Hollow mesoporous silica microsphere (HMSS) has unique structure and excellent physico-chemical properties,such as large specific surface area,low density,high stability,good biocompatibility,strong surface permeability,etc.It has been more and more popular in the research and development of new materials,and has been widely used in the fields of catalysis,medicine,environmental protection,food and so on.Through the synthesis and modification methods HMSS research progress in recent years were summarized.The synthesis method was divided into soft template method,hard template method and in-situ template method.The modified method was divided into chemical modification,physical modification and the modification method,and carryed on the elaboration,the advantages and disadvantages.On this basis,the last for the future development direction of HMSS was discussed.
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