特殊形貌结构光催化材料的模板法制备一直是研究的热点,其制备工艺简单,所得产品性能高效,一直被广泛地应用于吸附领域。综述了常见模板的种类及其特点,对模板法制备的样品在吸附剂和光催化剂的应用进行了介绍。并对今后的模板法研究方向及应用提出了总结和展望。
The template method for the preparation of photocatalytic materials with special morphology has always been a research hotspot.The preparation process is simple,and the performance of the obtained products is high.It has been widely used in the field of adsorption.The types and characteristics of common templates were reviewed,and the applications of samples prepared by template methods in adsorbents and photocatalysts were introduced.It also summarized and prospected the future research directions and applications of template method.
[1] 郑冰,牛海军,白续铎.有机染料敏化纳米晶太阳能电池[J].化学进展,2008,20(6):828-840.
[2] 崔家强.室内甲醛催化降解介孔二氧化锰催化剂的研究[D].青岛:山东科技大学,2009.
[3] 杜立功.介孔材料制备及其吸附性能研究[D].青岛:山东科技大学,2007.
[4] Wang B,Di J,Zhang P,et al.Ionic liquid-induced strategy for porous perovskite-like PbBiO2 Br photocatalysts with enhanced photocatalytic activity and mechanism insight[J].Applied Catalysis B:Environmental,2017,206:127-135.
[5] Jiang X,Li C,Liu S,et al.The synthesis and characterization of ytterbium-doped TiO2 hollow spheres with enhanced visible-light photocatalytic activity[J].RSC Advances,2017,7:24598-24606.
[6] Guo Y,Pu Y,Cui Y,et al.A simple method using citric acid as the template agent to improve photocatalytic performance of BiFeO3,nanoparticles[J].Materials Letters,2017,196:57-60.
[7] 黄云,马若男,曾宪哲,等.软模板法制备三维花状MgAl-LDH及其吸附性能[J].无机化学学报,2018,34(5):128-135.
[8] 王路峰,施海波,王騊,等.氧化亚铜模板法制备中空结构的Pt/Cu合金及其电催化性能研究[J].浙江理工大学学报,2015,33(5):622-628.
[9] Kang D,Ko J H,Choi J,et al.Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks[J].Chemical Communications,2017,53:53-62.
[10] Han D,Song P,Zhang H,et al.Cu2O template-assisted synthesis of porous In2O3 hollow spheres with fast response towards acetone[J].Materials Letters,2014,124:93-96.
[11] Jin C,Zhu K,Peterson G,et al.Morphology dependent photocatalytic properties of ZnO nanostructures prepared by a carbon-sphere template method[J].Journal of Nanoscience and Nanotechnology,2018,18(8):5234-5241.
[12] Wei N,Cui H,Wang X,et al.Hierarchical assembly of In2O3,nanoparticles on ZnO hollow nanotubes using carbon fibers as templates:enhanced photocatalytic and gas-sensing properties[J].Journal of Colloid and Interface Science,2017,498:263-270.
[13] 高海荣.以MOFs为模板合成多孔金属氧化物降解水中亚甲蓝[J].工业水处理,2019,39(5):73-77.
[14] 赵俊凯.花粉模板法制备氧化物及复合氧化物空心微纳米材料的研究[D].青岛:山东科技大学,2019.
[15] Yang X,Xu B,Zhang X,et al.Preparation of micro/nanostructure TiO2 spheres by controlling pollen as hard template and soft template[J].Journal of Nanoscience & Nanotechnology,2014,14(9):7228-7233.
[16] 冀菲.微纳复合结构的构筑及其在水处理中的应用[D].济南:济南大学,2018.
[17] Yuan Y,Fu A,Wang Y,et al.Spray drying assisted assembly of ZnO nanocrystals using cellulose as sacrificial template and studies on their photoluminescent and photocatalytic properties[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,522:173-182.
[18] Kale G,Arbuj S,Kawade U,et al.Synthesis of porous nitrogen doped zinc oxide nanostructures using a novel paper mediated template method and their photocatalytic study for dye degradation under natural sunlight[J].Materials Chemistry Frontiers,2018,2:163-170.
[19] 黄雨婷,英祖萍,郑继兴,等.分级多孔结构ZnO的秸秆生物模板法制备及光催化性能[J].高等学校化学学报,2018,39(9):2030-2038.
[20] 李洪峰,李嘉,王俊.以棉花为模板制备生物形态ZnO[J].材料导报,2008,22(z3):52-54.
[21] Wang J W,Kuo Y M.Hierarchically porous cobalt oxyhydroxide derived from morpho-butterfly wings:preparation,characterization,and carbon monoxide detection at low temperatures[J].Physica Status Solidi,2013,210(3):494-502.
[22] Jeong Y J,Koo W T,Jang J S,et al.Chitosan-templated Pt nanocatalyst loaded mesoporous SnO2 nanofibers:a superior chemiresistor toward acetone molecules[J].Nanoscale,2018,10:13713-13721.
[23] Karpuraranjith M,Thambidurai S.Immobilization effect of morphological,thermal and optical properties in biotemplate on zinc oxide nanocomposite from chitosan[J].International Journal of Nanoscience,2017,16:1760045.
[24] Tian J,Shao Q,Zhao J,et al.Microwave solvothermal carboxymethyl chitosan templated synthesis of TiO2/ZrO2 composites toward enhanced photocatalytic degradation of Rhodamine B[J].Journal of Colloid and Interface Science,2019,541:18-29.
[25] Ijiro K,Mitomo H.Metal nanoarchitecture fabrication using DNA as a biotemplate[J].Polymer Journal,2017,49(12):815-824.
[26] Alkaim A F,Alrobayi E M,Algubili A M,et al.Synthesis,characterization,and photocatalytic activity of sonochemical/hydration-dehydration prepared ZnO rod-like architecture nano/microstructures assisted by a biotemplate[J].Environmental Technology,2016,38(17):1-11.
[27] Ge S,Zhang Q,Wang X,et al.Bacteria-directed construction of ZnO/CdS hollow rods and their enhanced photocatalytic activity[J].Journal of Nanoscience and Nanotechnology,2016,16(5):4929-4935.
[28] Hernández-Gordillo A,Campero A,Vera-Robles L I.Mesoporous TiO2 synthesis using a semi-hard biological template[J].Microporous and Mesoporous Materials,2018,270:140-148.
[29] 杨莉,李旭,汪子孺,等.基于酵母的钨酸铋空心微球制备及其光催化降解盐酸四环素性能[J].化工新型材料,2016,44(2):98-101.
[30] 张文治,张秀丽,李莉,等.CTAB作用下纳米复合材料ZnO-TiO2制备与多模式光催化降解罗丹明B[J].分子催化,2013,27(5):474-482.
[31] 李晓娜.SiO2/Bi2WO6中空复合微球的合成及水体污染处理研究[J].吉林农业大学学报,2018,40(5):89-93.
[32] 杨则恒,李红艳,张卫新.基于MCM-41模板制备β-MnO2纳米纤维及其催化降解亚甲基蓝染料[J].高等学校化学学报,2010,31(6):1108-1112.
[33] 刘凤艳,肖丽伟,康志成,等.多孔二氧化钛吸附刚果红[J].化工进展,2014,33(5):1321-1326.
[34] 孔超.利用松花粉模板制备MgAl-LDHs/MgFe2O4及其吸附性能的研究[D].济南:济南大学,2015.
[35] 杨为森,简绍菊,左甜,等.Ag/ZnO复合中空材料的制备及光催化降解罗丹明B[J].化工新型材料,2018,46(4):146-149.
[36] 张昔玉,葛圣松,邵谦,等.酵母菌模板法制备CeO2空心微球及其光催化性能[J].无机化学学报,2016,32(9):1535-1542.
[37] 楼章萍.模板法合成氮掺杂类石墨烯及其类酶活性研究[D].南京:南京大学,2019.
[38] Liu Z X,Park J N,Abdi S H R,et al.Nano-sized carbon hollow spheres for abatement of ethylene[J].Topics in Catalysis,2006,39(3-4):221-226.
基金资助
国家自然科学基金(21176145);山东省自然科学基金项目(ZRZR2018MEE003)
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