钨酸盐材料是重要的无机功能材料。对钨酸盐材料的研究进展进行了综述,介绍了高温固相法、水热法、溶剂热法、微波水热法、共沉淀法、溶胶-凝胶法、燃烧法、喷雾热解法等多种合成钨酸盐材料的方法,并对各种制备方法的特点进行了归纳和总结。同时,概述了钨酸盐材料在太阳能电池、照明和显示、储氢材料、温度传感器以及光催化材料等领域的应用情况。
Tungstate materials are an important class of inorganic functional materials.The research progress of tungstate materials was reviewed.The various synthetic methods for tungstate materials,including high temperature solid phase method,hydrothermal method,solvothermal method,microwave hydrothermal method,co-precipitation method,sol-gel method,combustion method and spray pyrolysis method were introduced.The characteristics of each synthesis method were also analyzed and summarized.At the same time,the research progress of tungstate materials in emerging fields such as solar cells,lighting and display,hydrogen storage materials,temperature sensor and photocatalytic materials were summarized.
[1] 赵中伟,孙丰龙,杨金洪,等.我国钨资源技术和产业发展现状与展望[J].中国有色金属学报,2019,29(9):1902-1916.
[2] 袁博,孙立楠,王国平,等.我国钨产业现状及战略储备思考[J].中国钨业,2019,34(2):74-77.
[3] Pourmortazavi S M,Rahimi-Nasrabadi M,Khalilian-Shalamzari M,et al.Synthesis,structure characterization and catalytic activity of nickel tungstate nanoparticles[J].Applied Surface Science,2012,263:745-752.
[4] Garadkar K M,Ghule L A,Sapnar K B,et al.A facile synthesis of ZnWO4 nanoparticles by microwave assisted technique and its application in photocatalysis[J].Materials Research Bulletin,2013,48(3):1105-1109.
[5] Dhiaf M,Megdiche Borchani S,Gargouri M,et al.Temperature-dependent impedance spectroscopy of monovalent double tungstate oxide[J].Journal of Alloys and Compounds,2018,767:763-774.
[6] Kloprogge J T,Weier M L,Duong L V,et al.Microwave-assisted synthesis and characterisation of divalent metal tungstate nanocrystalline minerals:ferberite,hübnerite,sanmartinite,scheelite and stolzite[J].Materials Chemistry and Physics,2004,88(2/3):438-443.
[7] Ben Bacha F,Megdiche Borchani S,Dammak M,et al.Optical and complex impedance analysis of double tungstates of mono- and trivalent metals for LiGd(WO4)2 compound[J].Journal of Alloys and Compounds,2017,712:657-665.
[8] Xiao W Q,Yin L Q,Zhou J P,et al.Influence of reaction parameters on the luminescence properties of monodisperse NaGd(1-x-y)(WO4)2:xEu3+,yTb3+ phosphor by molten salt synthesis[J].Journal of Rare Earths,2018,36:49-57.
[9] Xu W,Hu Y W,Zheng L J,et al.Enhanced NIR-NIR luminescence from CaWO4:Nd3+/Yb3+ phosphors by Li+ codoping for thermometry and optical heating[J].Journal of Luminescence,2019,208:415-423.
[10] Feng X,Feng W L,Xia M,et al.Co-precipitation synthesis,photoluminescence properties and theoretical calculations of MgWO4:Eu3+ phosphors[J].RSC Advances,2016,6(18):14826-14831.
[11] 张林森,王志涛,王力臻,等.ZnWO4的制备及在染料敏化太阳能电池中的光电性能研究[J].人工晶体学报,2012,41(5):1352-1356.
[12] Zhai Y Q,Sun Q L,Yang S,et al.Morphology-controlled synthesis and luminescence properties of green-emitting NaGd(WO4)2:Tb3+ phosphors excited by n-UV excitation[J].Journal of Alloys and Compounds,2019,781:415-424.
[13] Li M T,Takei T,Zhu Q,et al.Morphology tailoring of ZnWO4 crystallites/architectures and photoluminescence of the doped RE3+ ions (RE=Sm,Eu,Tb,and Dy)[J].Inorganic Chemistry,2019,58(14):9432-9442.
[14] Xu C X,Wei X,Ren Z H,et al.Solvothermal preparation of Bi2WO6 nanocrystals with improved visible light photocatalytic activity[J].Materials Letters,2009,63(26):2194-2197.
[15] Liu Y X,Yue X J,Cai K,et al.Microwave-assist hydrothermal synthesis and luminescence of NaGd(WO4)2:Tb3+ phosphors:a case study for the energy saving in the synthesis of phosphors[J].Energy,2015,93:1413-1417.
[16] Alharthia F A,Alsaiarib M A,Jalalahbc M S,et al.Combustion synthesis of β-SnWO4-rGO:anode material for Li-ion battery and photocatalytic dye degradation[J].Ceramics International,2020,47(7):10291-10300.
[17] Santiago A A G,Fernandes Y L R L,Tranquilin R L,et al.Influence of Zn1-xCaxWO4 heterostructures synthesized by spray pyrolysis on photoluminescence property[J].Ceramics International,2019,45(17):23256-23264.
[18] Li K,Deun R V.Novel intense emission-tunable Li1.5La1.5WO6:Mn4+,Nd3+,Yb3+ material with good luminescence thermal stability for potential applications in c-Si solar cells and plant-cultivation far-red-NIR LEDs[J].ACS Sustainable Chemistry & Engineering,2019,7(19):16284-16294.
[19] Makhlouf M M,Abdulkarim S,Adam M S S,et al.Unraveling urea pre-treatment correlated to activate Er2(WO4)3 as an efficient and stable counter electrode for dye-sensitized solar cells[J].Electrochimica Acta,2020,333:135540.
[20] Han B,Dai Y Z,Zhang J,et al.Luminescence properties of a novel yellow-emitting phosphor NaLaMgWO6:Dy3+[J].Materials Letters,2017,204:145-148.
[21] Zhai Y Q,Wang M,Zhao Q,et al.Fabrication and luminescent properties of ZnWO4:Eu3+,Dy3+ white light-emitting phosphors[J].Journal of Luminescence,2016,172:161-167.
[22] Zhang W,Shen N,Han S M,et al.Hydrogen storage properties of MgH2+20wt% Na2WO4 composite[J].Materials Research Bulletin,2015,72:197-203.
[23] Wang J S,Zhang W,Li B,et al.Effects of Fe modified Na2WO4 additive on the hydrogen storage properties of MgH2[J].Journal of Wuhan University of Technology-Materials Science Edition,2019,34(5):1030-1036.
[24] Zhang Y,Chai X N,Li J,et al.Enhanced up-conversion luminescence and excellent temperature sensing properties in Yb3+ sensitized Er3+-doped Bi3Ti1.5W0.5O9 multifunctional ferroelectric ceramics[J].Journal of Alloys & Compounds,2017,735:473-479.
[25] Zhang S,Liu Z,Zhang Y,et al.Highly effective photoelectrochemical performance of solar energy materials based on Ag2WO4-AgX(X=Cl,Br,I) sensitized TiO2 nanotube arrays[J].Ceramics International,2018,44(6):6659-6665.
[26] Meng J,Chen T,Wei X,et al.Template-free hydrothermal synthesis of MgWO4 nanoplates and their application as photocatalysts[J].RSC Advances,2019,9(5):2567-2571.
基金资助
国家自然科学基金(21804030);河北省自然科学基金(B2020201082)
PDF
