Research progress on perovskite based anode for methane fuel SOFC

Yan Fei, Dong Runze, Yang Pu, Li Ping

doi:10.19817/j.cnki.issn1006-3536.2022.06.013

New Chemical Materials >

2022 , Vol. 50 >Issue 6: 71 - 74

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2022.06.013

Research progress on perovskite based anode for methane fuel SOFC

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1. North China Electric Power University,Baoding Campus,Department of Environmental Science and Engineering,Baoding 071003;
2. Hebei Key Laboratory of Power Plant Flue Gas Multi-Pollutants Control,Department of Environmental Science and Engineering, North China Electric Power University,Baoding 071003

Received date: 2021-03-10

Revised date: 2022-02-11

Online published: 2022-07-06

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Abstract

Solid oxide fuel cell (SOFC) fueled by methane can effectively alleviate energy crisis and environmental pollution.Perovskite-based anode materials exhibit good carbon deposition resistance,and are considered to be a good substitute for traditional metal anode materials.The research progress of perovskite-based anode catalysts was reviewed,including perovskite type,double perovskite type and phase transition type perovskite anode materials.At present,perovskite and double perovskite anode materials was need to further improve the catalytic activity,and reduced the operating temperature.For the phase transformation perovskite materials,the key problem was to clarify the phase transition in situ self-assembly mechanism,and to construct high catalytic activity and high stability anode materials.

Key words： methane; solid oxide fuel cell; anode; perovskite

Cite this article

Yan Fei, Dong Runze, Yang Pu, Li Ping . Research progress on perovskite based anode for methane fuel SOFC[J]. New Chemical Materials, 2022 , 50(6) : 71 -74 . DOI: 10.19817/j.cnki.issn1006-3536.2022.06.013

References

[1] Seo H G,Choi Y,Jung W.Exceptionally enhanced electrode activity of (Pr,Ce)O_2-δ-based cathodes for thin-film solid oxide fuel cells[J].Advanced Energy Materials,2018,8:1703647.
[2] Duan C,Kee R J,Zhu H,et al.Highly durable,coking and sulfur tolerant,fuel-flexible protonic ceramic fuel cells[J].Nature,2018,557:217-222.
[3] Badwal S P S,Giddey S,Kulkarni A,et al.Direct ethanol fuel cells for transport and stationary applications-a comprehensive review[J].Applied Energy,2015,145:80-103.
[4] Wu H,Xiao J,Zeng X,et al.A high performance direct carbon solid oxide fuel cell-A green pathway for brown coal utilization[J].Applied Energy,2019,248:679-687.
[5] Zhan Z,Barnett S A.An octane-fueled solid oxide fuel cell[J].Science,2005,308:844-747.
[6] Lu X C,Zhu J H.Cu(Pd)-impregnated La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-delta anodes for direct utilization of methane in SOFC[J].Solid State Ionics,2007,178:1467-1475.
[7] Toscani L M,Giangiordano F V,Nichio N,et al.In-situ Ni exsolution from NiTiO₃ as potential anode for solid oxide fuel cells[J].International Journal of Hydrogen Energy,2020,45:23433-23443.
[8] Niu B,Jin F,Fu R,et al.Pd-impregnated Sr_1.9VMoO_6-δ double perovskite as an efficient and stable anode for solid-oxide fuel cells operating on sulfur-containing syngas[J].Electrochimica Acta,2018,274:91-102.
[9] Pena M A,Fierro J L G.Chemical structures and performance of perovskite oxides[J].Chemical Review,2001,101:1981-2017.
[10] Shi K Y,Guo L L,Liu H X,et al.Preparation and optical properties of thin-films of layered perovskite-type hybrid compounds (C_nH_2n+1NH₃)₂PbX₄[J].Science and Technology of Hybrid Materials,2006,111:119-122.
[11] Jiang S P,Liu L,Khuong P O B,et al.Electrical conductivity and performance of doped LaCrO₃ perovskite oxides for solid oxide fuel cells[J].Journal of Power Sources,2008,176:82-89.
[12] Lay E,Dessemond L,Gauthier G H.Synthesis and characterization of Ce_xSr_1-xCr_0.5Mn_0.5O_3-δ perovskites as anode materials for solid oxide fuel cells (SOFC)[J].Electrochimica Acta,2016,216:420-428.
[13] Aliotta C,Liotta L F,Deganello F,et al.Direct methane oxidation on La_1-xSrCr_xFeyO_3-δ perovskite-type oxides as potential anode for intermediate temperature solid oxide fuel cells[J].Applied Catalysis B-Environmental,2016,180:424-433.
[14] Shahid M,He C,Sankarasubramanian S,et al.Enhanced methane electrooxidation by ceria and nickel oxide impregnated perovskite anodes in solid oxide fuel cells[J].International Journal of Hydrogen Energy,2020,45:11287-11296.
[15] 庄林.弛豫时间分布法分解固体氧化物燃料电池电化学阻抗谱[J].物理化学学报,2019,35(5):457-458.
[16] Tao S W,Irvine J T S.A redox-stable efficient anode for solid-oxide fuel cells[J].Nature Materials,2003,2:320-323.
[17] Wan J,Zhu J H,Goodenough J B.La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-delta+Cu composite anode running on H₂ and CH₄ fuels[J].Solid State Ionics,2006,177:1211-1217.
[18] Horikiri F,Han LQ,Iizawa N,et al.Electrical properties of Nb-doped SrTiO₃ ceramics with excess TiO₂ for SOFC anodes and interconnects[J].Journal of the Electrochemical Society,2008,155:B16-B20.
[19] Fagg D P,Kharton V V,Kovalevsky A V,et al.The stability and mixed conductivity in La and Fe doped SrTiO₃ in the search for potential SOFC anode materials[J].Journal of the European Ceramic Society,2001,21:1831-1835.
[20] Kim H S,Jeon Y,Kim J H,et al.Characteristics of Sr_1-xY_xTi_1-yRu_yO_3+/-δ and Ru-impregnated Sr_1-xY_xTiO_3+/-δ perovskite catalysts as SOFC anode for methane dry reforming[J].Applied Surface Science,2020,510:145450.
[21] Kim H S,Yoon S P,Yun J W,et al.Sr_0.92Y_0.08TiO_3-delta/Sm_0.2Ce_0.8O_2-delta anode for solid oxide fuel cells running on methane[J].International Journal of Hydrogen Energy,2012,37:16130-16139.
[22] Zhang Y,Fan H,Han M.Stability of Ni-YSZ anode for SOFCs in methane fuel:the effects of infiltrating La_0.8Sr_0.2FeO_3-δ and Gd-doped CeO₂ materials[J].Journal of the Electrochemical Society,2018,165:F756-F763.
[23] Bian L Z,Duan C,Wang L J,et al.Ce-doped La_0.7Sr_0.3Fe_0.9Ni_0.1O_3-δ as symmetric electrode for high performance direct hydrocarbon solid oxide fuel cell[J].Journal of Materials Chemistry A,2017,5(29),DOI:10.1039/C7TA03001K.
[24] 陈永红,杨洋,杨雪,等.新型双钙钛矿基对称固体氧化物燃料电池的制备及性能[J].硅酸盐学报,2017,45(11):1673-1678.
[25] 杜志鸿,李媛媛,赵海雷,等.固体氧化物燃料电池双钙钛矿陶瓷阳极缺陷结构设计与性能调控[J].硅酸盐学报,2021,49(1):7-13.
[26] Huang Y H,Dass R I,Xing Z L,et al.Double perovskites as anode materials for solid-oxide fuel cells[J].Science,2006,312:254-257.
[27] Wang Z,Tian Y,Li Y.Direct CH₄ fuel cell using Sr₂FeMoO₆ as an anode material[J].Journal of Power Sources,2011,196:6104-6109.
[28] Huang Y H,Liang G,Croft M,et al.Double-perovskite anode materials Sr₂MMoO₆ (M=Co,Ni) for solid oxide fuel cells[J].Chemistry of Materials,2009,21:2319-2326.
[29] Lee D,Kim D,Son S J,et al.Simultaneous A- and B- site substituted double perovskite (AA′B₂O_5+δ) as a new high-performance and redox-stable anode material for solid oxide fuel cells[J].Journal of Power Sources,2019,434:226743.
[30] Rath M K,Lee K T.Characterization of novel Ba₂LnMoO₆ (Ln=Pr and Nd) double perovskite as the anode material for hydrocarbon-fueled solid oxide fuel cells[J].Journal of Alloys and Compounds,2018,737:152-159.
[31] Sengodan S,Choi S,Jun A,et al.Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells[J].Nature Materials,2014,14:205-209.
[32] Kwon O,Kim K,Joo S,et al.Self-assembled alloy nanoparticles in a layered double perovskite as a fuel oxidation catalyst for solid oxide fuel cells[J].Journal of Materials Chemistry A,2018,6:15947-15953.
[33] Hou N,Yao T,Li P,et al.A-site ordered double perovskite with in situ exsolved core-shell nanoparticles as anode for solid oxide fuel cells[J].ACS Applied Materials & Interfaces,2019,11:6995-7005.

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