Fe-BTC@芳纶复合材料的制备及其性能研究

张颖1, 张琳萍1*, 钟毅1, 徐红1, 毛志平1,2,3

化工新型材料 ›› 2022, Vol. 50 ›› Issue (3) : 79 -83.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (3) : 79-83. DOI: 10.19817/j.cnki.issn1006-3536.2022.03.016
新材料与新技术

Fe-BTC@芳纶复合材料的制备及其性能研究

    张颖1, 张琳萍1*, 钟毅1, 徐红1, 毛志平1,2,3
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Preparation and property of Fe-BTC@aramid fabric

  • Zhang Ying1, Zhang Linping1, Zhong Yi1, Xu Hong1, Mao Zhiping1,2,3
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摘要

采用层层自组装的方式在芳纶织物的表面负载金属有机框架材料(MOF)Fe-BTC。通过红外光谱、扫描电镜、能谱分析了Fe-BTC@芳纶的表面形态以及组成结构。并测试了Fe-BTC@芳纶催化双氧水降解异丙隆的性能。结果表明:循环自组装20次的Fe-BTC@芳纶复合材料在双氧水浓度为20mmol/L下,24h可将5mg/L异丙隆完全降解。Fe-BTC@芳纶对大肠杆菌的抑菌率达到了97.4%,表明Fe-BTC@芳纶在水处理和化学防护方面具有潜在的应用前景。

Abstract

Fe-BTC was loaded on the surface of aramid fabric by layer-by-layer self-assembly method.The surface morphology and composition of Fe-BTC@aramid fabric were analyzed by FT-IR,SEM and EDS.The catalytic performance of the fabric in the degradation of isoproton by H2O2 was also tested.The results showed that 5mg/L isoproturon can be completely degraded by the fabric within 24h under the best condition:20 times of assembly cycles,hydrogen peroxide concentration 20mmol/L.The antibacterial rate of the fabric against Escherichia coli reached 97.4%.It indicated that the fabric had potential application prospects in water treatment and chemical protection.

关键词

金属有机框架材料 / 芳纶 / 催化 / 异丙隆

Key words

metal organic framework / aramid / catalysis / isoproton

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Fe-BTC@芳纶复合材料的制备及其性能研究[J]. 化工新型材料, 2022, 50(3): 79-83 DOI:10.19817/j.cnki.issn1006-3536.2022.03.016

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参考文献

[1] Panella B,Hirscher M,Pütter H,et al.Hydrogen adsorption inm etal-organic frameworks:Cu-MOFs and Zn-MOFs compared[J].Advanced Functional Materials,2006,16(4):520-524.
[2] Morris R E,Cejka J.Exploiting chemically selective weakness in solids as a route to new porous materials[J].Nature Chemistry,2015,7(5):381-388.
[3] Kaye Steven S,Dailly Anne,Yaghi Omar M,et al.Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)[J].JACS,2007,129(46):14176.
[4] 赵建波,袁海丰,谢冰,等,基于金属有机框架的催化应用研究进展[J].化工新型材料,2020,48(2):50-54.
[5] Chatterjee A,Jana A K,Basu J K.A novel synthesis of MIL-53(Al)@SiO2:an integrated photocatalyst adsorbent to remove bisphenol a from wastewater[J].New Journal of Chemistry,2020,44(43):18892-18905.
[6] Kholdeeva O A,Skobelev I Y,Ivanchikova I D,et al.Hydrocarbon oxidation over Fe- and Cr-containing metal-organic frameworks MIL-100 and MIL-101-a comparative study[J].Catalysis Today,2014,238:54-61.
[7] Wang D B,Jia F Y,Wang H,et al.Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs[J].Journal of Colloid and Interface Science,2018,519:273-284.
[8] Wang C,Liu C.Decontamination of alachlor herbicide wastewater by a continuous dosing mode ultrasound/Fe2+/H2O2 process[J].Journal of Environmental Sciences,2014,26(6):1332-1339.
[9] 张美云,罗晶晶,杨斌,等.芳纶纳米纤维的制备及应用研究进展[J].材料导报,2020,34(5):5158-5166.
[10] Morawski F D M,Winiarski J P,Maduro De Campos C E,et al.Sensitive simultaneous voltammetric determination of the herbicides diuron and isoproturon at a platinum/chitosan bio-based sensing platform[J].Ecotoxicology and Environmental Safety,2020,206:111181.
[11] 孙纪全,黄星,何健,等.异丙隆降解菌Y57的分离鉴定及其降解特性[J].中国环境科学,2006,26(3):315-319.
[12] Mao Z,Xie R,D Fu,et al.PAN supported Ag-AgBr@Bi20TiO32 electrospun fiber mats with efficient visible light photocatalytic activity and antibacterial capability[J].Separation & Purification Technology,2017,176:277-286.
[13] Liang R W,Chen R,Jing F F,et al.Multifunctional polyoxometalates encapsulated in MIL-100(Fe):highly efficient photocatalysts for selective transformation under visible light[J].Dalton Transactions,2015,44(41):18227-18236.

基金资助

国家自然科学基金(21872025)

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