石墨烯具有优异的机械性能及导热性能,将其与聚合物结合制成复合材料,是发挥石墨烯优异性能最可行的方法之一。然而,石墨烯在聚合物中分散时易团聚,石墨烯功能化是解决这一问题最常用的方法。基于以上背景,重点介绍了石墨烯与氧化石墨烯的功能化方法,包括共价功能化和非共价功能化。同时,阐述了功能化石墨烯在改性环氧树脂力学性能和导热性能的应用现状。
Graphene(RGO) has excellent mechanical properties and thermal conductivity,in order to give play to these excellent properties,one of the most feasible ways is combining it with polymers to make nanocomposites.However,the bottleneck is that RGO sheets tend to form severe aggregations in the polymer,RGO functionalization is the most commonly used method to solve this problem.Thus,the functionalization methods of GRO and graphene oxide(GO) were focused,including covalent functionalization and non-covalent functionalization.The research status of RGO functionalization in the mechanical properties and thermal conductivity of modified EP was summarized.
[1] Tiwari S K,Sahoo S,Wang N N,et al.Graphene research and their outputs:status and prospect[J].Journal of Science:Advanced Materials and Devices,2020,5(1):10-29.
[2] 王明浩.石墨烯的研究进展及应用前景概述[J].科技与创新,2019(20):140-141.
[3] Zheng W,Chen W G,Ren S X,et al.Interfacial structures and mechanisms for strengthening and enhanced conductivity of graphene/epoxy nanocomposites[J].Polymer,2019,163:171-177.
[4] Nandanapalli K R,Mudusu,D,Lee S.Functionalization of graphene layers and advancements in device applications(review)[J].Carbon,2019,152:954-985.
[5] Yadav A,Kumar A,Sharma K,et al.Investigating the effects of amine functionalized graphene on the mechanical properties of epoxy nanocomposites[J].Materials Today:Proceedings,2019,11:837-842.
[6] Aswathnarayan M S,Muniraju M,Reddappa H N,et al.Synergistic effect of nano graphene on the mechanical behaviour of glass-epoxy polymer composites[J].Materials Today:Proceedings,2020,20(2):177-184.
[7] Shukla M K,Kumar A,Yadav A,et al.Improved mechanical properties of graphene oxide reinforced cross-linked epoxy nanocomposites:a molecular dynamics approach[J].Materials Today:Proceedings,2019,11:679-685.
[8] Jin F L,Li X,Park S J.Synthesis and application of epoxy resins:a review[J].Journal of Industrial and Engineering Chemistry,2015,29:1-11.
[9] Singh N P,Gupta V K,Singh A P.Graphene and carbon nanotube reinforced epoxy nanocomposites:a review[J].Polymer,2019,180:121724.
[10] 吕鹏,冯奕钰,张学全,等.功能化石墨烯的应用研究新进展[J].中国科学:技术科学,2010,40(11):1247-1256.
[11] 张晓勇.石墨烯偶氮功能化及重氮盐功能化[D].长沙:湖南大学,2014.
[12] 郝冰洁,宋涛,黄晓宇,等.石墨烯共价修饰中的有机反应[J].有机化学,20 ,40(10):10.
[13] Zhao S,Chang H,Chen S,et al.High-performance and multifunctional epoxy composites filled with epoxide-functionalized graphene[J].European Polymer Journal,2016,84:300-312.
[14] Chauhan D S,Quraishia M A,Ansaria K R,et al.Graphene and graphene oxide as new class of materials for corrosion control and protection:present status and future scenario[J].Progress in Organic Coatings,2020,147:105741.
[15] 方瑞萍,唐辉,黄剑,等.碳材料的芳基重氮盐改性及其应用进展[J].化工新型材料,2014,42(9):191-193,196.
[16] Yao H,Hawkins S A,Sue H J.Preparation of epoxy nanocomposites containing well-dispersed graphene nanosheets[J].Composites Science and Technology,2017,146(7):161-168.
[17] Hu Z,Song C H,Shao Q,et al.One-step functionalization of graphene by cycloaddition of diarylcarbene and its application as reinforcement in epoxy composites[J].Composites Science and Technology,2016,135:21-27.
[18] Jayan J S,Saritha A,Deeraj B D S,et al.Triblock copolymer grafted Graphene oxide as nanofiller for toughening of epoxy resin[J].Materials Chemistry and Physics,2020,248:122930.
[19] Wang X,Wei Y Xing W Y,Zhang P,et al.Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites[J].Composites Science and Technology,2012,72(6):737-743.
[20] Li J,Zhu W J,Zhang S F,et al.Amine-terminated hyperbranched polyamide covalent functionalized graphene oxide-reinforced epoxy nanocomposites with enhanced toughness and mechanical properties[J].Polymer Testing,2019,76:232-244.
[21] Li Y C,Wang Z Y,Zhan Y H,et al.Improved mechanical and dielectric performances of epoxy nanocomposites filled with aminated polyethylene glycol grafted graphene[J].Materials Letters,2019,246:149-152.
[22] Duan W P,Chen Y,Ma J H,et al.High-performance graphene reinforced epoxy nanocomposites using benzyl glycidyl ether as a dispersant and surface modifier[J].Composites Part B:Engineering,2020,189:107878.
[23] 杨少军.石墨烯的非共价功能化修饰及其传感应用研究[D].沈阳:辽宁大学,2019.
[24] Li Y C,Tang,J G,Huang L J,et al.Facile preparation,characterization and performance of noncovalently functionalized graphene/epoxy nanocomposites with poly(sodium 4-styrenesulfonate)[J].Composites Part A Applied Science & Manufacturing,2015,68(1):1-9.
[25] Javidparvar A A,Naderi R,Ramezanzadeh B.Non-covalently surface modification of graphene oxide nanosheets and its role in the enhancement of the epoxy-based coatings` physical properties[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2020,602:125061.
[26] 张荣金,袁妍.离子液体分散石墨烯的研究进展[C].2018第十九届中国辐射固化年会论文报告集,2018.
[27] Hou W X,Gao Y,Wang J,et al.Recent advances and future perspectives for graphene oxide reinforced epoxy resins[J].Materials Today Communications,2020,23:100883.
[28] Wolk A,Rosenthal M,Weiß J,et al.Graphene oxide as flexibilizer for epoxy amine resins[J].Progress in Organic Coatings,2018,122:280-289.
[29] Ferreira F V,Brito F S,Franceschi W,et al.Functionalized graphene oxide as reinforcement in epoxy based nanocomposites[J].Surfaces and Interfaces,2018,10:100-109.
[30] 史婷,郑亚萍,李沛沛.不同沉积物无溶剂纳米石墨烯流体/环氧树脂复合材料阻燃性能对比[J].复合材料学报,2017,34(1):31-39.
[31] Li P P,Zheng Y P,Li M Z,et al.Enhanced toughness and glass transition temperature of epoxy nanocomposites filled with solvent-free liquid-like nanocrystal-functionalized graphene oxide[J].Materials & Design,2016,89:653-659.
[32] Li Z,Wang R G,Robert J,et al.Control of the functionality of graphene oxide for its application in epoxy nanocomposites[J].Polymer,2013,54(23):6437-6446.
[33] 胡涛,赵东林,程兴旺,等.GO增强环氧树脂复合材料的制备及其力学性能研究[J].北京化工大学学报(自然科学版),2018,45(6):29-33.
[34] Ramezanzadeh B,Bahlakeh G,Moghadam M H M,et al.Impact of size-controlled p-phenylenediamine (PPDA)-functionalized graphene oxide nanosheets on the GO-PPDA/Epoxy anti-corrosion,interfacial interactions and mechanical properties enhancement:Experimental and quantum mechanics investigations[J].Chemical Engineering Journal,2018,335:737-755.
[35] Ahmadi-Moghadam B,Sharafimasooleh M,Shadlou S,et al.Effect of functionalization of graphene nanoplatelets on the mechanical response of graphene/epoxy composites[J].Materials and Design,2015,66(feb.):142-149.
[36] Ashori A,Rahmani H,Bahrami R.Preparation and characterization of functionalized graphene oxide/carbon fiber/epoxy nanocomposites[J].Polymer Testing,2015,48:82-88.
[37] 杨坤好,姚盼,肖海刚,等.石墨烯纳米片/环氧树脂的导热性能研究[J].热固性树脂,2019,34(4):40-44.
[38] Liu Y J,Lu J Y,Cui Y B.Improved thermal conductivity of epoxy resin by graphene-nickel three-dimensional filler[J].Carbon Resources Conversion,2020,3:29-35.
[39] Pettes M T,Ji H,Ruoff R S,et al.Thermal transport in three-dimensional foam architectures of few-layer graphene and ultrathin graphite[J].Nano Letters,2012,12(6):2959-2964.
[40] Shen X,Wang Z Y,Wu Y,et al.Effect of functionalization on thermal conductivities of graphene/epoxy composites[J].Carbon,2016,108:412-422.
[41] 张玉伟,沈育才,王庭慰.石墨烯/环氧复合材料导热性能的研究进展[J].高分子通报,2017(9):27-32.
[42] Chen Y,Xiao H,Liao M,et al.Constructing a “pea-pod-like” alumina-graphene binary architecture for enhancing thermal conductivity of epoxy composite[J].Chemical Engineering Journal,2019,381:122690.
[43] Ji C,Yan C,Wang Y,et al.Thermal conductivity enhancement of CNT/MoS2/graphene-epoxy nanocomposites based on structural synergistic effects and interpenetrating network[J].Composites Part B:Engineering,2019,163:363-370.
基金资助
国家自然科学基金(U1837601)
PDF
