PMMA基复合薄膜的日间辐射制冷特性研究

张帅, 荆为龙, 朱海涛*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (3) : 94 -99.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (3) : 94-99. DOI: 10.19817/j.cnki.issn1006-3536.2022.03.019
新材料与新技术

PMMA基复合薄膜的日间辐射制冷特性研究

    张帅, 荆为龙, 朱海涛*
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Study on the daytime radiant cooling property of PMMA-based composite film

  • Zhang Shua,i Jing Weilong, Zhu Haitao
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摘要

采用静电纺丝法以PMMA为基底,ZnO和ZrO2为添加剂,制备了辐射制冷复合薄膜。并通过自组装测试装置对薄膜的净辐射制冷功率进行测试,探究了无机颗粒对复合薄膜制冷性能的影响。研究结果表明,选择ZrO2为添加剂且添加量为8%(wt,质量分数)时,PMMA复合纺丝薄膜的性能最好。它在太阳光波段的反射率为97.7%,在大气窗口波段的发射率为86.7%。该薄膜在平均617W/m2的太阳强度下显示出低于周边环境温度3.5℃的温差和62.6W/m2的净辐射制冷功率。

Abstract

Radiant cooling composite films were prepared by electrospinning method with polymethyl methacrylate (PMMA) as matrix,ZnO and ZrO2 as additives.The net radiative cooling power of the film was measured by a self-assembly test device.The influence of the inorganic particles on cooling effect was investigated.The results shown that the film exhibited the best radiative cooling property when ZrO2 was selected as the additive,and the addition amount was 8wt%.The reflectance in the solar spectrum was 97.7%,and the emissivity in the sky window was 86.7%.The film shown temperature difference of 3.5℃ lower than the ambient temperature,and net radiative cooling power of 62.6W/m2 under an average solar illumination intensity of 617W/m2.

关键词

辐射制冷 / 静电纺丝 / 二氧化锆 / 反射率 / 净辐射制冷功率

Key words

radiative cooling / electrospinning / ZrO2 / reflectance / net radiative cooling power

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PMMA基复合薄膜的日间辐射制冷特性研究[J]. 化工新型材料, 2022, 50(3): 94-99 DOI:10.19817/j.cnki.issn1006-3536.2022.03.019

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基金资助

国家自然科学基金资助项目(51741206,51872151);山东省自然科学基金(ZR2017MEM004)

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