New Chemical Materials >

2023 , Vol. 51 >Issue 6: 40 - 44

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2023.06.008

Research progress of high-safety lithium-ion battery separators

Expand
  • School of Petrochemical Engineer,Liaoning Petrochemical University,Fushun 113001

Received date: 2022-03-04

  Revised date: 2023-02-26

  Online published: 2023-07-07

Fold

Abstract

Lithium-ion batteries have become the dominant mobile power source due to their high energy density,long life and low self-discharge rate.The safety of lithium-ion batteries has always attracted people's attention.As an important part of the lithium-ion battery,the separator not only provides a channel for the transmission of lithium-ions,but also isolates the positive and negative electrodes to prevents the battery from short-circuiting,playing an important role in the safety of the lithium-ion battery.In recent years,researchers have devoted themselves to the development of various multifunctional safety separators from different perspectives of methods,materials and practical requirements.In this review,we mainly highlighted the latest developments of separators with high thermal stability and high safety for use in high-safety lithium-ion batteries.In addition,the future development direction and challenges of the next generation of high-safety,lithium-ion battery separators were also proposed.

Key words： lithium-ion battery; separator; modification; safety

Cite this article

Xu Delian, Li Qi, Qiao Qingdong, Xiao Wei, Yan Jiahui, Li Ying . Research progress of high-safety lithium-ion battery separators[J]. New Chemical Materials, 2023 , 51(6) : 40 -44 . DOI: 10.19817/j.cnki.issn1006-3536.2023.06.008

References

[1] Li Y,Yu L,Hu W,et al.Thermotolerant separators for safe lithium-ion batteries under extreme conditions[J].Journal of Materials Chemistry A,2020,8(39):20294-20317.
[2] Wang Q,Ping P,Zhao X,et al.Thermal runaway caused fire and explosion of lithium ion battery[J].Journal of Power Sources,2012,208(24):210-224.
[3] Feng X,Ouyang M,Liu X,et al.Thermal runaway mechanism of lithium ion battery for electric vehicles:a review[J].Energy Storage Materials,2018,10:246-267.
[4] Wang Y,Shi L,Zhou H,et al.Polyethylene separators modified by ultrathin hybrid films enhancing lithium ion transport performance and Li-metal anode stability[J].Electrochimica Acta,2018,259:386-394.
[5] 肖伟,巩亚群,王红,等.锂离子电池隔膜技术进展[J].储能科学与技术,2016,5(2):188-196.
[6] Thackeray M M,Wolverton C,Isaacs E D.Electrical energy storage for transportation—approaching the limits of,and going beyond,lithium-ion batteries[J].Energy & Environmental Science,2012,5(7):7854-7863.
[7] Su M,Huang G,Wang S,et al.High safety separators for rechargeable lithium batteries[J].Science China Chemistry,2021,64(7):1131-1156.
[8] Liu Xiang,Ren Dongsheng,Hsu Hungjen,et al.Thermal runaway of lithium-ion batteries without internal short circuit[J].Joule,2018,2(10):2047-2064.
[9] Croce F,Focarete M L,Hassoun J,et al.A safe,high-rate and high-energy polymer lithium-ion battery based on gelled membranes prepared by electrospinning[J].Energy & Environmental Science,2011,4(3):921-927.
[10] Chi M,Shi L,Wang Z,et al.Excellent rate capability and cycle life of Li metal batteries with ZrO2/POSS multilayer-assembled PE separators[J].Nano Energy,2016,28:1-11.
[11] Feng X,Ren D,He X,et al.Mitigating thermal runaway of lithium-ion batteries[J].Joule,2020,4(4):743-770.
[12] Zhang C,Liang H Q,Pi J K,et al.Polypropylene separators with robust mussel-inspired coatings for high lithium-ion battery performances[J].Chinese Journal of Polymer Science,2019,37(10):1015-1022.
[13] Liu L,Wang Z,Xie Y,et al.Zirconia/polyethylene terephthalate ceramic fiber paper separator for high-safety lithium-ion battery[J].Ionics,2020,26(33):6057-6067.
[14] Liang X,Yang Y,Jin X,et al.The high performances of SiO2/Al2O3-coated electrospun polyimide fibrous separator for lithium-ion battery[J].Journal of Membrane Science,2015,493:1-7.
[15] Zhang Y,Wang Z,Xiang H,et al.A thin inorganic composite separator for lithium-ion batteries[J].Journal of Membrane Science,2016,509:19-26.
[16] Cho J,Jung Y C,Lee Y S,et al.High performance separator coated with amino-functionalized SiO2 particles for safety enhanced lithium-ion batteries[J].Journal of Membrane Science,2017:S0376738817303654.
[17] Li W,Li X,Yuan A,et al.Al2O3/poly(ethylene terephthalate) composite separator for high-safety lithium-ion batteries[J].Ionics,2016,22(11):2143-2149.
[18] Zhang J,Xiang Y,Imran J M,et al.Polymers/zeolite nanocomposite membranes with enhanced thermal and electrochemical performances for lithium-ion batteries[J].Journal of Membrane Science,2018,564:S0376738818308706-.
[19] Shi C,Dai J,Xiu S,et al.A high-temperature stable ceramic-coated separator prepared with polyimide binder/Al2O3 particles for lithium-ion batteries[J].Journal of Membrane Science,2016,517:91-99.
[20] Jeon H,Yeon D,Lee T,et al.A water-based Al2O3 ceramic coating for polyethylene-based microporous separators for lithium-ion batteries[J].Journal of Power Sources,2016,315:161-168.
[21] Jia S,Long J,Li J,et al.Biomineralized zircon-coated PVDF nanofiber separator for enhancing thermo-and electro-chemical properties of lithium ion batteries[J].Journal of Materials Science,2020,55(30):14907-14921.
[22] Wu D,Deng L,Sun Y,et al.A high-safety PVDF/Al2O3 composite separator for Li-ion batteries via tip-induced electrospinning and dip-coating[J].RSC Advances,2017,7(39):24410-24416.
[23] Chen Z,Lin Q,Li Y,et al.Fabrication and application of TiO2-modified PMIA separators with strong mechanical properties in lithium-ion batteries[J].Ionics,2022,28(1):117-125.
[24] Xu H,Li M,Han K,et al.Study on preparation and properties of polyimide lithium battery separator[J].IOP Conference Series:Materials Science and Engineering,2019,493(1):012080.
[25] Moon J,Jeong J Y,Kim J I,et al.An ultrathin inorganic-organic hybrid layer on commercial polymer separators for advanced lithium-ion batteries[J].Journal of Power Sources,2019,416:89-94.
[26] Qiu Z,Yuan S,Wang Z,et al.Construction of silica-oxygen-borate hybrid networks on Al2O3-coated polyethylene separators realizing multifunction for high-performance lithium ion batteries[J].Journal of Power Sources,2020,472:228445.
[27] Shi J,Xia Y,Yuan Z,et al.Porous membrane with high curvature,three-dimensional heat-resistance skeleton:a new and practical separator candidate for high safety lithium ion battery[J].Scientific Reports,2015,5:8255.
[28] Li J,Tian W,Yan H,et al.Preparation and performance of aramid nanofiber membrane for separator of lithium ion battery[J].Journal of Applied Polymer Science,2016,133(30),DOI:10.1002/app.43623.
[29] Walton J J,Hiasa T,Kumita H,et al.Fluorocyanoesters as additives for lithium-ion battery electrolytes[J].ACS Applied Materials & Interfaces,2020,12(13):15893-15902.
[30] Xu K.Nonaqueous liquid electrolytes for lithium-based rechargeable batteries[J].Chemical Reviews,2004,104(10):4303-4418.
[31] Jing P,Liu M,Wang P,et al.Flexible nonwoven ZrO2 ceramic membrane as an electrochemically stable and flame-resistant separator for high-power rechargeable batteries[J].Chemical Engineering Journal,2020,388:124259.
[32] Peng L,Kong X,Li H,et al.A rational design for a high-safety lithium-ion battery assembled with a heatproof-fireproof bifunctional separator[J].Advanced Functional Materials,2021,31(10):2008537.
Options
Outlines

/

〈 〉

京ICP备09035943号-38
Copyright © New Chemical Materials, All Rights Reserved.
Tel: 010-64437113　E-mail: hgxx@cncic.cn
Powered by Beijing Magtech Co., Ltd.