化工新型材料

化工新型材料 ›› 2022, Vol. 50 ›› Issue (1) : 39-45. DOI: 10.19817/j.cnki.issn1006-3536.2022.01.009

综述与专论

手性有机多孔材料的合成及其手性拆分膜研究进展

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作者信息 +

Research progress on chiral porous material and chiral separation membrane

Huang Yuan¹, Zang Yu¹, Xu Liang², Wu Yunfeng¹, Lei Tianyang¹, Cui Jia¹, Xie Yujie¹

Author information +

文章历史 +

Received		Published
2020-09-07		2022-01-20
Issue Date	Revised Date
2022-02-08	2020-09-07

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摘要

随着光学纯化合物需求的不断增加,手性分离的研究在医药、化学、生物学等领域具有重要意义。膜分离法是近年来发展的一种新型节能技术,具有连续操作、易于放大、无污染等优点,被认为是一种具有潜力的大规模拆分对映异构体的方法。大多数一维聚合物手性分离膜的选择性与通量之间呈反向关系,且耐溶剂性差,导致分离性能不稳定,通量较低。有机多孔材料具有较大的比表面积和永久孔隙率,对有机溶剂具有极高的稳定性,在合成过程中引入手性官能团制备出手性材料可以实现在手性分离膜领域的应用。

Abstract

With the increasing demand for optically pure compounds,chiral separation is of great significance in medicine,chemistry,biology and other industries.Membrane separation is a new energy-saving technology developed in recent years.It has the advantages of continuous operation,easy amplification and no pollution.It is considered to be a potential method for large-scale enantiomeric separation.The selectivity of most one-dimensional polymer chiral membranes is inversely related to the flux,and the poor solvent resistance leads to unstable separation performance and low flux.Organic porous materials have large specific surface area,permanent porosity and high stability in organic solvents,which can be used in chiral membrane separation by introducing chiral groups in the synthesis process.

关键词

有机多孔材料 / 手性膜 / 手性基团 / 对映体分离

Key words

organic porous material / chiral membrane / chiral group / enantiomeric separation

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手性有机多孔材料的合成及其手性拆分膜研究进展[J]. 化工新型材料, 2022, 50(1): 39-45 DOI:10.19817/j.cnki.issn1006-3536.2022.01.009

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