Progress in the preparation of fluorinated graphene

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  • 1. School of Environmental and Safety Engineering,North University of China,Taiyuan 030051;
    2. Sichuan Huachuan Industry Co.,Ltd.,Chengdu 610106

Received date: 2020-10-11

  Revised date: 2021-01-22

  Online published: 2021-05-10

Abstract

The new carbon material fluorinated graphene has attracted wide attention due to its unique physical and chemical properties,and has broad application prospects in many fields.The preparation methods of fluorinated graphene were reviewed,including the physical exfoliation method using fluorinated graphite as raw material,the preparation method using different chemical solvents as intercalating agents,and the preparation method using graphene oxide and graphene as raw materials.The advantages and disadvantages of various preparation methods were discussed,and prospected the future development prospects of fluorinated graphene.

Cite this article

Wen Xu, Wang Jianhua, Zhai Siyuan, Zhu Yu, Tan Ming . Progress in the preparation of fluorinated graphene[J]. New Chemical Materials, 2021 , 49(3) : 5 -8 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.03.002

References

[1] Nair R R,Ren W,Jalil R,et al.Fluorographene:a two-dimensional counterpart of teflon[J].Small,2015,6(24):2877-2884.
[2] Worsley K A,Ramesh P,Mandal S K,et al.Soluble graphene derived from graphite fluoride[J].Chemical Physics Letters,2007,445(1/2/3):51-56.
[3] Pilao R,Ramalho E,Pinho C.Overall characterization of cork dust explosion[J].Journal of Hazardous Materials,2006,133(1/2/3):183-195.
[4] 郑帅周,周琦,杨生荣,等.氟化石墨烯的制备及其作为润滑油添加剂的摩擦学性能研究[J].摩擦学学报,2017,37(3):402-408.
[5] Zhang M,Liu L,He T,et al.Melamine assisted solid exfoliation approach for the synthesis of few-layered fluorinated graphene nanosheets[J].Materials Letters,2016,171(15):191-194.
[6] Liu Lin,Zhang Miao,Xiong Zhitao,et al.Ammonia borane assisted solid exfoliation of graphite fluoride for facile preparation of fluorinated graphene nanosheets[J].Carbon,2015,81:702-709.
[7] Wang Z,Wang J,Li Z,et al.Cooperatively exfoliated fluorinated graphene with full-color emission[J].RSC Advances,2012,2(31):11681-11686.
[8] 白瑞,卢翠英,高平强.低介电聚酰亚胺/氟化石墨烯复合薄膜的制备及表征[J].表面技术,2017,46(1):44-47.
[9] Zhang Min,Ma Yaochen,Zhu Yinyan,et al.Two-dimensional transparent hydrophobic coating based on liquid-phase exfoliated graphene fluoride[J].Carbon,2013,63:149-156.
[10] 康文泽,李尚益,刘玉.氧化法制备氟化石墨烯及其性能研究[J].炭素技术,2018,37(2):32-36.
[11] Bourlinos A B,Georgakilas V,Zboril R,et al.Reaction of graphite fluoride with NaOH-KOH eutectic[J].Journal of Fluorine Chemistry,2008,129(8):720-724.
[12] Radek Z,Karlicky F,Bourlinos A B,et al.Graphene fluoride:a stable stoichiometric graphene derivative and its chemical conversion to graphene[J].Small,2015,6(24):2885-2891.
[13] Gong P,Wang Z,Wang J,et al.One-pot sonochemical preparation of fluorographene and selective tuning of its fluorine coverage[J].Journal of Materials Chemistry,2012,22(33):16950-16956.
[14] Athanasios B,Klara Safarova,Karolina Siskova,et al.The production of chemically converted graphenes from graphite fluoride[J].Carbon,2012,50:1425-1428.
[15] Yang Y,Lu G,Li Y,et al.One-step preparation of fluorographene:a highly efficient,low-cost,and large-scale approach of exfoliating fluorographite[J].ACS Appl Mater Interfaces,2013,5(24):13478-13483.
[16] Kang W Z,Li Shangyi.Preparation of fluorinated graphene to study its gas sensitivity[J].RSC Advances,2018,8(41):23459-23467.
[17] Herraiz M,Dubois M,Batisse N,et al.Large-scale synthesis of fluorinated graphene by rapid thermal exfoliation of highly fluorinated graphite[J].Dalton Transactions,2017,47(13):4596-4606.
[18] Zhu M S,Xie X D,Guo Y L,et al.Fluorographene nanosheets with broad solvent dispersibility and their applications as a modified layer in organic field-effect transistors[J].Physical Chemistry Chemical Physics,2013,15(48):20992-21000.
[19] Li H,Hou G,Tian Q,et al.Preparation of fluorinated graphene oxide with different oxygen content and its superhydrophobic property[J].Materials Research Express,2018,6(4):1-10.
[20] Chang H,Cheng J,Liu X,et al.Facile synthesis of wide-bandgap fluorinated graphene semiconductors[J].Chemistry-A European Journal,2011,17(32):8896-8903.
[21] 何云凤,顾健,李磊,等.简捷水热法制备氟化石墨烯及其表征[J].材料导报,2018,32(z1):141-143;148.
[22] 蒲琳钰,马拥军,胡海龙,等.水热法制备氟化石墨烯[J].西南科技大学学报,2012,27(3):18-22.
[23] 徐龙华.氟化石墨烯/超高分子量聚乙烯复合材料的制备和性能研究[D].兰州:兰州大学,2016.
[24] Wang Z,Wang J,Li Z,et al.Synthesis of fluorinated graphene with tunable degree of fluorination[J].Carbon,2012,50:5403-5410.
[25] Zhu W,Wu C,Chang Y,et al.Solvent-free preparation of hydrophilic fluorinated graphene oxide modified with amino-groups[J].Materials Letters,2019,237(15):1-4.
[26] Zhou Baoming,Qian Xiaoming,Li Mingming,et al.Tailoring the chemical composition and dispersion behavior of fluorinated graphene oxide via CF4 plasma[J].Journal of Nanoparticle Research,2015,17(3):1-12.
[27] Zhao F G,Zhao G,Liu X H,et al.Fluorinated graphene:facile solution preparation and tailorable properties by fluorine-content tuning[J].Journal of Materials Chemistry A,2014,2(23):8782-8789.
[28] Zhang H,Fan L,Dong H,et al.Spectroscopic investigation of plasma-fluorinated monolayer graphene and application for gas sensing[J].ACS Applied Materials & Interfaces,2016,8(13):8652-8661.
[29] Bi Xu,Li Yanyan,Qiu Zhipeng,et al.Fluorinated graphene prepared by direct fluorination of N,O-doped graphene aerogel at different temperatures for lithium primary batteries[J].Materials,2018,11(7):1-11.
[30] Jeon K J,Lee Z,Pollak E,et al.Fluorographene:a wide bandgap semiconductor with ultraviolet luminescence[J].ACS Nano,2011,5(2):1042-1046.
[31] Nebogatikova N A,Antonova I V,Prinz V Ya,et al.Fluorinated graphene dielectric films obtained from functionalized graphene suspension:preparation and properties[J].Physical Chemistry Chemical Physics,2015,17(20):13257.
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