Preparation of sodium alginate-gangue composite molecular sieves and their methylene blue adsorption properties

  • Chen Guohao ,
  • Li Jiyang ,
  • Liu Gang ,
  • Lang Daning ,
  • Guo Jia ,
  • Wu Ronglan
Expand
  • 1. Key Laboratory of petroleum and Natural Gas Fine Chemicals of Ministry of Education and Xinjaing Uyghur Autonomous Region,School of Chemical Engineering and Technology, Xinjiang University,Urumqi 830046;
    2. Xinjiang Energy Group Co.,Ltd.,Urumqi 830000

Received date: 2024-03-25

  Revised date: 2024-11-26

  Online published: 2025-05-21

Abstract

Sodium alginate-gangue-based molecular sieve composites (SA-CGMS) were prepared by composite calcination using gangue and sodium alginate (SA) as raw materials.The composites were used for the adsorption of methylene blue (MB).The structure was characterized by SEM.The results showed that the prepared composite molecular sieves had an orthotetrahedral structure with smooth surface and sharp corners,and the SA was uniformly attached on the gangue molecular sieves (CGMS).The adsorption experiments revealed that the maximum adsorption capacity of SA-CGMS for MB was 99.824mg/g and the adsorption conformed to the Langmuir model and quasi-secondary kinetic model,which indicated that the adsorption was a monolayer chemisorption.The adsorption process was characterized by interaction forces such as hydrogen bonding and electrostatic interaction.

Cite this article

Chen Guohao , Li Jiyang , Liu Gang , Lang Daning , Guo Jia , Wu Ronglan . Preparation of sodium alginate-gangue composite molecular sieves and their methylene blue adsorption properties[J]. New Chemical Materials, 2025 , 53(5) : 202 -210 . DOI: 10.19817/j.cnki.issn1006-3536.2025.05.026

References

[1] Yang C,Zeng Q H,Guo Z G.Biomimetic seaweed absorbable membrane for dye adsorption in wastewater treatment[J].New Journal of Chemistry,2024,48(11):5018-5024.
[2] 杨虹虹,宋晓婕,王慧南,等.BiOI光催化剂在水污染处理中的研究进展[J].化工新型材料,2023,51(S2):168-173.
[3] Shah S F A,Khitab F,Rasool S,et al.Modified clinoptilolite for the removal of rhodamine B dye from wastewater[J].Sustainability,2024,16(6):2267-2286.
[4] Khajuria A,Kaushal J,Sudan S.Encapsulated cobalt-doped coconut husk biochar (Co@CHBc) for the remediation of anionic dye from wastewater[J].Biomass Conversion and Biorefinery,2024,DOI:10.1007/s13399-024-05378-8.
[5] Singh VK,Sett A,Karmakar S.Waste to wealth:facile activation of red mud waste and insights into industrial reactive dye removal from wastewater[J].Chemical Engineering Journal,2024,481:1385-1406.
[6] Katheresan V,Kansedo J,Lau S Y.Efficiency of various recent wastewater dye removal methods:a review[J].Journal of Environmental Chemical Engineering,2018,6(4):4676-4697.
[7] 高海荣,姜明月,黄振旭,等.磁性黑藻生物炭复合材料的制备及其对水体Cu2+的吸附[J].化工新型材料,2021,49(10):186-190.
[8] 贾可,刘罡,陈仕飞,等.rGO/ZnO纳米复合材料的制备及其光催化降解性能及机理研究[J].化工新型材料,2023,51(6):225-230.
[9] Khulbe K C,Matsuura T.Removal of heavy metals and pollutants by membrane adsorption techniques[J].Applied Water Science,2018,8(1):661-691.
[10] Hu Y S,Han X Y,Sun Z Z,et al.Study on the reactivity activation of coal gangue for efficient utilization[J].Materials (Basel),2023,16(18):6321-6339.
[11] 陶亚东,曾红久,霍军杰,等.煤矸石制备高性能吸水材料的研究[J].化工新型材料,2023,51(5):282-284.
[12] Liu C D,Zhang R,Wang Z X,et al.Research on the fire extinguishing performance of new gel foam for preventing and controlling the spontaneous combustion of coal gangue[J].Environmental Science and Pollution Research,2023,30(38):88548-88562.
[13] Han R H,Guo X N,Guan J F,et al.Activation mechanism of coal gangue and its impact on the properties of geopolymers:a review[J].Polymers (Basel),2022,14(18):3861-3885.
[14] Zheng Y S,Zhou J X,Ma Z J,et al.Preparation of a high-silicon ZSM-5 molecular sieve using only coal gangue as the silicon and aluminum sources[J].Materials (Basel),2023,16(12):4338-4351.
[15] Daulay A,Astuti W,Sumardi S,et al.Synthesis and characteristics of Na-A zeolite from coal fly ash and application for adsorption of cerium(Ⅲ)[J].Journal of Rare Earths,2024,24:721.
[16] Chen X L,Wang Y,Wang C,et al.Synthesis of NaA zeolite via the mesoscale reorganization of submolten salt depolymerized kaolin:a mechanistic study[J].Chemical Engineering Journal,2023,454:243-254.
[17] Hellal M S,Rashad A M,Kadimpati K K,et al.Adsorption characteristics of nickel(Ⅱ) from aqueous solutions by zeolite scony mobile-5(ZSM-5) incorporated in sodium alginate beads[J].Scientific Reports,2023,13(1):19601.
[18] Isik B,Ugraskan V.Adsorption of methylene blue on sodium alginate-flax seed ash beads:isotherm,kinetic and thermodynamic studies[J].International Journal of Biological Macromolecules,2021,167:1156-1167.
[19] Hou X Y,Feng J,Ren Y M,et al.Synthesis and adsorption properties of spongelike porous MnFe2O4[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2010,363(1-3):1-7.
[20] Wang H,Yi L,Huang F X,et al.Facile synthesis of graphene nanosheets on wastewater sediments for high efficient adsorption of methylene blue[J].Separation and Purification Technology,2024,337:1383-1396.
[21] Ren Z L,Wang Y H,Fei P,et al.An economic magnetic adsorbent for acid blue 80 and methylene blue removal[J].ChemistrySelect,2019,4(31):9174-9178.
[22] Wang S,Dou J L,Zhang T T,et al.Selective adsorption of methyl orange and methylene blue by porous carbon material prepared from potassium citrate[J].ACS Omega,2023,8(38):35024-35033.
[23] Simonič M,Flucher V,Luxbacher T,et al.Adsorptive removal of heavy metal ions by waste wool[J].Journal of Natural Fibers,2022,19(16):14490-14503.
[24] Cheng M,Zeng G M,Huang D L,et al.High adsorption of methylene blue by salicylic acid-methanol modified steel converter slag and evaluation of its mechanism[J].Journal of Colloid and Interface Science,2018,515:232-239.
[25] Supelano G I,Gómez Cuaspud J A,Moreno-Aldana L C,et al.Synthesis of magnetic zeolites from recycled fly ash for adsorption of methylene blue[J].Fuel,2020,263:16-26.
[26] Silva F,Nascimento L,Brito M,et al.Biosorption of methylene blue dye using natural biosorbents made from weeds[J].Materials (Basel),2019,12(15):2486-2502.
[27] De Freitas J D S,Delgado Berteli M B,Neto J C,et al.Biosorption of methylene blue by residue from Lentinus crinitus mushroom cultivation[J].World Journal of Microbiology and Biotechnology,2023,39(5):110.
[28] Mphuthi B R,Thabede P M,Modise J S,et al.Adsorption of cadmium and methylene blue using highly porous carbon from hemp seeds[J].Applied Sciences,2023,13(17):9659-9674.
[29] Cheng J F,Bi C Q,Zhou X,et al.Preparation of bamboo-based activated carbon via steam activation for efficient methylene blue dye adsorption:modeling and mechanism studies[J].Langmuir,2023,39(39):14119-14129.
[30] Jin H Z,Zhang Y H,Zhang X X,et al.3D printed geopolymer adsorption sieve for removal of methylene blue and adsorption mechanism[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,648:648-656.
[31] Hoc Thang N,Sy Khang D,Duy Hai T,et al.Methylene blue adsorption mechanism of activated carbon synthesised from cashew nut shells[J].RSC Advances,2021,11(43):26563-26570.
[32] Wu T T,Yang G P,Cao J X,et al.Activation and adsorption mechanisms of methylene blue removal by porous biochar adsorbent derived from eggshell membrane[J].Chemical Engineering Research and Design,2022,188:330-341.
Options
Outlines

/