20 September 2025, Volume 53 Issue 9
    

  • Select all
    |
  • Sun Chang, Qiao Yu, Zhao Lina
    New Chemical Materials. 2025, 53(9): 1-7. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.004
    Abstract ( )   Knowledge map   Save
    Metal-organic frameworks (MOFs) materials have a rich porous topology,and when they interact with small molecules or metal ions,their structure or properties change,causing changes in fluorescence or color,which provides favorable conditions for the development of MOFs-based optical sensors.Carbon quantum dots (CQDs) are a new type of spheroidal nanoparticles and can absorb ultraviolet and visible light,with good fluorescence properties,offering great application potential in fluorescence sensing.Introducing CQDs into MOFs adds new active sites to MOFs materials,resulting in the prepared CQDs@MOFs with the advantages of shorter response time and lower detection limits.This paper reviewed the composite methods of CQDs@MOFs and their application progress in fluorescence sensors,and further discussed the future development prospects of CQDs@MOFs composites.
  • Liu Ling, Qu Yunyi, Fan Baoxi, Cheng Xiaoyue, Wu Zheng, Zhang Luohong, Hong Siqi
    New Chemical Materials. 2025, 53(9): 8-12. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.010
    Abstract ( )   Knowledge map   Save
    Metal-organic frameworks (MOFs) have been extensively utilized in the domains of gas adsorption,catalysis,and separation.However,the experimental screening of high-performance MOFs is arduous and time-consuming.Along with the advancement of artificial intelligence,machine learning offers an efficient and precise research approach for MOFs to capture CO2.In this paper,the screening process of the MOFs machine learning model and its application in carbon capture were reviewed.It was proposed that automated methods for extracting MOFs features or interpretability methods to enhance the reliability and understandability of the model should be the future research orientations of machine learning-assisted MOFs materials for carbon capture.
  • Hu Qian, Mo Ya, Yue Meng, Wu Wanchao, Hu Chuanqun
    New Chemical Materials. 2025, 53(9): 13-18. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.005
    Abstract ( )   Knowledge map   Save
    Waterborne damping materials offer simpler processes and are environmentally friendly.Their damping performance mainly depends on the properties of base emulsion and fillers.Polyurethane damping materials are currently one of most widely researched and applied viscoelastic materials.In order to improve the damping performance of waterborne polyurethane damping materials,broaden their damping temperature range and loss factor,synthesis methods such as mechanical blending,copolymerization,and interpenetrating polymer networks are often used.This article introduced the noise reduction mechanism of polyurethane damping materials,summarized the synthesis methods of waterborne polyurethane damping materials,and reviewed the modification and application progress of waterborne polyurethane damping materials.
  • Lang Yufan, Zhao Hang, Zhang Xue, Liu Siyu, Duan Yi, Luo Weihua
    New Chemical Materials. 2025, 53(9): 19-23. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.029
    Abstract ( )   Knowledge map   Save
    The metal-biomass frameworks (Bio-MOFs) not only retain the adjustable pore size and structure,high specific surface and high density of active sites of traditional MOFs,but also have the characteristics of environmental friendliness and low cost due to biomass molecules replacing traditional organic ligands,and can improve the intrinsic activity to a certain extent,attracting growing attention in the field of electrocatalysis.In this paper,the commonly used biomass ligands for current Bio-MOFs were summarized,and the application progress of Bio-MOFs in electrocatalysis was reviewed.The existing problems were analyzed,and the future development directions of Bio-MOFs were put forward.
  • Ying Bo, Liu Li
    New Chemical Materials. 2025, 53(9): 24-29. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.035
    Abstract ( )   Knowledge map   Save
    Because of the suitable energy band structure,stable physicochemical properties and simple preparation method of g-C3N4 materials,they have been widely used in photocatalytic hydrogen production.The g-C3N4 materials have the problems of high photogenerated charge transfer resistance,low utilization of photogenerated carriers,and insufficient redox active sites on the surface during the photocatalytic reaction.The modification study of g-C3N4 materials to enhance their photocatalytic performance has been a hot research topic in this field.In this paper,we reviewed the modification strategies of g-C3N4 materials in terms of elemental doping,construction of heterojunction and co-catalysts loading,and enumerated the research progress based on g-C3N4 materials in recent years.
  • Li Rongxing, Gao Yuanming, Zheng Fei, Ma Wen, Feng Xueying, Bai Yu, Liu Jiong, Zuo Tonglin
    New Chemical Materials. 2025, 53(9): 30-36. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.001
    Abstract ( )   Knowledge map   Save
    Because of the unique electronic structure and physicochemical properties of rare-earth elements,Oxysalt-based rare-earth luminescent materials show great potential in the field of luminescence.In recent years,remarkable progress has been made in this field,mainly focusing on material preparation,luminescence mechanism and performance optimization.By improving the synthesis methods,such as high-temperature solid-phase method and precipitation method,the controllable synthesis of these materials has been realized.At the same time,the application of nanotechnology further improves the luminescence efficiency and stability of the materials.At present,oxysalt-based rare-earth luminescent materials show wide application prospects in lighting,display,biomedicine and other fields,and continue to promote the innovation and development of related industries.In this paper,the composition and classification of rare-earth luminescent materials were introduced,the research progress of oxysalt-based rare-earth luminescent materials was reviewed,and the future research directions were prospected.
  • Sun Mingming
    New Chemical Materials. 2025, 53(9): 37-41. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.028
    Abstract ( )   Knowledge map   Save
    Membrane electrode is the core component of proton exchange membrane fuel cell,and low Pt loading and long-life membrane electrode is very important to accelerate its commercialization.After two generations of technology evolution,the latest generation of ordered membrane electrodes is the current research hotspot.From the perspective of patent technology,based on the search results of Himmpat Database,the patent application situation of ordered membrane electrode was analyzed,and the main countries of origin of the patents and the important applicants were compared.From the directions of the ordered structure of catalyst layer,and the fully ordered structure based on exchange membrane layer or diffusion layer,the research progress of patented technology was also summarized and analyzed.It was found that,from the perspective of industrialization,the fully ordered structure based on exchange membrane or diffusion layer offered more advantageous.It was recommended that the key domestic applicants should optimize the completeness of the patent layout and pay more attention to the membrane electrode module enterprises with integrated production capacity during the process of patent transformation and application.
  • Wang Weiwei, Zhao Fei, Rui Wenyi
    New Chemical Materials. 2025, 53(9): 42-46. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.050
    Abstract ( )   Knowledge map   Save
    Graphene conductive ink is a new type of ink based on the high conductivity of graphene.An analysis of literature and patents from 2010 to 2024 shows that the trend of domestic and foreign literature publication and patent application in this technology field presents a highly consistent trend,with rapid development around 2016 and a slight decline after 2020.From the analysis of the papers,the research hotspots focus on three aspects:process improvement,component optimization,and application field expansion.Specifically,it includes the application of inkjet printing and conductive wire materials in 3D printing,the improvement of dispersants,the development of water-based and environmentally friendly solvents,the optimization of composite inks and sintering processes,and the development of emerging fields such as strain sensors and humidity sensors.From patent analysis,the main application areas include electronic devices (such as sensors,RFID antennas,transistors,etc.),electromagnetic interference shielding,and nanofilms applied to electronic and optical devices.High impact patents mainly are mainly concentrated in 3D nanostructures,multi-layer printed circuits,flexible sensors,and other fields.The future research fields of graphene conductive ink are developing towards high-performance sensors,flexible electronics,energy storage,and biomedical applications.
  • Xu Ziqi, Huang Jian, Liu Zhenxuan, Yuan Guangming, Chen Zhiyan
    New Chemical Materials. 2025, 53(9): 47-52. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.036
    Abstract ( )   Knowledge map   Save
    The rapid advancement of wireless communication technology and the escalating number of electronic devices have exacerbated the issue of electromagnetic interference,significantly affecting data transmission and equipment performance.Consequently,the research and development of high-performance electromagnetic wave-absorbing materials are of paramount importance.Due to its abundant resources,environmental friendliness,and low density,cellulose has garnered significant attention for its potential in the field of high-efficiency wave absorption.The pure cellulose material,characterized by its low dielectric loss,high resistivity,and non-magnetic properties,exhibits weak wave-absorbing capabilities,making it challenging to apply directly without modification.This paper reviewed the principles and properties of modified cellulose,summarized three modification methods that researchers have used to enhance its magnetic properties by incorporating magnetic metals and its dielectric properties by employing carbon materials and conductive polymers.Lastly,based on relevant reviews,the challenges currently faced by modified cellulose wave-absorbing materials were discussed,and prospects for the next stage of development were outlined.
  • Huang Jiangnan, Wang Wendong, Wu Xinfeng
    New Chemical Materials. 2025, 53(9): 53-58. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.048
    Abstract ( )   Knowledge map   Save
    This paper briefly reviewed the research progress on the friction and wear properties of aramid composites,and introduced the friction and wear properties of fiber-reinforced,particle-filled and polymer blend-modified aramid composites.The effects of different lubrication conditions,such as dry friction,water lubrication and oil lubrication,on the friction and wear properties of aramid composites were comparatively analyzed,and the friction and wear properties of aramid composites were improved after modification.Additionally,the applications of aramid composites in aerospace,automotive industries,protective equipment and other fields were briefly discussed.Finally,prospects for future research directions of aramid composites were proposed.
  • Liu Gang, Gao Xu
    New Chemical Materials. 2025, 53(9): 59-63. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.025
    Abstract ( )   Knowledge map   Save
    While carbon fiber is widely used in high-end manufacturing due to its advantages of high strength,high specific modulus,high chemical resistance and low thermal expansion,the various links of its industry chain also generate waste and end-of-life (EOL) recycling and reuse issues.Wind turbine blades,aircraft,automobiles and building materials are the major carbon fiber waste streams in the world,and the research and development of carbon fiber recycling and reuse patented technologies and market applications are imminent.By analyzing the trend of carbon fiber recycling and reuse patent applications,sorting out the geographical distribution of applications,major recycling technologies and applicant rankings,it revealed the existing problems,clarified the directions of key technological innovations and improving the patent layout and industrial layout of carbon fiber recycling and reuse.
  • Guo Ziyu, Tang Sijia, Zhang Zhiyu, Zhu Chengzhi
    New Chemical Materials. 2025, 53(9): 64-69. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.047
    Abstract ( )   Knowledge map   Save
    Self-healing hydrogels exhibit exceptional reliability,long-term stability,and sustainability.As a fundamental component of flexible sensors,they have significantly facilitated the vigorous advancement of the flexible electronics field.The self-healing capability of hydrogels depends on the dynamic reversible chemical bonds in the network.However,developing hydrogels with excellent self-healing that meet the practical requirements of flexible sensors was challenging.The paper reviewed the design strategies of self-healing hydrogels networks and the recent progress in flexible sensor applications,highlighted the two network design strategies based on dynamic reversible covalent bond and dynamic reversible non-covalent bond,and their applications in resistive,capacitive and piezoelectric flexible sensors.The future development of self-healing hydrogels was also prospected.
  • Lu Yajing, Tian Xinjiao, Wang Liang, Huang Yue, Gao Jingfei, Liu Jingxian
    New Chemical Materials. 2025, 53(9): 70-76. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.049
    Abstract ( )   Knowledge map   Save
    To investigate the application of aramid (PMIA) nanofiber membranes in high-temperature and dusty environments,this study prepared PMIA nanofiber membranes using electrospinning technology.Their filtration and mechanical properties under high-temperature and acid-alkali conditions were investigated.The results indicated that the optimal process parameters were as follows:PMIA concentration of 12%,spinning receiving distance of 12cm,and spinning voltage of 25kV.The average diameter of the prepared PMIA nanofiber membrane was 312.44nm,with a filtration efficiency of 98.45% for PM0.3 particles,a pressure drop of 141.57Pa,a quality factor (QF) of 0.0294Pa-1,and a breaking strength of 16.015MPa,indicating outstanding filtration and mechanical performance.Furthermore,the PMIA nanofiber membrane exhibited excellent resistance to high temperatures,and acid-alkali environments,demonstrating potential for application in the ultrafine particle filtration in high-temperature flue gas.These findings provide a critical foundation for the future development of high-performance,high-temperature resistant dust nanofiltration materials.    
  • Zhao Renhang, Li Qinliang, Wang Peng, Yuan Xiaoya
    New Chemical Materials. 2025, 53(9): 77-84. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.026
    Abstract ( )   Knowledge map   Save
    wG/wPU electrothermal films with different wG content were prepared by scraping method using water-based conductive graphene (wG) as filler and water-based flexible polyurethane (wPU) as resin base solution.The effects of wG content on the conductivity,electrothermal property and flexibility of the films were studied.The results showed that when the wG content was 6wt%,the overall performance of the film was the best.Under 15V and 20V voltage,the thermal equilibrium temperature of the film increased from (25±1)℃ to (45±1)℃ and (61±1)℃,respectively,and the power consumption was 540W/m2 and 1100W/m2,respectively.The bending test results demonstrated that the wG-6wt% electrothermal film still maintained excellent electrothermal performance and working stability when the bending degree was changed in real time (curvature 0~100cm-1).The results of SEM,XRD and FT-IR analysis indicated that the wG nanosheets were uniformly dispersed in the wPU matrix but did not react with the substrate.The resulting graphene-modified flexible polyurethane film demonstrated excellent electrothermal properties and environment-friendly preparation process,which was expected to have a good application prospect in flexible medical treatment,flexible wearing and other fields.
  • Fu Fengyan, Gao Zhihua, Wang Yan, Wang Xiaohong, Wang Chao
    New Chemical Materials. 2025, 53(9): 85-89. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.022
    Abstract ( )   Knowledge map   Save
    The development of sulfonated polyether ether ketone (SPEEK) in the field of proton exchange membranes is limited because of its lower proton conductivity.In contrast,metal-organic framework materials (MOFs) have great potential in improving proton conductivity.Herein,UiO-66-NH2 and UiO-66-SO3H composite SPEEK proton exchange membranes were prepared,and the thermal stability,swelling degree,water uptake,and proton conductivity of the composite membranes were studied.The results showed that the composite membranes had excellent thermal stability.Because the UiO-66-NH2 and UiO-66-SO3H could inhibit the movement of polymer chains,the swelling degree of the composite membranes were lower than that of the SPEEK membrane,and their size stabilities were better than that of the SPEEK membrane.The porous structures of UiO-66-NH2 and UiO-66-SO3H had strong water storage capacity,endowing the composite membrane with strong water retention ability,and its water uptake was higher than that of the SPEEK membrane;The higher water retention capacity could provide sufficient water for proton migration,so the proton conductivity of the composite membranes were higher than that of the SPEEK membrane.Among them,the proton conductivity of the composite membrane SPEEK/UiO-66-SO3H could reach 20.73mS/cm,which was 1.12 times higher than that of the SPEEK membrane.The composite membranes presented excellent stabilities and proton conductivities,making them broad application prospect in the field of fuel cells.
  • Zhang Min, Zhao Yamin, Qi Yanjiao, Xian Liang, Yang Xiaojun, Zhang Bin
    New Chemical Materials. 2025, 53(9): 90-95. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.044
    Abstract ( )   Knowledge map   Save
    In order to improve the defects of poor mechanical properties of pure chitosan,chitosan/sodium alginate/citric acid composite gel membranes were prepared by solution casting method using sodium alginate as composite membrane material,citric acid (CA) as crosslinking agent and glycerol as plasticizer.The effects of citric acid addition on the thickness,mechanical properties,infrared spectroscopy,X-ray diffraction,surface wettability and opacity of chitosan/sodium alginate composite gel membranes were studied in detail.The results showed that with the increase of CA content,the crosslinking degree of CS/SA-CA composite gel membrane increased.CS/SA-10% CA composite gel membrane exhibited the highest TS value (685.2kPa) and EB value (105.36%),which made it have certain potential application value in the field of food packaging.
  • Zhang Zongshun, Liang Sen, Shi Haoqi, Huang Xiaojian
    New Chemical Materials. 2025, 53(9): 96-99. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.023
    Abstract ( )   Knowledge map   Save
    A preparation and sintering process of carbon fiber reinforced aluminum alloy composite material coated with alumina coating was proposed.By simulating the motion,energy changes and structural evolution of atoms combined with SEM and FT-IR,the effect of carbon fiber surface treatment on carbon fibers was observed to explore the most effective sintering process for improving the mechanical properties of composite materials.The results showed that the tensile strength of carbon fiber reinforced aluminum alloy composite materials increased first and then decreased with the increase of preheating temperature.It decreased with the increase of sintering infiltration temperature.At a preheating temperature of 500℃ and a sintering temperature of 700℃,the maximum tensile strength was 417.3MPa.
  • Zhong Jinbao, Wang Yongpeng, Fan Haoxi, Meng Xiangyi, Zhang Jian, Feng Xianglong
    New Chemical Materials. 2025, 53(9): 100-106. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.043
    Abstract ( )   Knowledge map   Save
    Sodium acetate trihydrate (SAT) has a wide range of applications,but it suffers from low thermal conductivity,large subcooling and phase separation problems,which have a large negative impact on its application in solar thermal storage systems.Modified expanded graphite (MEG) with good hydrophilicity was prepared by modifying expanded graphite (EG) with anionic surfactant sodium dodecyl sulfate (SDS).When the additions of SDS and EG were 1∶2 and 1∶1,the supercooling degree was only 1.7℃ and 2.8℃,which had not been reported before,and the encapsulation efficiency of EG on SAT was also improved up to 92.52%.The melting enthalpies of SAT and MEG composite phase change materials (CPCM) were as high as 236.5J/g and 236.9J/g,the phase change temperatures were 56.7℃ and 56.5℃,and the thermal conductivities were 51.56% and 34.47% higher than those of SAT.After 100 cycles of storage and exothermic cycling,it still maintained good thermal cycling stability,which was of practical application value.
  • Zhang Chen, Xiao Dingkan, Zhang Jun, Li Haoran, Xu Wei, Zhou Yong
    New Chemical Materials. 2025, 53(9): 107-111. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.042
    Abstract ( )   Knowledge map   Save
    Rigid polyurethane foam,with its advantages of short reaction time,high expansion ratio,ease of operation,and high strength,holds great potential for use in rapid airport pavement repair.In airport repair projects,key reaction parameters such as temperature and time significantly impact the performance of this material.To guide repair practices,this study set four temperatures (5℃,15℃,23℃,and 35℃) and four curing times (0.5h,2h,4h,and 24h).Under these conditions,experiments were conducted to measure reaction time,expansion ratio,and unconfined compressive strength (UCS),along with microstructural analysis using CT scanning.The results indicated that as the temperature increased,the reaction time of the material gradually decreased,achieving 20 minutes 30 seconds at 5℃ and 3 minutes 20 seconds at 35℃.The expansion ratio of the material decreased with rising temperature,with the highest expansion ratio of 7.02 occurred at 35℃.The compressive strength of the material first increased and then decreased with rising temperature,reaching its peak strength at 23℃.At low temperatures,the internal pores of the material were denser,and some unreacted material remained even after full curing.At high temperatures,the internal pores were larger,resulting in lower density and strength.After 0.5h of curing,the material's strength reached 80% of its final strength,and after 4h,it nearly reached its final strength.In the early stage of curing,some pores were not fully formed,with more pores at the bottom than at the top.Once fully cured,the bottom pores became denser than the top ones,leading to higher strength at the bottom.For optimal repair outcomes,it was recommended to mix the rigid polyurethane foam at around 23℃.After 0.5h of curing,the material's strength was sufficient to fully support the weight of the surface materials and accommodated the passage of vehicles and machinery.
  • Huang Xiaoqing, Li Weihao, Shu Xugang, Chen Jiazhi, Li Daiyuan
    New Chemical Materials. 2025, 53(9): 112-116. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.016
    Abstract ( )   Knowledge map   Save
    Tetramethylbisphenol A-type copolymer polycarbonate (PC) was synthesized by an interfacial polycondensation method using triphosgene (BTC),3,3',5,5'-tetramethylbisphenol A (TMBPA) and bisphenol A (BPA) as raw materials.The chemical structure of the polymer was confirmed by Fourier-transform infrared spectroscopy (FT-IR),nuclear magnetic resonance (1H-NMR) and X-ray diffraction (XRD),and the thermal and dielectric properties of the polymer were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).The results showed that the glass transition temperature (Tg) of the synthesized copolymer PC increased with the increase of the molar ratio of TMBPA/BPA,reaching a maximum of 193.5℃.In nitrogen.The 5% thermal decomposition temperature (Td) decreased first and then increased,but the lowest Td also reached 400.4℃.The coefficient of linear expansion (CET) decreased from 73.89×10-6K-1 to 32.91×10-6K-1.Finally,the dielectric and optical properties of the tetramethylbisphenol A-type copolymer PC were studied,and the minimum dielectric constant (ε) was 2.65 and the minimum dielectric loss tangent (tanδ) was 0.00522 at 10GHz.These results indicated that tetramethylbisphenol A-type copolymer PC was a highly optically transparent material with low dielectric constant and excellent high-temperature resistance.
  • Ding Peijie, Zhao Ming, Zhang Shuangkun, Lin Husitu, Wu Zhanpeng
    New Chemical Materials. 2025, 53(9): 117-120. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.006
    Abstract ( )   Knowledge map   Save
    Composite aryloxy polyphosphazene (PDPP) thermal insulation materials were fabricated from PDPP by adding three phosphorus-based flame retardants,and the influence of these retardants on the material's mechanical performance and ablation resistance was systematically studied.The results showed that the introduction of phosphorus-based flame retardants significantly improved the elongation at break of the PDPP thermal insulation materials.Among them,tributyl phosphate (TBP) increased the elongation at break from 120% to 206%,while ammonium polyphosphate (APP) enhanced it to 160% while maintaining the tensile strength unchanged.These flame retardants also notably improved the ablation resistance of the PDPP thermal insulation materials,and the APP demonstrated the most pronounced effect,reducing the linear ablation rate and mass ablation rate of the material to 0.087mm/s and 0.063g/s,respectively,and forming a ceramic layer on the surface of the char layer during ablation.The introduction of APP not only restricted the flowability of SiO2 at high temperatures,but also facilitated its solidification on the char layer surface,forming a robust ceramic layer.This ceramic layer provided excellent protection under direct flame impingement,effectively shielding the char layer structure from damage.The incorporation of phosphorus-based flame retardants significantly enhanced the overall performance of the PDPP thermal insulation materials.
  • Xu Changquan, Zhu Longchao, Luo Mingfeng, Huang Xiaomei, Cao Haijian
    New Chemical Materials. 2025, 53(9): 121-125. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.013
    Abstract ( )   Knowledge map   Save
    In order to investigate the effects of fabric structure on the tensile and shear properties of composite skins,four typical woven fabrics-plain weave,twill weave,double layer and three-dimensional shallow cross bending-were designed and prepared.The carbon fiber composite skins were prepared by vacuum-assisted resin transfer and autoclave process,and their tensile properties and interlayer shear properties were tested.The results showed that the inner fiber bundles of the twill structure skin material was approximately straight,and the properties of the carbon fiber bundles could be effectively utilized during the stretching process.As a result,the warp and weft tensile strength and tensile modulus of the corresponding composite skin were the largest.The bending degree of the inner fiber bundles of shallow cross-bending composite skin was the highest,the carbon fiber bundles could produce decomposition force during the stretching process,and the strength utilization rate of the fiber bundles themselves was low,so the warp and weft tensile strength and tensile modulus of the shallow cross-bending composite skins prepared with them were the smallest.Compared with the other three kinds of composite skins,the shallow cross-bending structure carbon fiber composite skins had the best interlayer shear performance,and its interlayer shear strength was increased by more than 80%.
  • Zhao Chunmei, Wang Mengyao, Li Yuanyuan, Li Yuling, Xie Guanghui, Zhang Lingli
    New Chemical Materials. 2025, 53(9): 126-129. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.019
    Abstract ( )   Knowledge map   Save
    With polyaniline as precursor and zinc chloride as activator,porous carbon materials were prepared by high-temperature pyrolysis.The morphology,structure and supercapacitor performance of the materials were characterized by scanning electron microscopy,X-ray diffractometer,physical adsorption instrument and electrochemical test,respectively.The effects of zinc chloride dosage on the supercapacitor perfoamance of the materials were investigated.The results showed that with the increase of the zinc chloride dosage,the specific surface area and pore volume of porous carbon materials first increased and then decreased.When the mass ratio of polyaniline to zinc chloride was 2∶1,the maximum specific surface area and pore volume of the porous carbon material reached the maximum,1186.7970m2/g and 0.5779cm3/g,respectively.Meanwhile,the specific capacitance was also the largest,which was 306.05F/g.When the current density increased from 1A/g to 5A/g,the specific capacitance remained about 70%,showing good magnification performance.
  • Song Xianghong, Wang Zongyu, Wang Yongkang, Wu Zhanpeng
    New Chemical Materials. 2025, 53(9): 130-137. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.032
    Abstract ( )   Knowledge map   Save
    Ethylene propylene diene monomer (EPDM) rubber has good chemical stability,heat and oxygen aging resistance,wear resistance,and electrical insulation properties.EPDM is widely used in the field of thermal protection and when subjected to high-temperature,it undergoes pyrolysis reaction to take away most of the heat and form a carbonized insulation layer.This article investigated the effects of vulcanization system,filler type,and vulcanization process on the mechanical properties and compressive permanent deformation of EPDM rubber insulation materials.The results showed that when filled with 3 parts of bis (tert butyl) peroxide diisopropylbenzene (BIPB) as the vulcanizing agent,the comprehensive performance was optimal,with a tensile strength of 11.7MPa and a fracture elongation of 763%;The compression permanent deformation of the material reached 22.22% at 25℃,28.97% at 55℃,and 28.42% at 70℃.In the discussion of vulcanization additives,it was found that adding 2 parts of sulfur (S) resulted in the best compressive deformation performance,with compression permanent deformation of 16.85%,37.45%,and 35.29% at 25℃,55℃,and 70℃,respectively.We investigated the effects of several reinforcing fillers on the compression permanent deformation of EPDM insulation materials at different temperatures.After filling with silica,the mechanical properties reached 12.7MPa,and the elongation at break was 625%,along with good resistance to compression deformation.silica achieved compression permanent deformation of 15%,30%,and 52% at 25℃,55℃,and 70℃,respectively.The insulation material filled with silica had better ablation performance,lower linear ablation rate,while still ensuring the strength and integrity of the carbon layer.
  • Hu Zhe, Tao Yang, He Yinglei, Xiang Mingwu, Guo Junming, Bai Wei
    New Chemical Materials. 2025, 53(9): 138-143. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.033
    Abstract ( )   Knowledge map   Save
    A nickel and boron co-doped LiNi0.08B0.06Mn1.86O4 cathode material was prepared via a solid-state combustion method.Its crystal structure and micro-morphology were characterized by XRD and SEM,and the effects of different charge cut-off voltages on the electrochemical performances of the cathode material were systematically investigated by galvanostatic charge/discharge mode.Additionally,the kinetic and impedance changes of the electrode material were investigated by cyclic voltammetry and alternating current impedance.The results showed that the as-prepared LiNi0.08B0.06Mn1.86O4 cathode material possessed the spinel structure with good crystallinity and polyhedral morphology.The different charge cut-off voltages affected the discharge specific capacity and cycle performance,and the discharge specific capacity increased with the increase of charge cut-off voltage.The optimal charge cut-off voltage of LiNi0.08B0.06Mn1.86O4 cathode material at room temperature was 4.5V,and the high initial discharge specific capacity of 113mAh/g could be released at room temperature and 1 C rate.The capacity retention rate retained 89% after 300 cycles,and it still had a high initial discharge specific capacity of 106 mAh/g at 55℃ and 5C rate.
  • Lv Duanzhe, Zhong Weili, Shan Xiaohui, Tang Lidan, Qi Jingang
    New Chemical Materials. 2025, 53(9): 144-149. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.008
    Abstract ( )   Knowledge map   Save
    Manganese cobalt tetrasulfide (MnCo2S4) electrode materials were synthesized via a two-step hydrothermal method.The structure,morphology and electrochemical performance of the electrode materials were characterized and investigated using X-ray diffraction,field emission scanning electron microscope,cyclic voltammetry,constant current charge-discharge tests,and alternating current impedance tests.The experimental results indicated that when the sulfurization temperature was 160℃ and the sulfurization time was 6h,the prepared electrode material exhibited a morphology featuring numerous nano-needle structures with dendritic ends,and the nano-needles were interwoven with each other with dense distribution,forming the optimal material structure.The mass specific capacitance reached 873.5F/g at a current density of 1A/g.An MCS//AC asymmetric supercapacitor was assembled using MnCo2S4 as the positive electrode material and activated carbon (AC) as the negative electrode material.The mass specific capacitance of MCS//AC asymmetric supercapacitor at a current density of 1A/g was 33.1F/g.Its capacitance retention rate was 56% when the current density increased from 1A/g to 5A/g.
  • Zhang Xiangsong, Zhang Yonglin
    New Chemical Materials. 2025, 53(9): 150-153. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.018
    Abstract ( )   Knowledge map   Save
    Based on the polyurethane high-pressure foaming system,the process of synthesizing polyurethane using isocyanate (NCO) and polyether polyol (—OH) as raw materials was simulated under the catalytic action of various additives.Using the Aspen Plus software platform,a process model for the high-pressure foaming of polyurethane was established.The effects of isocyanate index (R),reaction temperature,and catalyst ratio on the polyurethane process were investigated.Sensitivity analysis of the data was conducted using Energy Analyzer,leading to optimized operating parameters:R=1.2~1.3,reactor temperature at 60℃,and the mass fractions of catalyst DMCHA and T-12 were 2% and 0.05%,respectively.Under optimal conditions,the process time was reduced by 12.37%,and the product conversion rate increased by 12.19%.This provides a very important theoretical foundation and practical significance for the production process of polyurethane materials.
  • Liu Chuang, Li Yonggui, Ma Wenxiao, Zhuo Zhiming
    New Chemical Materials. 2025, 53(9): 154-158. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.012
    Abstract ( )   Knowledge map   Save
    Fine denier ethylene-propylene side by side (ES)(thermally bonded polyester) fibers were prepared by selecting polyethylene (PE) as the skin layer and low melting point polyester (LPET) as the core layer for two-component skin-core composite spinning.The surface morphology and mechanical properties of the fibers were analyzed and tested by scanning electron microscope and electronic single-yarn strength machine,and the effects of spinning temperature,winding speed,drafting multiplier,drafting temperature,and skin-core ratio on the mechanical properties and spinnability of the fine denier ES fibers were studied.The results showed that the fine denier ES fiber spinning process was smooth and the fibers were well formed when the PE extrusion temperatures were 182℃,200℃,203℃,205℃,and the LPET extrusion temperatures were 190℃,205℃,213℃,215℃.When the drafting temperature was 80℃,the drafting multiplier was 1.75 times,the winding speed was 3600m/min,and the ratio of skin-to-core ratio was 5∶5,the fibers exhibited good spinnability,morphology and mechanical properties.
  • Li Fushuang, Gong Xin, Yang Zhanfeng, Dong Zichao
    New Chemical Materials. 2025, 53(9): 159-164. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.031
    Abstract ( )   Knowledge map   Save
    The isotropic pitch with softening point of 255℃ was used as raw material to prepare pitch fibers by melt spinning.The effects of pre-oxidation and carbonization process parameters on the mechanical properties of the fibers were studied.The results showed that in the studied range of pre-oxidation treatment conditions,with the increase of pre-oxidation temperature,the oxidation weight gain of the pitch fibers increased first and then decreased,and the tensile strength of the corresponding carbon fibers decreased gradually.With the increase of pre-oxidation time,the oxidation weight gain of the pitch fibers decreased gradually,and the mechanical properties of carbon fibers remained basically unchanged.The oxidation weight gain of the pitch fibers and the tensile strength of carbon fibers increased with the increase of pre-oxidation heating rate.When the pre-oxidation temperature reached 270℃ and above,excessive oxidation occurred when the pre-oxidation temperature was too high,and more oxygen-containing functional groups on the surface of the fiber underwent oxidative decomposition,forming defects and pore structures on the surface and inside of the fiber,resulting in a decrease in the mechanical properties of the fibers.With the increase of carbonization temperature,the fibers became denser,and the tensile strength and tensile modulus of the carbon fibers increased.The pitch-based carbon fibers were pre-oxidized at 230℃ for 60min at a heating rate of 0.5℃/min,and then carbonized at 1200℃ for 5min.The tensile strength and tensile modulus of the obtained pitch-based carbon fibers were 655.0MPa and 33.52GPa,respectively.
  • Wang Zhiyu, Liu Hongru, Wang Xiaochun, Gao Changyu
    New Chemical Materials. 2025, 53(9): 165-169. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.014
    Abstract ( )   Knowledge map   Save
    Intrinsic self-healing SA/GEL hydrogels were synthesized by using sodium alginate (SA) and gelatin (GEL) as copolymer monomers.The self-healing effect of the hydrogels was verified through the characterization and testing of microscopic morphology,mechanical properties,and dissolution properties,etc.,and the optimized conditions for the preparation of hydrogels were determined.The results showed that the self-healing ability of SA/GEL hydrogel was mainly due to the formation of borate bond,and the self-healing ability could be effectively improved by adjusting the mass concentration of SA,GEL and the mass concentration of the total reactants.When the mass concentration of SA was 0.035g/mL,the mass concentration of GEL was 0.035g/mL,and the mass concentration of borax was 0.0175g/mL,the self-healing of the hydrogel was best,with an elongation at break of 550% after self-healing.When the self-healing time was 7h,the hydrogel had the best self-healing effect,and the hydrogel could still maintain a high elongation rate after many breaks and repairs,indicating the stability and durability of its network structure.
  • Qu Jiayu, Liu Wenyan, Li Zhichao, Zhang Yafa, Zhao Hongxuan
    New Chemical Materials. 2025, 53(9): 170-174. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.007
    Abstract ( )   Knowledge map   Save
    Conductive carbon black was dispersed in an epoxy resin system,and honeycomb absorbing materials with varying carbon black contents and impregnation times were prepared by impregnation method.The wave absorbing performance of the honeycomb materials at 4~18GHz and 26.5~40GHz was tested by the bow method.Incident electromagnetic waves were reflected and absorbed between the honeycomb walls with the wave absorbing performance for many times,achieving the materials' wide bandwidth absorption for electromagnetic waves.The reflectance trend,frequency bandwidth and coverage rate of honeycomb absorbing materials in different wave bands were analyzed by experiments,and the absorption properties of honeycomb absorbing materials with different carbon black contents and thicknesses were compared.The results showed that with the increase of carbon black content and impregnation times,the carbon black content attached to the aramid paper honeycomb gradually increased,the wave absorption performance was continuously improved at first,and the wave absorption performance decreased after the carbon black content reached a certain value.The absorbing properties of the materials with carbon black mass fraction of 20% and impregnation times of 3 and 4 were improved in different degrees at 4~18GHz,and the broadband absorption effect was good.The optimal thickness of the aramid paper honeycomb core was 4mm.With the increase of aramid honeycomb core thickness,the absorption performance of the materials with 20% carbon black mass fraction and 3 impregnation times decreased at 26.5~40GHz,and the optimal thickness of aramid honeycomb core was 2mm.
  • Zhou Yihui, Yi Shi, Shen Yanjin, Hou Zhihua, Lei Xiping
    New Chemical Materials. 2025, 53(9): 175-179. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.003
    Abstract ( )   Knowledge map   Save
    In this paper,sinusoidal alternating current coagulation (SACC) method was used to prepare nano α-FeOOH adsorbent with large specific surface area and high charge density for the removal of Ni2+,Zn2+ and Cu2+ from water.The α-FeOOH adsorbent was analyzed and characterized by scanning electron microscopy (SEM),energy-dispersive spectroscopy (EDS),X-ray diffraction (XRD),Fourier-transform infrared spectroscopy (FT-IR),and X-ray photoelectron spectroscopy (XPS).The adsorption properties of α-FeOOH in monometallic and polymetallic competitive systems were investigated and the removal mechanism of heavy metal ions (Ni2+,Zn2+ and Cu2+) in electroflocculation reaction system was analyzed.The results showed that α-FeOOH prepared by SACC method had a large specific surface area and a high affinity for heavy metal ions.During the adsorption of monometallic ions,the adsorption capacity of α-FeOOH for Cu2+ was higher than that of Ni2+ and Zn2+,and the adsorption selectivity of the metal was Cu2+>Ni2+>Zn2+.The maximum adsorption capacities of Ni2+,Zn2+ and Cu2+ in monometallic systems were 56.3mg/g,52.5mg/g and 60mg/g,respectively.The maximum adsorption capacities in polymetallic system of Ni2+,Zn2+ and Cu2+ were 43.3mg/g,35.6mg/g and 52.1mg/g,respectively.The main removal mechanism of heavy metal ions (Ni2+,Zn2+,Cu2+) were as follows:the reduction reaction at the electrode (cathode) interface;the formation of Ni(OH)2,Zn(OH)2 and Cu(OH)2 precipitate;and the adsorption and coprecipitation of heavy metal ions by hydroxyl groups on the surface of α-FeOOH.
  • Jiang Daoyong, Deng Weixing, Chen Jihong, Pan Fan, Zhang Pengfei, Wang Yong
    New Chemical Materials. 2025, 53(9): 180-186. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.027
    Abstract ( )   Knowledge map   Save
    The salicylic aldehyde derivative ligand,3,5-dibromosalicylaldehyde-o-phenylenediamine (H2L),and its three transition systems Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ) metal complexes were synthesized.The structures of the ligand and complexes were characterized by 1H-NMR,MS and FT-IR and elemental analysis.The thermal stability of complexes was investigated.The TG-DTG tests showed that the three complexes had good thermal stability.The photophysical properties of the complexes were studied by UV-Vis absorption spectroscopy,fluorescence excitation and emission spectra and DFT calculations.Among them,the ZnL·H2O complexes' energy band structure model was constructed and its optical band gap was obtained to be 2.62eV.At the same time,the ligand and its metal complexes were also screened against S.aureus,E.coli and E.herbicola.The antibacterial screening data indicated that both ligand and complexes exhibited certain antibacterial effects,and the antibacterial activity of the complexes were better than that of the ligand.Metal elements were important factors affecting the antibacterial activity of the complexes.Moreover,ZnL·H2O had low cytotoxicity and was successfully applied in HeLa cell tracing and imaging.
  • Wu Wei, Zhu Xiang, Li Haining, Yuan Chaosheng
    New Chemical Materials. 2025, 53(9): 187-191. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.020
    Abstract ( )   Knowledge map   Save
    In this work,the degradation behavior of 1-butyl-3-methylimidazole hexafluorophosphate (BMIMPF6) under different temperature and pressure conditions and the influence of SiO2 on its degradation behavior were researched.The BMIMPF6 and BMIMPF6/SiO2 were subjected to various treatments,including high pressure at room temperature,high temperature at low pressure,and high temperature at high pressure by using a piston cylinder and a double-sided top press.The structure and composition of the treatment products were analyzed by Fourier transform infrared spectroscopy (FT-IR),Raman spectroscopy (Raman) and nuclear magnetic resonance (NMR) analysis.The results showed that the ionic liquid BMIMPF6 underwent partial thermal degradation at 120℃,0.1MPa and 1000MPa.However,the pressure did not significantly change the thermal degradation behavior of the ionic liquid.Under the same temperature and pressure conditions,the thermal degradation reaction of the ionic liquid BMIMPF6 was deeper when silica was involved.The thermal degradation mechanism of ionic liquid BMIMPF6 was analyzed from the perspective of chemical reaction paths,and the possible thermal degradation reaction process of liquid BMIMPF6 with the participation of silica was given.
  • Li Zhaohui, Fan Tingting
    New Chemical Materials. 2025, 53(9): 192-196. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.040
    Abstract ( )   Knowledge map   Save
    Fe-(H3BTC/H2BDC)/PAN (BBP) composites were prepared by in-situ growth method using polyacrylic fiber (PAN) as the substrate,ferrous sulfate heptahydrate (FeSO4·7H2O) as the metal salt,and trimesic acid (H3BTC) and terephthalic acid (H2BDC) as the dual ligands.The effect of ligand ratio on the photocatalytic performance of BBP composites was investigated using reactive black KN-B as the decolorization object.The appearance morphology,phase structure,and pore structure of the composites were analyzed by SEM,XRD,and SBET characterization methods.The influence of inorganic salts and surfactant components in printing and dyeing wastewater on the photocatalytic degradation performance of BBP composites was explored.The reusability and photocatalytic decolorization mechanism of the composites were studied.The results showed that the decolorization effect of BBP composite prepared with a ligand H3BTC and H2BDC ratio of 1∶1 was the best.By adding 0.08mL/L of 30% H2O2 to 50mg/L of reactive black KN-B dye solution and treating under 1000W xenon light for 30min,the decolorization rate of the 5g/L composite for the dye reached 96%,and the decolorization rate was 83% after repeated use for 5 times.The addition of inorganic salts and surfactants had inhibitory effects on dye degradation.The inhibitory effects,from strong to weak,were:anionic surfactant SDS,non-ionic surfactant Peregal O,and Na2SO4.In the photocatalytic degradation of dyes,h+ played a major role,while ·O-2 and ·OH played auxiliary roles.
  • Yang Yuzhe, Hu Bin, Hong Yuwen, Luo Ganbin, Fu Dongxue, Cheng Huiling
    New Chemical Materials. 2025, 53(9): 197-203. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.011
    Abstract ( )   Knowledge map   Save
    Using surface imprinting method with Cr(Ⅲ) as the template ion and UiO-66 as the metal organic framework material (MOF),the imprinting conditions were systematically optimized to prepare 19 types of Cr(Ⅲ) ion-imprinted polymers [Cr(Ⅲ)-IIPs] and their corresponding non-imprinted polymers (NIPs).The optimized conditions for preparing the imprinted polymers were as follows:α-methyl acrylic acid as the functional monomer,the molar ratio of template ion to functional monomer and crosslinking agent of 1∶4∶60,the UiO-66 amount of 30.00mg,and ethanol and water (v/v=1∶1) as pore forming solvents.The structure and performance of Cr(Ⅲ)-IIP14 and NIP14 prepared under the optimized conditions were characterized and studied by scanning electron microscopy,Fourier transform infrared spectroscopy and adsorption experiments.The results showed that the Cr(Ⅲ)-IIP14 had an adsorption capacity of 4.61mmol/g for Cr(Ⅲ) ions,an imprinting factor of 1.66,and good adsorption selectivity for the target ions under the coexistence of “competitive ions”.The adsorption behavior of Cr(Ⅲ)-IIP14 conformed to the Freundlich isothermal adsorption model and quasi-second-order kinetic model,and the adsorption process was mainly chemical adsorption and multimolecular layer adsorption.
  • Li Juan, Gao Yahui, Wu Chunlai, Dou Baobao, Zhang Yibo, Zhang Mengqi
    New Chemical Materials. 2025, 53(9): 204-210. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.015
    Abstract ( )   Knowledge map   Save
    BiOBr/α-Bi2O3 heterojunction composites were constructed by in-situ precipitation method,and BiOBr nanosheets were tightly assembled on the surface of α-Bi2O3 microrods.Compared with α-Bi2O3 or BiOBr,BiOBr/α-Bi2O3 heterojunction composites exhibited superior performance for the photocatalytic degradation of ciprofloxacin (CIP) and inactivation of E.coli under visible light.Among them,BOB/BO-3 displayed the optimal photocatalytic activity,achieving a CIP degradation rate of 86.8% at 60 min,and the reaction rate constants were 12.8 and 4.0 times higher than those of α-Bi2O3 and BiOBr.In addition,1×107cfu/mL E.coli were all inactivated by BOB/BO-3 at 100min.Based on the matched band structure,good heterojunction interface and efficient photogenerated carrier separation,BiOBr/α-Bi2O3 heterojunction composites exhibited excellent photocatalytic performance.Hole (h+) and hydroxyl radical (·OH) were the main oxidizing active groups for the degradation of CIP and the destruction of E.coli cells.
  • Quan Mengqiu, Wang Yuqing, Cui Minghui, Chen Jing, Wu Bozhen
    New Chemical Materials. 2025, 53(9): 211-216. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.017
    Abstract ( )   Knowledge map   Save
    Distinguished from traditional polymer materials,polyurethane has a microphase separation structure,which endows it with the excellent ability to adjust performance,and thus the structure of the molecular chain can be adjusted by different modification methods to obtain polyurethane composites with the required properties.Two main modification methods of medical polyurethane in recent years were introduced.The first involved using polyols with different structures as soft segments and combining with different isocyanates or non-isocyanates to prepare polyurethanes,so that their structures and properties were varied.The second method was adding fillers to further modify the existing structure of polyurethane,so as to increase additional properties such as antibacterial,antioxidant and tissue regeneration on the basis of the original properties,improving the practicality of the material.The article also introduced the specific application of polyurethane in the biomedical field.Finally,the modification methods and applications of biomedical polyurethane materials were prospected and summarized.
  • Shi Shuangyou, Shi Yongming, Zhu Jintang, Hu Zhiyu, Cui Ning, Shi Xianning, Wu Pengfei
    New Chemical Materials. 2025, 53(9): 217-222. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.041
    Abstract ( )   Knowledge map   Save
    Using recycled nylon 6 (PA6) from waste textiles as raw material,regenerated PA6 fibers were successfully prepared via melt spinning at a spinning speed of 3000m/min.The impurity ions in the recycled PA6 and their structures were characterized through elemental analysis,FT-IR and 1H-NMR.Additionally,the stability,thermal properties,and mechanical properties of the regenerated PA6 fibers were investigated using TG,DSC and WAXD.The findings revealed that,compared to pure PA6 fibers,the regenerated PA6 fibers also exhibited commendable thermal stability and dimensional stability.However,an excess of residual Ca2+ in the recycled PA6 could complex with the PA6 fibers and disrupt the intermolecular hydrogen bonding,leading to diminished thermal stability,lower melting point and decreased crystallization temperature of the regenerated PA6 fibers.Furthermore,after stretching and setting,the internal crystal structure of the fibers could not be transformed from γ-phase to α-phase.Moreover,the presence of dyes in the recycled PA6 diminished the fiber's breaking strength.This research offers scientific guidance for the recycling and reuse of PA6 material from waste textiles.
  • Zhou Pucha, An Feng, Teng Na, Liu Yaodong
    New Chemical Materials. 2025, 53(9): 223-227. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.034
    Abstract ( )   Knowledge map   Save
    This study prepared regenerated cellulose fibers by dry-jet wet spinning to investigate the influence of different coagulation bath temperatures and draw ratios on the properties and structure of the fibers.The changes in crystalline structure of the regenerated fibers were systematically studied.The results indicated that the coagulation bath temperature significantly affected the maximum draw ratio and the mechanical properties of the regenerated fibers for the lithium chloride/dimethylacetamide solvent system.The temperature of the coagulation bath had a notable influence on the mechanical properties and microstructure of the fibers.At 0℃,the maximum tensile strength of the fibers reached up to 198MPa,while a maximum tensile modulus of 17.3GPa was achieved at -20℃.With the increase of the draw ratio,the fiber strength and modulus were significantly enhanced,resulting in more regular fiber cross-sections with reduced pore and crack densities.XRD and SEM analyses revealed that lower temperatures favored the formation of dense microstructures and higher crystallinity in fibers.By adjusting coagulation bath temperature and draw ratio,the performance and microstructure of the regenerated cellulose fibers could be significantly improved.
  • Li Longfei, Xu Kangjing, Wang Chunmei
    New Chemical Materials. 2025, 53(9): 228-232. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.030
    Abstract ( )   Knowledge map   Save
    In order to broaden the application of copper-organic framework materials (Cu-BTC) in the fields of adsorption,photocatalysis and antibacterial,PVP/Cu-BTC/wool composites were prepared with layer-by-layer assembly of wool in the mixed solution of (Zn,Cu) hydroxybissalt with polyethylene pyrrolidone (PVP) and 1,3,5-benzenetricarboxylic acid (BTC) solution at room temperature.The chemical composition,crystal structure and morphology of the PVP/Cu-BTC/wool composites were proved by Fourier transform infrared spectroscopy,scanning electron microscopy,energy dispersive spectroscopy,X-ray diffraction and UV-Vis absorption spectra.The liquid-phase adsorption and photocatalytic properties for Cr(Ⅵ) and antibacterial properties of the composites assembled with different numbers of assembly times were tested.The results showed that the adsorption equilibrium of Cr(Ⅵ) on wool and 3-PVP/Cu-BTC/wool composite reached within 30 minutes,and the removal rates were 8.3% and 73.6%,respectively.After 60 minutes of photocatalysis under 1000W xenon light,the removal rate of Cr(Ⅵ) by 3-PVP/Cu-BTC/wool composite was 99.9%,while wool had no photocatalytic removal effect of Cr(Ⅵ).The antibacterial rates of 3-PVP/Cu-BTC/wool composite against Escherichia coli and Staphylococcus aureus were 99.6% and 99.3%,respectively.
  • Li Junhao, He Qian, Li Jun
    New Chemical Materials. 2025, 53(9): 233-236. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.038
    Abstract ( )   Knowledge map   Save
    Lithium-ion batteries are widely used in the fields of consumer electronics,energy storage and new energy vehicles,but there are still some problems,resulting in their service life and cruising range cannot meet the growing demand.How to improve the cycle performance of the battery is very important.The application of self-healing materials in lithium-ion batteries is a hot topic in recent years.In this paper,the structures and mechanisms of two kinds of self-healing materials,i.e.intrinsic type and extrinsic type,were mainly introduced.The application progress of self-healing materials in lithium-ion batteries was reviewed.The research achievements and existing challenges in this field in recent years were summarized,and the future research and development direction was prospected.
  • Sun Zhuangzhuang, Zhang Wentao, Yan Xintao, Wang Kuang, Zhuo Yan, Hou Lin, Liu Jianli, Zhu Bo
    New Chemical Materials. 2025, 53(9): 237-242. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.037
    Abstract ( )   Knowledge map   Save
    To improve the dyeing performance of meta-aramid,different mass fractions of sodium hydroxide (NaOH) solutions were used to pre-regulate the meta-aramid,followed by dyeing with cationic dyes R-29 to investigate the effect of NaOH pre-regulation on the dyeing performance of meta-aramid.The crystalline structure,surface morphology,and chemical structure of meta-aramid were characterized using X-ray diffraction,scanning electron microscopy,and Fourier-transform infrared spectroscopy,respectively.The thermal performance was tested using thermogravimetric analysis.Additionally,the dyeing performance,including the K/S value,dye uptake,dry and wet rubbing fastness,wash fastness,light fastness,and mechanical properties,were evaluated.The results showed that when the mass fraction of NaOH solution was between 10% and 50%,the crystallinity of pre-regulated meta-aramid decreased by 2.4%,2.95%,4.31%,5.01%,and 8.37%,respectively.The fiber surface underwent etching,with amide bonds breaking and new active groups forming.The thermal performance of meta-aramid dyed after 50% NaOH pre-regulation was somewhat lower than that of other samples.Dyeing performance tests indicated that meta-aramid pre-regulated with 40% NaOH exhibited the best dyeing results,with the K/S value and dye uptake increasing by 87.26% and 95.51%,respectively.Wash fastness improved by three grades,light fastness by two grades;the tensile strength and elongation at break of the samples both showed a decline.
  • Zhu Youxin, Li Tong, Wu Shuai, Wang Yulin, Tian Siqiang
    New Chemical Materials. 2025, 53(9): 243-247. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.045
    Abstract ( )   Knowledge map   Save
    Two test specimens were fabricated by combining autoclave molding process and OoA molding process using domestic high-modulus M40J-grade carbon fiber as the reinforcement material and traditional autoclave prepregs and out-of-autoclave (OoA) prepregs with different resin impregnation levels.The internal quality and mechanical properties of the two test specimens were compared through A-scan ultrasonic testing,metallographic testing,and mechanical property testing.The results showed that the A-scan ultrasonic waveforms of the two types of test specimens prepared by the two molding processes had no obvious defects in internal quality.Metallographic testing revealed that the porosity of the autoclave-molded test specimen was 0.06%,and that of the OoA-molded test specimen was 0.11%,both of which were less than the critical porosity that caused a decrease in mechanical properties of the specimens.Mechanical property testing indicated that the average values of tensile,compressive,flexural,and interlaminar shear strengths of the test specimens prepared by the two molding processes differed by 0.65%,3.0%,6.7%,and 2.7%,respectively,and the average values of tensile,compressive,and flexural moduli differed by 0.94%,3.74%,and 3.91%,respectively.In addition,qualified main wing spars of unmanned aerial vehicle (UAV) main load-bearing structural components were fabricated using this domestic high-modulus OoA prepreg,further demonstrating the high feasibility of preparing aerospace main load-bearing structural components with domestic high-modulus OoA prepreg.
  • Liu Yang, Yu Weiwei, Chen Shiling, Li Jiajie, Han Yi, Jiang Qin
    New Chemical Materials. 2025, 53(9): 248-255. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.024
    Abstract ( )   Knowledge map   Save
    With rapid advances in the industrial,agricultural,and pharmaceutical sectors,emerging pollutants are increasingly contaminating aquatic environments.Their strong environmental persistence and biotoxicity present substantial pose significant challenges to water treatment and ecological protection.Nano zero-valent iron (nZVI),as an efficient water pollutant remediation agent,is commonly used to remove emerging contaminants from water.However,nZVI's tendency to agglomerate and deactivate in water,coupled with its limited mobility,can lead to performance degradation.In recent years,advancements have focused on enhancing nZVI stability by using carrier materials to mitigate nanoparticle agglomeration and increase active sites,thereby improving its application potential for water remediation.This article reviewed the synthesis methods of loaded nZVI and discussed the properties and conditions of various loading materials.By summarizing the current status of research on the application of composites to emerging pollutants in water,it explored the future application prospects and potential challenges,aiming to provide insights for the efficient preparation of loaded nZVI and its broad application in managing emerging water pollutants.
  • Luo Gang, Li Zengpeng, Dai Jianfeng, He Chuan, Ma Hong, Jiang Xiaoming
    New Chemical Materials. 2025, 53(9): 256-261. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.046
    Abstract ( )   Knowledge map   Save
    Bismuth oxide (Bi2O3) is a narrow-gap semiconductor photocatalyst that has been widely studied in recent years.Because of its advantages such as non-toxic,adjustable structure,high oxidation capacity,cheap and easy to obtain,it has broad development prospects in the fields of chemical reagents,glass coloring,varistor and anticorrosive coatings.How to improve the photocatalytic activity of bismuth oxide photocatalytic materials and further elucidate the mechanism of the increase in activity have become the focus of research.It is difficult to improve the migration and diffusion efficiency and high specific surface area of the oxygen vacancies in bismuth oxide by conventional electrochemical deposition,hydrothermal method and solid phase method.In view of this,in this paper,Bi2O3/BiFeO3 composite nano-heterojunctions were prepared by coaxial dual-nozzle electrospinning technology at different ratios and concentrations.The structure,morphology and photocatalytic properties of Bi2O3/BiFeO3 composite nano-heterojunctions were further analyzed by Raman spectroscopy,X-ray diffractometer (XRD),scanning electron microscope (SEM),transmission electron microscope (TEM) and other characterization instruments.The results showed that the photocatalytic degradation for methyl orange (MO) of Bi2O3/BiFeO3 nano-heterojunctions with short rod-like structure was greatly improved,and the visible light absorption range was effectively expanded compared with pure phase fibrous Bi2O3 and BiFeO3 nanomaterials.The separation efficiency of photogenerated charge and its utilization of visible light were improved,providing guidance and reference for the subsequent design of bismuth-based nanocomposite photocatalytic materials.
  • Li Zhuolin, Li Jiajie, Han Yi, Chen Shiling, Zhao Sikai, Yu Weiwei
    New Chemical Materials. 2025, 53(9): 262-268. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.039
    Abstract ( )   Knowledge map   Save
    Photocatalytic materials have good application prospects in wastewater treatment and energy production.At present,a variety of photocatalytic materials have been developed and numerous performance improvement strategies have been proposed.Among them,S-type heterojunction Bi-based photocatalytic materials (BSHM) have been widely studied due to their visible light response and high redox performance.The research on the synthesis and application of BSHM is helpful to improve the performance of wastewater treatment and explore the photocatalytic pathway of energy production.By sorting out the synthesis principles,synthesis methods and application effects of BSHM,the energy band conditions that each raw material should meet and the influencing factors of the synthesis process were clarified.it was found that the performance of most BSHM in applications was more than 2 times higher than that of raw materials,and the selectivity of specific products in some studies was more than 80%.On this basis,the reasons for the improvement of BSHM performance and product selectivity were analyzed,providing theoretical support for the environmental application of BSHM and sorting out the research directions for the highly selective output of energy.
  • Wang Bo, Qian Jun, Gao Shuaixiao, Chu Hongqiang, Zhang Chi
    New Chemical Materials. 2025, 53(9): 269-273. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.009
    Abstract ( )   Knowledge map   Save
    A simple one-step hydrothermal method was used to compound red phosphorus and hydrothermal carbon to form a new type of red phosphorus/hydrothermal carbon composite.The structure,microscopic morphology,light-absorbing properties and electrochemical properties of the composite were characterized by X-ray diffraction patterns (XRD),Fourier transform infrared absorption spectroscopy (FT-IR),scanning electron microscopy (SEM),ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS),and electrochemical workstation.The photocatalytic performance of the novel composites was studied using tetracycline hydrochloride (TCH) as the target pollutant,and the photocatalytic mechanism was explored and the reusability was verified.The results showed that the red phosphorus/hydrothermal carbon composites had better photocatalytic performance than single red phosphorus and single hydrothermal carbon.The TCH degradation rate in water by red phosphorus/hydrothermal carbon was 90.5% after 4h of visible light irradiation,which was greatly higher than that of single red phosphorus and single hydrothermal carbon.Superoxide radicals (·O-2) and hydroxyl radicals (·OH) were the main active species in the degradation of TCH.Moreover,the red phosphorus/hydrothermal carbon composites exhibited good recyclability in the reuse experiment.After five cycles,the degradation efficiency of TCH decreased by 3.8% and could still reach more than 86%.    
  • Li Jide, Yang Haikuan, Lu Jiamin, Zhang Shaohong
    New Chemical Materials. 2025, 53(9): 274-278. https://doi.org/10.19817/j.cnki.issn1006-3536.2025.09.002
    Abstract ( )   Knowledge map   Save
    By subtly adjusting the length of aromatic chains and the type of ring bonds,six cholesterol-based gelators with dynamic covalent bonds were synthesized through amine-aldehyde condensation reactions.The gelator molecules,which contained non-covalent bond rings and longer rigid chains,exhibited good gelation abilities and thermal stability.Scanning electron microscopy (SEM) showed that the supramolecular structures of the gels formed by gelators were mainly typical three-dimensional network structures.Fourier transform infrared (FT-IR) suggested that hydrogen bonding were the main driving forces for the formation of the supramolecular gels.Ultraviolet-visible (UV-Vis) indicated that the target gelators formed gels in cyclohexane and could effectively adsorb organic dyes like methyl orange and methylene blue.The adsorption rates were 80.2% and 82.6%,respectively.