Research progress in preparation and modification of PACF

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  • 1.Key Laboratory of Coal Science and Technology,Taiyuan University of Technology,Taiyuan 030024;
    2.College of Textile Engineering,Taiyuan University of Technology,Jinzhong 030600

Online published: 2020-10-20

Abstract

The phenolic-based virgin fiber is obtained by spinning a synthetic phenolic resin into phenolic fiber,and the raw yarn is cured,carbonized and activated to form a phenolic-based activated carbon fiber(PACF) with high specific surface area,uniform pore diameter and good electrical conductivity.Firstly,the preparation process of PACF was introduced.The synthesis of phenolic resin and the preparation method of phenolic-based virgin fiber were briefly summarized.The preparation methods mainly included wet spinning,melt spinning and electrospinning,etc.The carbonization and activation processes and method were summarized.The research progress on the structure,properties,application and modification of PACF was expounded.Finally,the future development direction of PACF was prospected.

Cite this article

Wang Huijuan, Lu Jianjun, Lian Dandan, Liu Miaoqing . Research progress in preparation and modification of PACF[J]. New Chemical Materials, 2020 , 48(10) : 236 -240 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.10.050

References

[1] 刘佳宁, 侯秋飞, 胡若飞, 等.酚醛树脂改性及应用概述[J].科技创业月刊, 2016, 29(11):134-136.
[2] 王静, 李琳, 刘云红.改性酚醛树脂复合材料的研究进展及应用[J].工程技术, 2016(12):00206-00206.
[3] 孙龙梅, 张丽平, 薛建华, 等.活性炭制备方法及应用的研究进展[J].化学与生物工程, 2016(3):5-8.
[4] Yuan H, Wang C, Zhang S, et al.Effect of surface modification on carbon fiber and its reinforced phenolic matrix composite[J].Applied Surface Science, 2012, 259(none):288-293.
[5] Singh S, Srivastava A, Singh S P.Inexpensive, effective novel activated carbon fibers for sample cleanup:application to multipesticide residue analysis in food commodities using a QuEChERS method[J].Analytical and Bioanalytical Chemistry, 2018, 410(8):2241-2251.
[6] 杨常玲, 孙彦平, 邴雪飞, 等.用作超级电容器电极材料的酚醛树脂基活性炭[J].电子元件与材料, 2009(10):15-17.
[7] 张明.聚苯胺/酚醛树脂基活性炭复合材料的制备及表征[J].当代化工, 2018, 47(2):268-271.
[8] 赵丽红, 史景利, 翟更太, 等.腰果壳油改性酚醛纤维的制备及性能研究[J].合成纤维, 2008, 37(12):1-4.
[9] Liu C L, Dong W S, Song J R, et al.Evolution of microstructure and properties of phenolic fibers during carbonization[J].Materials Science & Engineering A (Structural Materials:Properties, Microstructure and Processing), 2007, 459(1-2):347-354.
[10] 黄婧, 文婕, 江成发, 等.酚醛树脂基多孔炭的制备及应用研究进展[J].功能材料, 2015, 46(1):1016-1021.
[11] Oya A, Kimura M, Sugo T, et al.Antibacterial activated carbon fibre derived from phenolic resin fibre by use of co-graftpolymerization[J].Journal of Materials Science, 1993, 28(17):4731-4734.
[12] 杜玉泉, 吴昊, 冯启恒.水溶性酚醛树脂合成及其层压板的制备研究[J].橡塑技术与装备, 2019, 45(4):37-44.
[13] Foyer G, Chanfi B H, Boutevin B, et al.New method for the synthesis of formaldehyde-free phenolic resins from lignin-based aldehyde precursors[J].European Polymer Journal, 2016, 74:296-309.
[14] Bai Y, Huang Z H, Kang F.Electrospun preparation of microporous carbon ultrafine fibers with tuned diameter, pore structure and hydrophobicity from phenolic resin[J].Carbon, 2014, 66:705-712.
[15] Shrivastava S, Srivastava A K, Singh B, et al.Study on phenolic resin beads:effect of reaction parameters on the properties of polymeric beads[J].Journal of Applied Polymer Science, 2012, 123(6):3741-3747.
[16] Zhang D, Shi J, Guo Q, et al.Preparation mechanism and characterization of a novel, regulable hollow phenolic fiber[J].Journal of Applied Polymer Science, 2007, 104(4):2108-2112.
[17] 王迎.静电纺丝法制备酚醛树脂碳化纤维及其性能研究[D].北京:北京化工大学, 2017.
[18] Jin Z H, Wang L, Li F F, et al.Synthesis and characteration of phenolic resin/montmorillonite nanocomposites[C].Banff:International Conference on Mems.IEEE, 2004.
[19] 焦明立, 张彩云, 曹健, 等.酚醛基活性炭纤维静电纺丝制备的研究进展[J].炭素技术, 2018, 37(2):13-17.
[20] Liu Y Z, Li Y F, Yang Y G, et al.Preparation and properties of graphene oxide-carbon fiber/phenolic resin composites[J].Carbon, 2013, 52:624.
[21] 云庆跃.酚醛基活性炭纤维的制备、改性及其性能研究[D].太原:太原理工大学, 2018.
[22] 刘永卫, 曹春锋, 武彤, 等.活性炭纤维的生产工艺和应用[J].河北工业科技, 2008, 25(1):57-61.
[23] Wei X Q, Li Q H, Li H C, et al.The use of ZnCl2 activation to prepare low-cost porous carbons coated on glass fibers using mixtures of Novolac, polyethylene glycol and furfural as carbon precursors[J].New Carbon Materials, 2015, 30(6):579-586.
[24] Zhou H, Huang G S, Gao P, et al.Preparation of porous/hollow particles of phenolic resin[J].Polymers for Advanced Technologies, 2007, 18(7):582-585.
[25] 唐政.碳基复合材料用于船舶机舱含油污水处理的研究[D].厦门:集美大学, 2018.
[26] 代晓东, 刘欣梅, 钱岭, 等.物理化学耦合活化法制备活性炭[J].炭素技术, 2008, 27(4):30-34.
[27] Liu Y Z, Li Y F, Yang Y G, et al.Preparation and properties of graphene oxide-carbon fiber/phenolic resin composites[J].Carbon, 2013, 52(Complete):624.
[28] 张玉芹, 秦军, 陈明鸣, 等.活化温度对酚醛基活性炭纤维的孔结构和电化学性能的影响[C].天津:炭—石墨材料学术会议, 2008.
[29] Jiao M, Yang K, Diao Q, et al.Effect of monophenyl borate on properties of high-ortho phenolic fibers[J].Fibers and Polymers, 2017, 18(5):875-881.
[30] Ying Y G, Pan Y P, Ren R, et al.Effect of the molecular structure of phenolic novolac precursor resins on the properties of phenolic fibers[J].Materials Chemistry and Physics, 2013, 143(1):455-460.
[31] 李颖, 陈夫山, 王德宝.炭化温度对酚醛基活性炭纤维吸附性的影响[J].造纸科学与技术, 2017(4):16-19, 29.
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