Metal organic frameworks (MOFs) are new type of porous polymer materials.Their discovery and development are considered as one of the most important chemical breakthroughs in recent decades.Zr-MOFs materials are one of the important branches of metal organic framework materials.They have outstanding stability and comprehensive functional applications in many other fields,such as catalysis,adsorption,sensing and photocatalysis.Therefor the classification,synthesis and application in gas storage,adsorption and photocatalysis of Zr MOFs were introduced.The development of Zr MOFs were also prospected.
Zhu Lingfeng, Wang Xuewei, Xu Yun, An Ran, Zhou Yonghong
. Research progress on classification,synthesis and application of Zr-MOFs[J]. New Chemical Materials, 2021
, 49(4)
: 238
-241
.
DOI: 10.19817/j.cnki.issn1006-3536.2021.04.052
[1] Zhou H C,Long J R,Yaghi O M.Introduction to metal-organic frameworks[J].Chemical Reviews,2012,112(2):673-674.
[2] Bai Y,Dou Y B,Xie L H,et al.Zr-based metal-organic frameworks:design,synthesis,structure,and applications[J].Chem Soc Rev,2016,45:2327-2367.
[3] Cavka J H,Jakobsen S,Olsbye U,et al.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability[J].J Am Chem Soc,2008,130(42):13850-13851.
[4] 韩易潼.锆基金属-有机骨架UiO-66的调控合成研究[D].大连:大连理工大学,2018.
[5] Schaate A,Roy P,Godt A,et al.Modulated synthesis of Zr-based metal-organic frameworks:from nano to single crystals[J].Chemistry-A European Journal,2011,17:6643-6651.
[6] Yao M,Lv X,Fu Z,et al.Layer-by-layer assembled conductive metal-organic framework nanofilms for room-temperature chemiresistive sensing[J].Angewandte Chemie International Edition,2017,56:52-59.
[7] Zheng J,Ye J,Ortuño M,et al.Selective methane oxidation to methanol on Cu-oxo dimers stabilized by zirconia nodes of an NU-1000 metal-organic framework[J].Journal of the American Chemical Society,2019,141:9292-9304.
[8] Bon V,Senkovskyy V,Senkovska I.et al.Zr(Ⅳ) and Hf(Ⅳ) based metal-organic frameworks with reo-topology[J].Chem Commun,2012,48:8407-8409.
[9] Bon V,Senkovska I,Baburin I A,et al.Zr- and Hf-based metal-organic frameworks:tracking down the polymorphism[J].Cryst Growth Des,2013,13:1231-1237.
[10] Tang Y,Wang C,Chen S,et al.A terbium(Ⅲ) organic framework as a fluorescent probe for selectively sensing of organic small molecules and metal ions especially nitrobenzene and Fe3+[J].Journal of Coordination Chemistry,2017,70:24-46.
[11] Ou S,Wu C.Rational construction of metal-organic frameworks for heterogeneous catalysis[J].ChemInform,2014,45:52-80.
[12] Ikezoe Y,Washino G,Uemura T,et al.Autonomous motors of a metal-organic framework powered by reorganization of self-assembled peptides at interfaces[J].Nature Materials,2012,11:12-28.
[13] Dang G,Nguyen D,Le D,et al.Propargylamine synthesis via direct oxidative CC coupling reaction between N,N-dimethylanilines and terminal alkynes under metal-organic framework catalysis[J].Journal of Molecular Catalysis A Chemical,2014,120:395-433.
[14] Li S,Lan Y,Sakurai H,et al.Unusual regenerable porous metal-organic framework based on a new triple helical molecular necklace for separating organosulfur compounds[J].Chemistry-A European Journal,2012,18:51-69.
[15] Ren J W,Langmi H W,North B C,et al.Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications[J].International Journal of Hydrogen Energy,2014,39:890-895.
[16] Chavan S,Vitillo J G,Gianolio D,et al.H2 storage in isostructural UiO-67 and UiO-66 MOFs[J].Phys Chem Chem Phys,2012,14:1614-1626.
[17] Kandiah M,Nilsen M H,Usseglio S,et al.Synthesis and stability of tagged UiO-66 Zr-MOFs[J].Chem Mater,2010,22:6632-6640.
[18] Xu J,Liu J,Li Z,et al.Optimized synthesis of Zr(Ⅳ) metal organic frameworks (MOFs-808) for efficient hydrogen storage[J].New J Chem,2019,43:4092-4099.
[19] 赵辉.新型MOFs分子基材料的设计合成与性能研究[D].郑州:郑州轻工业学院,2016.
[20] 罗剑锋.调控Zr-MOFs晶面缺陷及其去除重金属离子性能的研究[D].南昌:南昌航空大学,2018.
[21] 黄宏亮.金属有机骨架材料的合成与吸附分离性能研究[D].北京:北京化工大学,2014.
[22] Zhang W,Huang H,Liu D,et al.A new metal-organic framework with high stability based on zirconium for sensing small molecules[J].Micro Meso Mater,2013,171:118-124.
[23] Silva C G,Luz I,Xamena F X L,et al.Water stable Zr-benzenedicarboxylate metal-organic frameworks as photocatalysts for hydrogen generation[J].Chem Eur J,2010,16:11133-11138.
[24] Jin Z L,Yang H.Exploration of Zr-metal-organic framework as efficient photocatalyst for hydrogen production[J].Nanoscale Research Letters,2017,12:539-549.
[25] Yuan S,Qin J S,Xu H Q,et al.[Ti8Zr2O12(COO)16] cluster:an ideal inorganic building unit for photoactive metal}organic frameworks[J].ACS Cent Sci,2018,4:105-111.
[26] 徐海群.Zr基MOFs的控制合成及其在光催化中的性能与机理研究[D].合肥:中国科学技术大学,2018.
