The excessive use of fossil energy has led to a continuous and gradual increase in global CO2 emissions,and climate warming has become the most serious environmental problem facing mankind.Metal-organic framework materials (MOFs) are ideal CO2 adsorbents and can be used for CO2 capture due to their excellent properties.In this paper,NbOFFIVE-1-Ni@PA CO2 composite adsorbent provided by Beijing University of Chemical Engineering was used to test the adsorption penetration curve of low concentration CO2 using a self-built fixed bed device,and the influence of flow rate,temperature,concentration,air humidity and bed thickness on the adsorption behavior was explored.Three kinetic models were used to fit the adsorption data,and the cyclic stability of NbOFFIVE-1-Ni@PA was also investigated.The results showed that with the increase of gas flow rate,the CO2 adsorption capacity of NbOFFIVE-1-Ni@PA increased first and then decreased.The dynamic CO2 adsorption performance of NbOFFIVE-1-Ni@PA was enhanced by decreasing adsorption temperature,increasing concentration,decreasing air humidity and increasing the bed height.Avrami model could better fit the experimental data,indicating that the adsorption of CO2 by NbOFFIVE-1-Ni@PA was a combination of physical and chemical adsorption.Finally,after 10 times of adsorption and desorption,the adsorption capacity of NbOFFIVE-1-Ni@PA only decreased by 4.5%,showing excellent reproducibility.
[1] 王昌国,杨志远,宁海龙,等.MOFs材料改性及其吸附二氧化碳的研究进展[J].化工新型材料,2022,50(2):287-292,297.
[2] Mahajan S,Lahtinen M.Recent progress in metal-organic frameworks (MOFs) for CO2 capture at different pressures[J].Journal of Environmental Chemical Engineering,2022,10(6):108930.
[3] Shi X Y,Xiao H,Azarabadi H,et al.Sorbents for direct capture of CO2 from ambient air[J].Angewandte Chemie International Edition,2019,59(18):6984-7006.
[4] Mai Bui C S A,André Bardow,Edward J Anthony.Carbon capture and storage (CCS):theway forward[J].Energy & Environmental Science,2018,11(5):1062-1176.
[5] Sun Z Q,Zhao S L,Zhang X,et al.Research progress on metal-organic frameworks (MOFs) in CO2 capture from post-combustion coal-fired flue gas:characteristic and preparation,modification and application[J].Journal of Materials Chemistry A,2022,10:5174-5211.
[6] 陈鸿伟,张泽,孙玮等.介孔材料CO2吸附性能的研究进展[J].材料导报,2016,30(5):63-68.
[7] Simone C,Carlos A G,Alírio E R.Adsorption equilibrium of methane,carbon dioxide,and nitrogenon zeolite 13X at high pressures[J].Journal of Chemical and Engineering Data,2004,49(4):1095-1101.
[8] Zhu X,Chen C,Suo H,et al.Synthesis of elevated temperature CO2 adsorbents from aqueous miscible organic-layered double hydroxides[J].Energy,2019,167:960-969.
[9] Zhou H C,Long J R,Yaghi O M.Introduction to metal-organic frameworks[J].Chemical Reviews,2012,112(2):673-674.
[10] Lin R B,Xiang S,Zhou W,et al.Microporous metal-organic framework materials for gas separation[J].Chemical Engineering,2020,6(2):337-363.
[11] Van Vleet M J,Weng T,Li X,et al.In situ,time-resolved,and mechanistic studies of metal-organic framework nucleation and growth[J].Chemical Reviews,2018,118(7):3681-3721.
[12] Wang J,Zhong Q,Zeng Y,et al.Rational construction of triangle-like nickel-cobalt bimetallic metal-organic framework nanosheets arrays as battery-type electrodes for hybrid supercapacitors[J].Journal of Colloid and Interface Science,2019,555:42-52.
[13] Zhang M,Dai Q,Zheng H,et al.Novel MOF-derived Co@N-C bifunctional catalysts for highly efficient zn-air batteries and water splitting[J].Advanced Materials,2018,30(10):1705431.
[14] Jiang H,Zhang W,Kang X,et al.Topology-based functionalization of robust chiral Zr-based metal-organic frameworks for catalytic enantioselective hydrogenation[J].Journal of the American Chemical Society,2020,142(21):9642-9652.
[15] Rezaei F,Lawson S,Hosseini H,et al.MOF-74 and UTSA-16 film growth on monolithic structures and their CO2 adsorption performance[J].Chemical Engineering Journal,2017,313:1346-1353.
[16] Mutyala S,Jonnalagadda M,Mitta H,et al.CO2 capture and adsorption kinetic study of amine-modified MIL-101(Cr)[J].Chemical Engineering Research and Design,2019,143:241-248.
[17] Li H,Li L,Lin R B,et al.Porous metal-organic frameworks for gas storage and separation:status and challenges[J].EnergyChem,2019,1(1):100006.
[18] Dissegna S,Epp K,Heinz W R,et al.Defective metal-organic frameworks[J].Advanced Materials,2018,30(37):e1704501.
[19] Huang Y B,Liang J,Wang X S,et al.Multifunctional metal-organic framework catalysts:synergistic catalysis and tandem reactions[J].Chemical Society Reviews,2017,46(1):126-157.
[20] Li Y L,Zhao D,Zhao Y,et al.Synthesis,structure,and magnetic and catalytic properties of metal frameworks with 2,2′-dinitro-4,4′-biphenyldicarboxylate and imidazole-containing tripodal ligands[J].Dalton Transactions,2016,45(21):8816-8823.
[21] Chen B,Ockwig N W,Millward A R,et al.High H2 adsorption in a microporous metal-organic framework with open metal sites[J].Angewandte Chemie International Edition,2005,44(30):4745-4749.
[22] Kayal S,Chakraborty A.Activated carbon (type Maxsorb-Ⅲ) and MIL-101(Cr) metal organic framework based composite adsorbent for higher CH4 storage and CO2 capture[J].Chemical Engineering Journal,2018,334:780-788.
[23] Li Y L,Zhao Y,Kang Y S,et al.Syntheses,structures,and sorption properties of metal-organic frameworks with 1,3,5-tris(1-imidazolyl)benzene and tricarboxylate ligands[J].Crystal Growth & Design,2016,16(12):7112-7123.
[24] Rada Z H,Abid H R,Shang J,et al.Effects of amino functionality on uptake of CO2,CH4 and selectivity of CO2/CH4 on titanium based MOFs[J].Fuel,2015,160:318-327.
[25] Yurdusşen A,Yürüm Y.A controlled synthesis strategy to enhance the CO2 adsorption capacity of MIL-88B type MOF crystallites by the crucial role of narrow micropores[J].Industrial & Engineering Chemistry Research,2019,58(31):14058-14072.
[26] Zhang Z,Ding Q,Cui J,et al.Fine-tuning pore dimension in hybrid ultramicroporous materials boosting simultaneous trapping of trace alkynes from alkenes[J].Small,2020,16(49):e2005360.
[27] Wen H M,Liao C,Li L,et al.A metal-organic framework with suitable pore size and dual functionalities for highly efficient post-combustion CO2 capture[J].Journal of Materials Chemistry A,2019,7(7):3128-3134.
[28] Guo M,Wu H,Lv L,et al.A highly efficient and stable composite of polyacrylate and metal-organic framework prepared by interface engineering for direct air capture[J].ACS Appl Mater Interfaces,2021,13(18):21775-21785.
[29] Tiwari D,Goel C,Bhunia H,et al.Dynamic CO2 capture by carbon adsorbents:kinetics,isotherm and thermodynamic studies[J].Separation and Purification Technology,2017,181:107-122.
