金属有机骨架(MOFs)材料是一种结构可设计、高比表面积的多孔材料,MOFs材料本身存在不同的金属中心和不饱和金属位点,利用MOFs结构特点引入具有催化能力的客体或金属配合物合成MOFs功能性衍生物,这些优势使其在催化领域备受关注。对MOFs材料的分类进行了介绍,综述了溶剂热、扩散、微波、超声等具备代表性的合成方法,重点总结讨论了MOFs材料催化作用和功能化催化作用的研究进展,最后提出MOFs材料及功能化衍生物在催化应用中面临的挑战和发展趋势。
Metal organic framework (MOFs) is a porous material with a designable structure and high specific surface area.The different metal centers and unsaturated metal sites of MOFs materials themselves,the structural characteristics of MOFs are used to introduce catalytically capable guests or metal complexes,and synthesized MOFs functional derivatives.These advantages make it attract attention in the field of catalysis.The classification of MOFs materials were introduced,and summarized several representative synthesis methods such as solvothermal,diffusion,microwave,ultrasound and mechanochemistry.The research progress of MOFs material catalysis and functional catalysis was focused on.Finally,the challenges and evelopment trends of MOFs materials and functionalized derivatives in catalytic applications were proposed.
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基金资助
国家自然科学基金(21702087)
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