiman.Influence of monomer concentration on the morphologies and electrochemical properties of PEDOT,PANI,and PPy prepared from aqueous solution[J].International Journal of Ploymer Science,2016,2016:1-12.
[20] Wang Kai,Zhao Pu,Zhou Xiaomo,et al.Flexible supercapacitors based on cloth-supported electrodes of conducting polymer nanowire array/SWCNT composites[J].J Mater Chem,2011,21:16373-16378.
[21] 肖娜,潘洋,宋云,等.锑硅纳米复合薄膜作为钠离子电池负极材料的电化学行为研究[J].无机材料学报,2018,33(5):494-500.
基金资助
国家自然科学基金(51763023)
PDF
