Progress on preparation of polymer porous membrane by N-TIPS method

Expand
  • 1. College of Chemistry and Environmental Engineering,China University of Mining and TechnologyBeijing,Beijing 100083;
    2. Beijing Key Laboratory of Membrane Materials and Engineering Department of Chemical Engineering,Tsinghua University,Beijing 100084;
    3. Small and Medium-sized Enterprise Service Center of Quzhou,Zhejiang 324000

Received date: 2020-08-07

  Revised date: 2021-09-26

  Online published: 2021-12-31

Abstract

Combined non-solvent and thermally induced phase separation(N-TIPS) method,as a kind of polymer porous membrane preparation method,incorporates the advantages of both thermally induced phase separation (TIPS) and non-solvent induced phase separation (NIPS).Polymer membranes prepared via N-TIPS method possess the characteristics of excellent mechanical properties and high porosity,thus much research attention has been aroused in recent years.Starting from an introduction of N-TIPS method,firstly the basic principle of polymer porous membrane preparation via N-TIPS method was described,and then the progress of different polymeric porous membrane preparation via N-TIPS method during these years was comprehensively reviewed.Finally current challenges were discussed.The future prospects and further development directions were also proposed.

Cite this article

Li Mufei, Tang Yuanhui, Zhou Bo, Lin Zhijing, Wang Xiaolin, Lin Yakai . Progress on preparation of polymer porous membrane by N-TIPS method[J]. New Chemical Materials, 2021 , 49(12) : 21 -26 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.12.005

References

[1] Loeb S,Sourirajan S.High flow porous membranes for separating water from saline solutions[P].US,3133132,1964-05-12.
[2] Loeb S,Sourirajan S.High flow semipermeable membranes for separation of water from saline solutions[J].Adv Chem Ser,1962,38(1):117-132.
[3] Lloyd D R,Kinzer K E,Tseng H.Microporous membrane formation via thermally induced phase separation.Ⅰ.Solid-liquid phase separation[J].J Membr Sci,1990,52(3):239-261.
[4] Lloyd D R,Kim S S,Kinzer K E.Microporous membrane formation via thermally-induced phase separation.Ⅱ.Liquid—liquid phase separation[J].J Membr Sci,1991,64(1/2):1-11.
[5] Kim S S,Lloyd D R.Microporous membrane formation via thermally-induced phase separation.Ⅲ.effect of thermodynamic interactions on the structure of isotactic polypropylene membranes[J].J Membr Sci,1991,64(1/2):13-29.
[6] Lim G B,Kim S S,Ye Q,et al.Microporous membrane formation via thermally-induced phase separation.Ⅳ.effect of isotactic polypropylene crystallization kinetics on membrane structure[J].J Membr Sci,1991,64(1/2):31-40.
[7] Kim S S,Lim G B,Alwattari A A,et al.Microporous membrane formation via thermally-induced phase separation.Ⅴ.effect of diluent mobility and crystallization on the structure of isotactic polypropylene membranes[J].J Membr Sci,1991,64(1/2):41-53.
[8] Alwattari A A,Lloyd D R.Microporous membrane formation via thermally-induced phase separation.Ⅵ.effect of diluent morphology and relative crystallization kinetics on polypropylene membrane structure[J].J Membr Sci,1991,64(1/2):55-67.
[9] Lloyd D R,Lim G B.Microporous membrane formation via thermally-induced phase separation.Ⅶ.effect of dilution,cooling rate,and nucleating agent addition on morphology[J].J Membr Sci,1993,79(1):27-34.
[10] Tan X M,Rodrigue D.A review on porous polymeric membrane preparation.part Ⅱ:production techniques with polyethylene,polydimethylsiloxane,polypropylene,polyimide,and polytetrafluoroethylene[J].Polym,2019,11(8):1-35.
[11] Matsuyama H,Takida H,Maki T,et al.Preparation of porous membrane by combined use of thermally induced phase separation and immersion precipitation[J].Polym,2002,43(19):5243-5248.
[12] Kim J F,Kim J H,Lee Y M,et al.Thermally induced phase separation and electrospinning methods for emerging membrane applications:a review[J].Alche J,2016,62(2):461-490.
[13] Zhang H,Lu X L,Liu Z Y,et al.Study of the dual role mechanism of water-soluble additive in low temperature thermally-induced phase separation[J].J Membr Sci,2017,543(1):1-9.
[14] Zhang H,Lu X L,Liu Z Y,et al.The unidirectional regulatory role of coagulation bath temperature on cross-section radius of the PVDF hollow-fiber membrane[J].J Membr Sci,2018,550(1):9-17.
[15] 逯志平,吕晓龙,武春瑞,等.低温热致相分离法制备聚偏氟乙烯中空纤维多孔膜的研究[J].膜科学与技术,2012,32(1):12-22.
[16] Cha B J,Yang J M.Preparation of poly(vinylidene fluoride) hollow fiber membranesfor microfiltration using modified TIPS process[J].J Membr Sci,2007,291(1):191-198.
[17] 祝振鑫,孟广祯.复合热致相分离制膜方法[J].膜科学与技术,2010,30(6):1-6.
[18] 王建强,潘凯,房昺,等.稀释剂对混合相分离法制备聚偏氟乙烯膜的影响[J].北京化工大学学报(自然科学版),2010,37(4):73-77.
[19] 王建强.混合相分离法制备聚偏氟乙烯膜[D].北京:北京化工大学材料科学与工程学院,2010.
[20] Matsuyama H,Takida H,Maki T,et al.Preparation of porous membrane by combined use of thermally induced phase separation and immersion precipitation[J].Polym,2002,43(19):5243-5248.
[21] Mulder M.Basic principles of membrane technology[M].Dordrecht:Springer Science &Business Media,1996:35-75.
[22] Jang H,Song D H,Lee H J,et al.Preparation of dual-layer acetylated methyl cellulose hollow fiber membranes via co-extrusion using thermally induced phase separation and non-solvent induced phase separation methods[J].J Appl Polym Sci,2015,132(43):1-8.
[23] Lee J W,Park B,Kim J,et al.Effect of PVP,lithium chloride,and glycerol additives on PVDF dual-layer hollow fiber membranes fabricated using simultaneous spinning of TIPS and NIPS[J].Macromol Res,2015,23(3):291-299.
[24] Liu J,Lu X,Wu C.Preparation and properties of poly (vinylidene fluoride) membranes via the low temperature thermally induced phase separation method[J].J Poly Research,2014,21(10).
[25] 唐元晖,林亚凯,李倩,等.热致相分离法聚偏氟乙烯膜的制备及应用[J].膜科学与技术,2015,35(2):98-107.
[26] 张明刚.PVDF膜的亲水改性及抗污染性能研究[D].上海:复旦大学高分子科学系,2007.
[27] 许振良,翟晓东,陈桂娥.高孔隙率聚偏氟乙烯中空纤维超滤膜的研究[J].膜科学与技术,2000,20(4):10-13.
[28] 吕晓龙.聚偏氟乙烯中空纤维多孔膜制法及产品[P].中国,98103153.6,1998-07-20.
[29] Li X F,Wang Y G,Lu X L,et al.Morphology changes of polyvinylidene fluoride membraneunder different phase separation mechanisms[J].J Membr Sci,2008,320(1):477-482.
[30] Hassankiadeh N T,Cui Z L,Kim J H,et al.Microporous poly(vinylidene fluoride) hollow fiber membranes fabricated with Polar Clean as water-soluble green diluent and additives[J].J Membr Sci,2015,479:204-212.
[31] Xiao T,Wang P,Yang X,et al.Fabrication and characterization of novel asymmetric polyvinylidene fluoride (PVDF) membranes by the nonsolvent thermally induced phase separation (NTIPS) method for membrane distillation applications[J].J Membr Sci,2015,489(1):160-174.
[32] Li Y,Jin C L,Peng Y L,et al.Fabrication of PVDF hollow fiber membranes via integrated phase separation for membrane distillation[J].J Taiwan Inst Chem Eng,2018,95:487-494.
[33] 王旭东,张凯,王磊,等.凝固浴组成对热诱导相分离法制备PVDF微孔膜形态结构的影响[J].膜科学与技术,2015,35(5):51-57.
[34] Wang L,Huang D X,Wang X D,et al.Preparation of PVDF membranes via the low-temperature TIPS method with diluent mixtures:The role of coagulation conditions and cooling rate[J].Desalination,2015,361:25-37.
[35] Jung J T,Kim J F,Wang H H,et al.Understanding the non-solvent induced phase separation (NIPS) effect during the fabrication of microporous PVDF membranes via thermally induced phase separation (TIPS)[J].J Membr Sci,2016,514(1):250-263.
[36] Lin Y,Tang Y,Ma H,et al.Formation of a bicontinuous structure membrane of polyvinylidene fluoride in diphenyl carbonate diluent via thermally induced phase separation[J].J Appl Polym Sci,2009,114(3):1523-1528.
[37] Nam Y S,Park T G.Biodegradable polymeric microcellular foams by modified thermally induced phase separation method[J].Biomaterials,1999,20(19):1783-1790.
[38] Xu H P,Lang W Z,Zhang X,et al.Preparation and characterizations of charged PVDF membranes via composite thermally induced phase separation (C-TIPS) method[J].J Ind Eng Chem,2015,21:1005-1013.
[39] Xiang S,Guo Z H,Wang Y L,et al.The microstructure regulation,strengthening,toughening and hydrophilicity of polyamide6 in fabricating poly (vinylidene fluoride)-based flat membrane via the thermally induced phase separation technique[J].Eur Polym J,2020,126.
[40] Hu N G,Xiao T H,Cai X H,et al.Preparation and characterization of hydrophilically modified PVDF membranes by a novel nonsolvent thermally induced phase separation method[J].Membr,2016,6(4).
[41] Kotte M R,Kuvarega A T,Cho M,et al.Mixed matrix PVDF membranes with in situ synthesized PAMAM dendrimer-like particles:a new class of sorbents for Cu(Ⅱ) recovery from aqueous solutions by ultrafiltration[J].EST,2015,49(16):9431-9442.
[42] Wei DY,Zhou S Y,Li M S,et al.PVDF/palygorskite composite ultrafiltration membranes:effects of nanoclay particles on membrane structure and properties[J].Appl Clay Sci,2019,181.
[43] Zhao J,Chong J Y,Shi L,et al.Explorations of combined nonsolvent and thermally induced phase separation (N-TIPS) method for fabricating novel PVDF hollow fiber membranes using mixed diluents[J].J Membr Sci,2019,572(1):210-222.
[44] Jung J T,Wang H H,Kim J F,et al.Tailoring nonsolvent-thermally induced phase separation (N-TIPS) effect using triple spinneret to fabricate high performance PVDF hollow fiber membranes[J].J Membr Sci,2018,559(1):117-126.
[45] Qiu Y R,Matsuyama H.Preparation and characterization ofpoly(vinyl butyral) hollow fiber membrane via thermally inducedphase separation with diluent polyethylene glycol 200[J].Desalination,2010,257:117-123.
[46] Qiu Y R,Qi J,Wei Y Q.Synergistic action of non-solvent induced phase separation in preparation of poly(vinyl butyral) hollow fiber membrane via thermally induced phase separation[J].J Cent South Univ,2014,21(6):2184-2190.
[47] Zhou J,Zhang H,Wang H T,et al.Effect of cooling baths on EVOH microporous membrane structures in thermallyinduced phase separation[J].J Membr Sci,2009,343(1):104-109.
[48] Xing X Y,Gu L,Jin Y,et al.Fabrication and characterization of cellulose triacetate porous membranes by combined nonsolvent-thermally induced phase separation[J].Cellulose,2019,26(6):3747-3762.
[49] Sun X X,Uyama H.A poly(vinyl alcohol)/sodium alginate blend monolith with nanoscale porous structure[J].Nanoscale Res Lett,2013,8.
[50] Sun X X,Fujimoto T,Uyama H.Fabrication of a poly(vinyl alcohol) monolith via thermally impacted non-solvent-induced phase separation[J].Polym J,2013,45(10):1101-1106.
Options
Outlines

/