长余辉发光材料是一种光致发光材料,具有广阔的应用前景。按照基质材料的不同,长余辉发光材料从最初的硫化物基质,逐渐发展形成了几大体系。系统地介绍了长余辉发光材料的分类,给出了各类型发光材料的典型代表,并对掺杂长余辉发光材料的研究历史和现状进行了综述。对各类型掺杂长余辉材料进行了横向和纵向对比,指出了存在的问题和进一步的研究方向,最后对长余辉材料的应用现状进行了简单介绍。
Long afterglow luminescent material is a kind of photoluminescence material,which has broad application prospects.According to the different matrix materials,the materials have gradually developed into several major systems from the initial sulfide system.The classification of the materials was systematically introduced,given the typical representatives of various types of luminescent materials,and summarized the research history and current situation of the materials.The transverse and longitudinal comparison of different types of the materials were made.The existing problems and further research directions were pointed out.Finally,the application status of the materials was briefly introduced.
[1] 储志强,刘东华,周康宁,等.碱土铝酸盐长余辉发光材料的研究进展与发展方向[J].金属材料与冶金工程,2019(1):27-32.
[2] 赵永旺.稀土掺杂纳米硅铝酸盐长余辉发光材料的制备与性能研究[D].北京:北京科技大学,2018.
[3] Zhao C L,Chen D H,Yuan Y H,et al.Synthesis of Sr4Al14O25∶Eu2+,Dy3+ phosphornanometer powders by combustion processes and its optical properties [J].Materials Science and Engineering,2006,133(22):200-204.
[4] 刘应亮,雷炳富,邝金勇,等.长余辉发光材料研究进展[J].无机化学学报,2009,25(8):1323-1329.
[5] 黄维超.长余辉发光材料的合成及性能研究[D].贵州:贵州大学,2018.
[6] Liu W,Cui R R,Deng C Y.Synthesis and luminescence properties of a novel near-infrared super-long afterglow material of Zn3Ga4GexO9+2x∶1%Cr3+[J].Journal of Optoelectronics Laser,2016,27(2):150-155.
[7] 李金磊.近红外长余辉纳米探针在体外检测肿瘤细胞中的应用[D].福建:华侨大学,2015.
[8] 闫武钊.超长红外长余辉材料及其发光机理的研究和探索[D].安徽:中国科学技术大学,2010.
[9] 申凤娟,夏继宏,程正富.长余辉荧光粉的研究进展[J].中国照明电器,2016(11):9-15.
[10] Bhargava R N,Gallagher D,Hong X,et al.Optical properties of manganese-doped nanocrystals of ZnS[J].Physical Review Letters,1994,72(3):416.
[11] Khalid A H,Kontis K.Thermographic phosphors for high temperature measurements:principles,current state of the art and recent applications[J].Sensors,2008,8(9):5673-5744.
[12] Sharma G,Lochab S P,Singh N.Investigation of thermoluminescence characteristics of CaSrS:Ce nanophosphors[J].Physica B:Condensed Matter,2010,405(21):4526-4529.
[13] Jiang W W,Zheng X,Zhang X Y,et al.Spectral characteristics of optical storage material CaSrS∶Eu,Sm[J].Materials Letters,2007,61(4):1042-1045.
[14] 李蕾.Ge4+/Cr3+掺杂ZnGa2O4的发光和光催化性能研究[D].广东:广东工业大学,2016.
[15] 沈冬冬.SrAl2O4∶(Eu2+,Dy3+)长余辉材料的制备及其性能研究[D].浙江:杭州电子科技大学,2014.
[16] Wang M W,Fu X F,Liao C S,et al.Synthesis and opti-cal properties of ZnS∶Cu(Ⅱ) nanoparticles[J].Solid State Communications,2000,115(9):493-496.
[17] 龚新勇.长余辉材料制备及性能研究[D].贵州:贵州大学,2018.
[18] 葛杏心,孙艳辉,刘聪,等.稀土蓝色光致发光材料研究进展[J].稀土,2019,30(1):80-85.
[19] 孙运亮,庞茂龙,王宁.ZnS基发光陶瓷釉的研制及发光机理探讨[J].山东陶瓷,2002,25(3):23-24.
[20] 赵永旺.稀土掺杂纳米硅铝酸盐长余辉发光材料的制备与性能研究[D].北京:北京科技大学,2018.
[21] 闺武钊.超长红外长余辉材料及其发光机理的研究和探索[D].合肥:中国科学技术大学,2010.
[22] 马建琴.Y2O2S∶Dy3+,Mg2+,Ti4+白色长余辉微纳米发光材料的水热制备及性能研究[D].太原:太原理工大学,2015.
[23] 邓瑞平,宋述岩,庞然,等.稀土硫化物的研究进展[J].中国科学:化学,2012(9):1337-1355.
[24] Palill F C,Levine A K,Tomkus M R.Fluorescent properties of alkaline earth aluminates of the type MAl2O4 activated by divalent europium[J].Journal of Electrochemical Society,1968,115(6):642-644.
[25] 肖志国,杨丽馨.多离子激活的碱土铝酸盐光致长余辉发光材料及制造方法[P].中国专利:94117228.7,1996-01-31.
[26] 郭斌,徐杰,陈泳,等.pH值对硅烷偶联剂表面改性稀土长余辉发光材料的影响[J].中国稀土学报,2011,29(5):589-592.
[27] 朱勇.SrAl2O4∶Eu2+,Dy3+长余辉发光材料的制备及表面包覆[D].广州:暨南大学,2009.
[28] 刘兵,黄建国,刘坐镇.稀土掺杂无机长余辉发光材料研究概况[J].材料导报,2013,27:178-182,188.
[29] 王晓欣,林元华.Eu,Dy共添加的Sr2MgSi2O7基长余辉发光材料[J].硅酸盐学报,2002,30(2):216-219.
[30] 姜洪义,陈伟.Sr2MgSi2O7基新型长余辉发光材料的合成与性能[J].武汉理工大学学报,2003,25(11):5-7.
[31] 毛大立,赵莉.纳米Sr2MgSi2O7∶Eu2+,Dy3+的长余辉发光行为[J].无机材料学报,2005,20(1):220-224.
[32] Wang X J,He Z Y,Jia D,et al.Crystal size dependence of the persistent phosphorescence in Sr2ZnSi2O7∶Eu2+,Dy3+[J].Micraelectron J,2005,36(3-6):546.
[33] Aitasalo T,Hölsá J,Kirm M,et al.Persistent lumines-cence and synchrotron radiation study of the Ca2MgSi2O7∶Eu2+,Re3+ materials[J].RadiatMeas,2007,42(4-5):644.
[34] Ding Y L,Zhang Y X,Wang Z Y,et al.Photoluminescence of Eu single doped and Eu/Dycodoped Sr2Al2SiO7 phosphors with long persistence[J].Journal of Luminescence,2009,129:294-299.
[35] Zhou W,Ma X X,Zhang M L,et al.Effect of different RE dopants on phosphorescence properties of Sr2AbSiO7∶Eu2+ phosphors[J].Journal of Rare Earths,2015,33(7):700-705.
[36] Kuang J,Liu Y,Huang L,et al.Blue-emitting long-lasting phosphor,Sr3Al10SiO20∶Eu2+,Ho3+[J].Solid State Commun,2005,136(1):6.
[37] Itoh S,Toki H,Sato Y,et al.The ZnGa2O4 phosphor for low-voltage blue cathodoluminescence[J].Journal of Electrochemical Society,1991,138(5):1509-1512.
[38] Shea L E,Datta R K,Brown J J.Photoluminescence of Mn2+-activated ZnGa2O4 journal of electrochemical society[J].Chemical Physics Letters,1994,141(7):1950-1954.
[39] Dhak P,Gayen U K,Mishra S,et al.Optical emission spectra of chromium doped nanocrystalline zinc gallate[J].Journal of Applied Physics,2009,106(6):063721(1)-063721(6).
[40] Jeong I K,Park H L,Mho S I.Photoluminescence of ZnGa2O4 mixed with InGaZnO4[J].Solid State Communications,1998,108(11):823-826.
[41] Pan Z W,Lu Y Y,Liu F.Sunlight-activated long-persistent luminescence in the near-infrared from Cr3+-doped zinc gallogermanates[J].Nature Materials,2012,11(1):58-63.
[42] Li Y,Zhou S,Li Y,et al.Long persistent and photo-stimulated luminescence in Cr3+ doped Zn-Ga-Sn-O phosphors for deep and reproducible tissue imaging[J].Journal of Materials Chemistry C,2014,2(15):2657-2663.
[43] Liu F,Yan W,Chuang YJ,et al.Photostimulated near-infrared persistent luminescence as a new optical read-out from Cr3+ doped LiGa5O8[J].Scientific Reports,2013,3(3):1554.
[44] Jin Y,Hu Y,Yuan L,et al.Multifunctional near-infrared emitting Cr3+-doped Mg4Ga8Ge2O20 particles with long persistent,photostimulated persistent puminescence and photochromism properties[J].Journal of Materials Chemistry C,2016,4(27):6614-6625.
[45] Yang H M,Shi J X,Gong M L.A novel red emitting phosphor Ca2SnO4∶Eu3+[J].Journal of Solid State Chemistry,2005,178(3):917-920.
[46] Chen Y C,Chang Y H,Tsai B S.Synthesis and the lumi-nescent properties of europium-activated Ca2SnO4 phosphors[J].Optical Materials,2005,27(12):1874-1878.
[47] Liu Z W,Liu Y L.Synthesis and luminescent properties of a new green afterglow phosphor CaSnO3∶Tb[J].Materials Chemistry & Physics,2005,93(1):129-132.
[48] Lei B F,Li B,Zhang H R,et al.Preparation and lumines-cence properties of CaSnO3∶Sm3+ phosphor emitting in the reddish orange region[J].Optical Materials,2007,29(11):1491-1494.
[49] 符史流,柴飞,陈洁,等.Ce4+离子在Ca2SnO4一维结构基质中的电荷迁移光谱研究[J].物理学报,2008(5):3254-3259.
[50] 符史流,柴飞,周涛,等.Ce4+和Eu3+共掺杂的Ca2SnO4发光材料的合成与光谱特性[J].无机化学学报,2009(1):76-80.
[51] 夏民芳.长波长发光材料的制备及发光性能研究[D].甘肃:兰州大学,2018.
[52] 龚新勇.长余辉材料制备及性能研究[D].贵阳:贵州大学,2018.
[53] 陈荀.水热法制备钛酸盐红色长余辉材料及其在陶瓷釉中的应用[D].长沙:湖南师范大学,2012.
[54] Diallo P T,Boutinaud P,Mahiou R,et al.Red luminescence in Pr3+-doped calcium titanates[J].Physica Status Solidi(A),1997,160(1):255-263.
[55] Tang W,Chen D.Photoluminescence properties Pr3+ and Bi3+-codoped CaTiO3 phosphor prepared by a peroxide-based route[J].Materials Research Bulletin,2009,44:836-839.
[56] Holliday K S,Kohlgruber T A,Tran I C,et al.Increased fluorescence intensity in CaTiO3∶Pr3+,phosphor due to NH3,treatmentand Nb co-doping[J].Optical Materials,2016,60:359-365.
[57] Wu Y,Zhao F.Zn-doped CaTiO3∶Eu3+ redphosphors for enhanced photoluminescence in white LED sbysolid-statereaction[J].Luminescence,2016,31(1):152-157.
[58] Noto L L,Pitale S S,Gusowki M A,et al.After glow enhancement with In3+,codoping in CaTiO3∶Pr3+,redphosphor[J].Powder Technology,2013,237(3):141-146.
[59] Cao R,Chen G.Enhanced photoluminescence of CaTiO3∶Sm3+ redphosphors by Na+,H3BO3,added[J].Materials Chemistry＆Physics,2016,171:222-226.
[60] Singh D K,Manam J.Investigation of structural,spectral and photometricproperties of CaTiO3∶Dy3+,nanophosphors for the lighting applications[J].Electronic Materials Letters,2017,13(4):1-10.
[61] Guo H,Chen W,Zeng W,et al.Structure and luminescent properties of a novel yellow super long lasting phosphate phosphor Ca6BaP4O17∶Eu2+,Ho3+[J].Journal of Materials Chemistry C,2015,3(22):5844-5850.
[62] Chermont Q L M D,Chaneac C,seguin J,et al.Nanoprobes with near-infrared persistent luminescence for invivoimaging[J].Proceedings of the National Academy of Sciences of the United States of America,2007,104(22):9266-9271.
[63] 李金磊.近红外长余辉纳米探针在体外检测肿瘤细胞中的应用[D].福建:华侨大学,2015.
[64] 宋春荣,冯蒙丽,蔡玉平,等.新型夜瞄复合荧光材料在步兵轻武器中的应用研究[J].军校工程学院学报,2014,26(2):75-78.
[65] 黄红军,宋春荣,冯蒙丽,等.步兵轻武器新型夜瞄复合荧光材料的性能研究[J].军校工程学院学报,2014,26(3):27-30.
[66] 宋春荣,冯蒙丽,蔡玉平,等.步兵轻武器新型夜瞄复合荧光材料耐腐蚀性能研究[J].装备环境工程,2013,10(4):38-40,51.
基金资助
陆军工程大学基础学科培育基金项目
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