Liu Tianli, Liu Yan, Gong Qinghua, Zhou Guowei . Research progress on preparation and application in energy storage of multi-shell transition metal oxide hollow spheres[J]. New Chemical Materials, 2020 , 48(8) : 12 -17 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.08.003

[1] Wang J,Cui Y,Wang D.Design of hollow nanostructures for energy storage,conversion and production[J].Advanced Materials,2018,31(38):1801993.
[2] Zhu W,Chen Z,Pan Y,et al.Functionalization of hollow nanomaterials for catalytic applications:nanoreactor construction[J].Advanced Materials,2018,31(38):1800426.
[3] Qi J,Lai X,Wang J,et al.Multi-shelled hollow micro-/nanostructures[J].Chemical Society Reviews,2015,44(19):6749-6773.
[4] Yu L,Hu H,Wu H B,et al.Complex hollow nanostructures:synthesis and energy-related applications[J].Advanced Materials,2017,29(15):1604563.
[5] Zhang P,Guan B Y,Yu L,et al.Facile synthesis of multi-shelled ZnS-CdS cages with enhanced photoelectrochemical performance for solar energy conversion[J].Chemistry,2018,4(1):162-173.
[6] Wang B,Li R,Zhang Z,et al.Novel Au/Cu₂O multi-shelled porous heterostructures for enhanced efficiency of photoelectrochemical water splitting[J].Journal of Materials Chemistry A,2017,5(27):14415-14421.
[7] Qu F,Shang W,Wang D,et al.Coordination polymer-derived multishelled mixed Ni-Co oxide microspheres for robust and selective detection of xylene[J].ACS Applied Materials & Interfaces,2018,10(17):15314-15321.
[8] Peng S,Gong F,Li L,et al.Necklace-like multishelled hollow spinel oxides with oxygen vacancies for efficient water electrolysis[J].Journal of the American Chemical Society,2018,140(42):13644-13653.
[9] Jang J Y,Le T M D,Ko J H,et al.Triple-,double-,and single-shelled hollow spheres of sulfonated microporous organic network as drug delivery materials[J].Chemistry of Materials,2019,31(2):300-304.
[10] Wu H,Wang Y,Zheng C,et al.Multi-shelled NiO hollow spheres:easy hydrothermal synthesis and lithium storage performances[J].Journal of Alloys and Compounds,2016,685:8-14.
[11] Li H,Ma H,Yang M,et al.Highly controlled synthesis of multi-shelled NiO hollow microspheres for enhanced lithium storage properties[J].Materials Research Bulletin,2017,87:224-229.
[12] Qi X,Zheng W,Li X,et al.Multishelled NiO hollow microspheres for high-performance supercapacitors with ultrahigh energy density and robust cycle life[J].Scientific Reports,2016,6(1):33241.
[13] Chen X,Zhang D,Zhang H,et al.Controllable synthesis of mesoporous multi-shelled ZnO microspheres as efficient photocatalysts for NO oxidation[J].Applied Surface Science,2018,435:468-475.
[14] Wu G,Jia Z,Cheng Y,et al.Easy synthesis of multi-shelled ZnO hollow spheres and their conversion into hedgehog-like ZnO hollow spheres with superior rate performance for lithium ion batteries[J].Applied Surface Science,2019,464:472-478.
[15] Wang S,Zhang X,Li S,et al.C-doped ZnO ball-in-ball hollow microspheres for efficient photocatalytic and photoelectrochemical applications[J].Journal of Hazardous Materials,2017,331:235-245.
[16] Li Y,Wang S,Hao P,et al.Soft-templated formation of double-shelled ZnO hollow microspheres for acetone gas sensing at low concentration/near room temperature[J].Sensors and Actuators B:Chemical,2018,273:751-759.
[17] Wang J,Tang H,Zhang L,et al.Multi-shelled metal oxides prepared via an anion-adsorption mechanism for lithium-ion batteries[J].Nature Energy,2016,1(5):16050.
[18] Guo F F,Fan M H,Jin P P,et al.Precursor-mediated synthesis of double-shelled V₂O₅ hollow nanospheres as cathode material for lithium-ion batteries[J].Crystengcomm,2015,18(22):4068-4073.
[19] Wang Y,Nie Z,Pan A,et al.Self-templating synthesis of double-wall shelled vanadium oxide hollow microspheres for high-performance lithium ion batteries[J].Journal of Materials Chemistry A,2018,6(16):6792-6799.
[20] Zu L,Su Q,Zhu F,et al.Antipulverization electrode based on low-carbon triple-shelled superstructures for lithium-ion batteries[J].Advanced Materials,2017,29(34):1701494.
[21] Wu H,Wu G,Ren Y,et al.Multishelled metal oxide hollow spheres:easy synthesis and formation mechanism[J].Chemistry,2016,22(26):8864-8871.
[22] Armutlulu A,Naeem M A,Liu H,et al.Multishelled CaO microspheres stabilized by atomic layer deposition of Al₂O₃ for enhanced CO₂ capture performance[J].Advanced Materials,2017,29(41):1702896.
[23] Wang Y,Yu L,Lou X W.Formation of triple-shelled molybdenum-polydopamine hollow spheres and their conversion into MoO₂/carbon composite hollow spheres for lithium-ion batteries[J].Angew Chem Int Ed Engl,2016,55(47):14668-14672.
[24] Zong L,Xu J,Jiang S,et al.Composite yttrium-carbonaceous spheres templated multi-shell YVO₄ hollow spheres with superior upconversion photoluminescence[J].Advanced Materials,2017,29(9):1604377.
[25] Qi X,Zheng W,He G,et al.NiCo₂O₄ hollow microspheres with tunable numbers and thickness of shell for supercapacitors[J].Chemical Engineering Journal,2017,309:426-434.
[26] Song X,Qiao L,Sun K,et al.Triple-shelled ZnO/ZnFe₂O₄ heterojunctional hollow microspheres derived from Prussian blue analogue as high-performance acetone sensors[J].Sensors & Actuators:B.Chemical,2018,256:374-382.
[27] Han Y,Mu J,Li X,et al.Triple-shelled NiMn₂O₄ hollow spheres as an efficient catalyst for low-temperature selective catalytic reduction of NO_x with NH₃[J].Chemical Communications,2018,54(70):9797-9800.
[28] Wu L,Wang Z,Long Y,et al.Multishelled Ni_xCo_3-xO₄ hollow microspheres derived from bimetal-organic frameworks as anode materials for high-performance lithium-ion batteries[J].Small,2017,13(17):1604270.
[29] Lu Y,Nai J,Lou X W D.Formation of NiCo₂V₂O₈ yolk-double shell spheres with enhanced lithium storage properties[J].Angewandte Chemie-International Edition,2018,57(11):2899-2903.
[30] Luo D,Deng Y,Wang X,et al.Tuning shell numbers of transition metal oxide hollow microspheres toward durable and superior lithium storage[J].ACS Nano,2017,11(11):11521-11530.
[31] Rajabzadeh M,Khalifeh R,Eshghi H,et al.A facile hydrothermal synthesis of novel hollow triple-shell CuNiFe₂O₄ nanospheres with robust catalytic performance in the Suzuki-Miyaura coupling reaction[J].Journal of Catalysis,2018,360:261-269.
[32] Yang J,Zeng D,Zheng H,et al.3D graphene encapsulated ZnO-NiO-CuO double-shelled hollow microspheres with enhanced lithium storage properties[J].Journal of Alloys and Compounds,2018,765:1158-1166.
[33] Guan B Y,Kushima A,Yu L,et al.Coordination polymers derived general synthesis of multishelled mixed metal-oxide particles for hybrid supercapacitors[J].Advanced Materials,2017,29(17):1605902.
[34] Wang Y,Pan A,Zhang Y,et al.Heterogeneous NiS/NiO multi-shelled hollow microspheres with enhanced electrochemical performances for hybrid-type asymmetric supercapacitors[J].Journal of Materials Chemistry A,2018,6(19):9153-9160.
[35] Zheng M,Tang H,Li L,et al.Hierarchically nanostructured transition metal oxides for lithium-ion batteries[J].Advanced Science,2018,5(3):1700592.
[36] Qi Y,Liu B,Zhang L,et al.One-pot controllable synthesis of CoFe₂O₄ solid,hollow and multi-shell hollow nanospheres as superior anode materials for lithium ion batteries[J].Journal of Materials Chemistry A,2017,5(41):21994-22003.
[37] Wu G,Jia Z,Cheng Y,et al.Easy synthesis of multi-shelled ZnO hollow spheres and their conversion into hedgehog-like ZnO hollow spheres with superior rate performance for lithium ion batteries[J].Applied Surface Science,2019,464:472-478.
[38] Yin J,Zhang Y,Lu Q,et al.Tunable Co₃O₄ hollow structures (from yolk-shell to multi-shell) and their Li storage properties[J].Journal of Materials Chemistry A,2017,5(25):12757-12761.
[39] Shin H,Lee W.Multi-shelled MgCo₂O₄ hollow microspheres as anodes for lithium ion batteries[J].Journal of Materials Chemistry A,2016,4(31):12263-12272.
[40] Xie F,Zhang L,Ye C,et al.The application of hollow structured anodes for sodium-ion batteries:from simple to complex systems[J].Advanced Materials,2018,31(38):1800492.
[41] Zhao X,Wang J,Yu R,et al.Construction of multishelled binary metal oxides via coabsorption of positive and negative ions as a superior cathode for sodium-ion batteries[J].Journal of the American Chemical Society,2018,140(49):17114-17119.
[42] Zhang X,Zhou Y,Luo B,et al.Microwave-assisted synthesis of NiCo₂O₄ double-shelled hollow spheres for high-performance sodium ion batteries[J].Nano-Micro Letters,2018,10(1):117-123.