为提升沥青的综合性能,采用废食用油对废胶粉进行活化处理,复配丁苯橡胶(SBR)制备复合改性沥青。采用响应面法中的Box-Behnken设计方法,分别对不同掺量废食用油、废胶粉、SBR制备的复合改性沥青进行三大指标和135℃旋转黏度性能测试,利用灰关联分析对沥青的性能进行综合评价,建立关联度的响应面数学模型,得出各改性剂的最优掺量。结果表明,选用响应面法-灰关联分析可以很好地对沥青改性剂的掺量进行优化;当废食用油掺量为10%、废胶粉掺量为10%、SBR掺量为5%时,制得的复合改性沥青综合性能最优,且关联度的预测值与实际值相对误差仅为2.45%,拟合程度较高。
In order to improve the comprehensive performance of asphalt,waste cooking oil was used to activate the waste crumb rubber and compounded with butadiene styrene rubber(SBR) to prepare composite modified asphalt.The Box-Behnken design method in the response surface methodology was selected to test and analyzed the three major indicators of asphalt and the rotational viscosity at 135°C.The correlation degree in the grey relation analysis was used to comprehensively evaluate the performance of the asphalt to establish a response surface with correlation degree mathematical model,thereby obtaining the optimal dosage of each modifier.The results showed that the selection of response surface methodology-grey relation analysis could optimize the content of asphalt modifiers.The optimal content of modifiers for the asphalt were:10% waste cooking oil,10% waste crumb rubber,5% SBR,the relative error between the predicted value and the actual value of the correlation degree was 2.45%,which showed a high degree of fit.
[1] 张正一,王朝辉,张廉,等.中国绿色公路建设与评估技术[J].长安大学学报(自然科学版),2018,38(5):76-86.
[2] Dong R K,Zhao M Z.Research on the pyrolysis process of crumb tire rubber in waste cooking oil[J].Renewable Energy,2018,125:557-567.
[3] Ji J,Yao H,Suo Z,et al.Effectiveness of vegetable oils as rejuvenators for aged asphalt binders[J].Journal of Materials in Civil Engineering,2016,29(3).https://doi.org/10.1061/(ASCE)MT.1943-5533.0001769.
[4] 方烁,张广泰,叶奋.植物油活化胶粉沥青流变及微观性能研究[J].公路工程,2018,43(4):116-119,132.
[5] Xu M Z,Liu J J,Li W Z,et al.Novel method to prepare activated crumb rubber used for synthesis of activated crumb rubber modified asphalt[J].Journal of Materials in Civil Engineering,2014,27(5),https://doi.org/10.1061/(ASCE)MT.1943-5533.0001115.
[6] 马峰,李晓彤,傅珍.生物油改性橡胶沥青及其混合料性能研究进展[J].武汉理工大学学报,2015,37(2):55-62.
[7] Liang P,Liang M,Fan W Y,et al.Improving thermo-rheological behavior and compatibility of SBR modified asphalt by addition of polyphosphoric acid (PPA)[J].Construction and Building Materials,2017,139:183-192.
[8] 丛玉凤,唐东,黄玮,等.新型丁苯橡胶复合改性沥青的制备及性能分析[J].化工新型材料,2018,46(2):268-271.
[9] 马艳红,陆江银,胡子昭,等.响应面法优化制备戊烯/辛烯/十二烯共聚物减阻剂[J].化工学报,2017,68(5):2195-2203.
[10] 邱颖,朱玲,孙晓英.星点设计-效应面优化法与正交设计和均匀设计的比较及其在药剂研究中的应用[J].海峡药学,2011,23(2):18-20.
[11] 王淋,郭乃胜,温彦凯,等.几种改性沥青疲劳破坏评价指标及性能研究[J].土木工程学报,2020,53(1):118-128.
[12] 肖飞鹏,宗启迪,陈军,等.离子体微表处理胶粉改性沥青工艺条件优化分析[J].中国公路学报,2019,32(4):170-176.
[13] 交通运输部公路科学研究院.JTG E20—2011公路工程沥青及沥青混合料实施规程[S].北京:人民交通出版社,2011:1-373.
[14] 何东坡,王浩.汽油活化橡胶粉制备的橡胶沥青路用性能研究[J].中外公路,2013,33(4):288-291.
[15] 何东坡,马明洋.改性生物沥青耐老化性能研究[J].公路工程,2019,44(1):193-197.
[16] 牛冬瑜,马英新,仁乾龙珠,等.加工参数对地沟油/废旧橡胶粉复合改性沥青性能的影响[J].江苏大学学报(自然科学版),2018,39(3):355-361.
[17] 薛哲,乔云雁,宋莉芳,等.橡胶沥青制备工艺参数及改性机理研究[J].筑路机械与施工机械化,2017,34(2):90-95.
[18] 杨国明,李昊,陈松,等.丁苯橡胶含量对改性沥青高低温性能影响的研究[J].化工新型材料,2019,47(6):248-251,256.
[19] 许晓辉,白波,丁晨旭,等.响应面法优化HB/PAA复合高吸水性材料的制备[J].化工新型材料,2015,43(8):83-86.
[20] 郭学东,林雪纯,马桂荣,等.基于响应曲面法的炭黑/硅烷偶联剂复合改性沥青路用性能[J].科学技术与工程,2018,18(31):218-223.
[21] 王谦,张宏波,戴丽雅,等.响应面法优化亚氯酸钠湿法脱硝工艺的研究[J].现代化工,2017,37(1):151-154.
基金资助
国家自然科学基金(51708092);中国博士后科学基金资助项目(2018M631894)