Preparation and photocatalytic performance of ZIF-8@PI nanofiber membrane

Expand
  • 1. School of Chemistry & Materials Engineering,Bohai University,Jinzhou 121013,China;
    2. Liaoning Engineering Technology Center of Supercapacitor,Jinzhou 121013

Received date: 2021-03-19

  Revised date: 2022-03-26

  Online published: 2022-08-09

Abstract

Polyamic acid precursor was prepared for electrospinning,then the polymaic acid electrospun fibers mats were obtained by using electrospinning method.A polyimide (PI) ultrafine fibers mats was prepared by thermal imidization process.ZIF-8 nanoparticles/plates were deposited on the surface by solution synthesis and hydrothermal synthesis method,so ZIF-8@PI fibers nanocomposites photocatalyst can be obtained.The samples were characterized by scanning electron microscopy,X ray diffraction.Using the PI fibers as template and carrier,ZIF-8 nano-particles/plates with uniform,less agglomeration and high loading can be loaded on the surface of PI fibers.The photocatalyst performance of ZIF-8@PI fibers nanocomposites membrane was investigated by the degradation of organic dyes in water,the results shown that tbe membrane possessed high photocatalyst efficiency (99.8%) and photocatalytic degradation rate(0.57mg·cm-2·h-1).

Cite this article

Ma Li, Li Ying, Yi Zishuo, Kong Mengdi, Xin Yuhan, He Tieshi . Preparation and photocatalytic performance of ZIF-8@PI nanofiber membrane[J]. New Chemical Materials, 2022 , 50(7) : 95 -98 . DOI: 10.19817/j.cnki.issn1006-3536.2022.07.020

References

[1] Zhuo S,Shao M,Lee S T.Upconversion and downconversion fluorescent graphene quantum dots:ultrasonic preparation and photocatalysis[J].ACS Nano,2012,6(2):1059-1064.
[2] He T,Zhou Z,Xu W,et al.Preparation and photocatalysis of TiO2-fluoropolymer electrospun fiber nanocomposites[J].Polymer,2009,50(13):3031-3036.
[3] He T,Zhou Z,Xu W,et al.Visible-light photocatalytic activity of semiconductor composites supported by electrospun fiber[J].Compos Sci Technol,2010,70(10):1469-1475.
[4] Xiao J D,Jiang H L.Metal-organic frameworks for photocatalysis and photothermal catalysis[J].Accounts of Chemical Research,2019,52(2):356-366.
[5] 梁祥,陈莲芬,张利,等.金属-有机框架在光催化中的应用[J].科学通报,2018,63(3):248-265.
[6] Dou Y,Zhang W,Kaiser A.Electrospinning of metal-organic frameworks for energy and environmental applications[J].Advanced Science,2020,7(3):1902590.
[7] Zhang Y,Yuan S,Feng X,et al.Preparation of nanofibrous metal-organic framework filters for efficient air pollution control[J].Journal of the American Chemical Society,2016,138(18):5785-5788.
[8] 肖娟定,李丹丹,江海龙.金属有机框架材料在光催化中的应用[J].中国科学:化学,2018,48(9):1058-1075.
[9] 王春宇,张晶,张青云,等.ZIF-8基多孔碳的制备及吸附性能[J].化工进展,2018,36(1):299-304.
[10] 郭艳蓉,常薇,张雯,等.MOF衍生的多孔ZnO/C、Ag/ZnO/C复合材料光催化性能研究[J].无机材料学报,2015,30(12):1321-1326.
[11] 李庆,张莹,樊增禄,等.Cu-有机骨架对染料废水的吸附和可见光降解[J].纺织学报,2018,39(2):112-118.
[12] Wang X,Liu J,Leong S K,et al.Rapid construction of ZnO@ZIF-8 heterostructures with size-Selective photocatalysis properties[J].ACS Applied Materials & Interfaces,2016,8(14):9080-9087.
[13] He T S,Yu X D,Bai T J,et al.Porous carbon nanofibers derived from PAA-PVP electrospun fibers for supercapacitor[J].Ionics,2020,26:4103-4111.
[14] He T,Fu Y,Meng X,et al.A novel strategy for the high performance supercapacitor based on polyacrylonitrile-derived porous nanofibers as electrode and separator in ionic liquid electrolyte[J].Electrochim.Acta,2018,282,97-104.
[15] 何铁石,周正发,徐卫兵.表面改性PVDF电纺纤维负载ZnS复合材料的制备与光催化性能[J].环境科学学报,2009,29(8):1713-1719.
Options
Outlines

/