Research progress on clay mineral applied in solid composite electrolyte

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  • School of Earth and Space Sciences,Peking University,Beijing 100871

Received date: 2020-06-22

  Revised date: 2021-07-05

  Online published: 2021-11-02

Abstract

Clay mineral is a type of natural silicate minerals with rich reserves and low prices.They have excellent properties such as high thermal stability,good mechanical properties,and stable chemical properties.Thus,they can be used as inorganic fillers to prepare solid composite electrolytes to improve battery performance.The mechanism of clay minerals to improve the performance of electrolyte was introduced,and summarized the research progress on montmorillonite,halloysite,attapulgite and sepiolite used in composite solid electrolyte.The main problems in current research were pointed out.

Cite this article

Qi Pengyue, Chuan Xiuyun, Yang Yang, Liu Fangfang, Li Jianzhuo . Research progress on clay mineral applied in solid composite electrolyte[J]. New Chemical Materials, 2021 , 49(10) : 249 -252 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.10.053

References

[1] Luntz A,Mccloskey B.Nonaqueous Li-air bstteries:a status report[J].Chemical Reviews,2014,114:11721.
[2] Fan L,Wei S,Li S,et al.Recent progress of the solid-state electrolytes for high-energy metal-based batteries[J].Advanced Energy Materials,2018,8(11):1702657.
[3] Zhang H P,Zhang P,Li Z H,et al.A novel sandwiched membrane as polymer electrolyte for lithium ion battery[J].Electrochemistry Communications,2007,9(7):1700-1703.
[4] 牛丽丹,傅相锴,刘素娟,等.PAMPSLi/P(MMA-VAc)为基体的聚合物电解质[J].高等学校化学学报,2010,31(2):391-396.
[5] Lin D,Liu W,Liu Y,et al.High ionic conductivity of composite solid polymer electrolyte via in situ synthesis of monodispersed SiO2 nanospheres in poly(ethylene oxide)[J].Nano Letters,2016,16(1):459-465.
[6] Liang B,Tang S,Jiang Q,et al.Preparation and characterization of PEO-PMMA polymer composite electrolytes doped with nano-Al2O3[J].Electrochimica Acta,2015,169:334-341.
[7] 苏柳梅,崔昌华,尚用甲,等.可瓷化高分子复合防火材料的研究进展[J].粉末冶金材料科学与工程,2009,14(5):290-294.
[8] Wang Z,Xu C,Zhao Y,et al.Fabrication and mechanical properties of exfoliated clay-CNTs/epoxy nanocomposites[J].Materials Science and Engineering A,2008,490(1-2):481-487.
[9] Chen Q,Zhu R,Liu S,et al.Self-templating synthesis of silicon nanorods from natural sepiolite for high-performance lithium-ion battery anodes[J].Journal of Materials Chemistry A,2018,6:15.
[10] Pan J,Wu C,Cheng J,et al.Sepiolite-sulfur as a high-capacity,high-rate performance,and low-cost cathode material for lithium-sulfur batteries[J].Journal of Power Sources,2015,293:527-532.
[11] 李杨,丁飞,桑林,等.固态电池研究进展[J].电源技术,2019,43(7):1085-1089.
[12] 王蔼廉,计文希,陈婧,等.锂电池用固态电解质研究进展[J].高分子通报,2019(9):1-14.
[13] 梁子雷,李琪,孙悦,等.改性凝胶聚合物电解质的研究进展[J].电池,2008,38(4):260-262.
[14] Walls H J,Riley M W,Fedkiw P S,et al.Composite electrolytes from self-assembled colloidal networks[J].Electrochimica Acta,2003,48:2071-2077.
[15] Wang M,Dong S.Enhanced electrochemical properties of nanocomposite polymer electrolyte based on copolymer with exfoliated clays[J].Journal of Power Sources,2007,170(2):425-432.
[16] Zhang H,Li C,Piszcz M,et al.Single lithium-ion conducting solid polymer electrolytes:advances and perspectives[J].Chemical Society Reviews,2017,46(3),DOI:10.1039/c6cs00491a.
[17] Ruiz-Hitzky E,Aranda P.Polymer-salt intercalation complexes in layer silicates[J].Advanced Materials,1990,2(11):545-547.
[18] Kim S,Park S J.Preparation and ion-conducting behaviors of poly(ethylene oxide)-composite electrolytes containing lithium montmorillonite[J].Solid State Ionics,2007,178(13-14):973-979.
[19] Moreno M,Ana M A S,Gonzalez G,et al.Poly(acrylonitrile)-montmorillonite nanocomposites.effects of the intercalation of the filler on the conductivity of composite polymer electrolytes[J].Electrochimica Acta,2010,55(4):1323-1327.
[20] Zhang Y,Zhao Y,Bakenov Z,et al.Poly(vinylidene fluoride-co-hexafluoropropylene)/poly(methylmethacrylate)/nanoclay composite gel polymer electrolyte for lithium/sulfur batteries[J].Journal of Solid State Electrochemistry,2014,18(4):1111-1116.
[21] Vaia R A,Ishii H,Giannelis E P.Synthesis and properties of two-dimensional nanostructures by direct intercalation of polymer melts in layered silicates[J].Chemistry of Materials,1993,5(12):1694-1696.
[22] Vaia R A,Vasudevan S,Krawiec W,et al.New polymer electrolyte nanocomposites:melt intercalation of poly(ethylene oxide) in mica-type silicates[J].Advanced Materials,1995,7(2):154-156.
[23] Du M,Guo B,Jia D.Newly emerging applications of halloysite nanotubes:a review[J].Polymer International,2010,59(5):574-582.
[24] Liu M,Jia Z,Jia D,et al.Recent advance in research on halloysite nanotubes-polymer nanocomposite[J].Progress in Polymer Science,2014,39(8):1498-1525.
[25] Lun P,Chen Z,Zhang Z,et al.Enhanced ionic conductivity in halloysite nanotube-poly(vinylidene fluoride) electrolytes for solid-state lithium-ion batteries[J].RSC Advances,2018,8(60):34232-34240.
[26] Pongsuk P,Pumchusak J.Effects of natural clay on ionic conductivity,crystallinity and thermal properties of PEO-LiCF3SO3-natural clay as solid polymer electrolyte nanocomposites[J].Key Engineering Materials,2019,803:98-103.
[27] Wang H,Zhang S,Zhu M,et al.Remarkable heat-resistant halloysite nanotube/polyetherimide composite nanofiber membranes for high performance gel polymer electrolyte in lithium ion batteries[J/OL].Journal of Electroanalytical Chemistry,2018,808:303-310.
[28] Lin Y,Wang X,Liu J,et al.Natural halloysite nano-clay electrolyte for advanced all-solid-state lithium-sulfur batteries[J].Nano Energy,2017,31:478-485.
[29] Tian L,Xiong L,Chen X,et al.Enhanced electrochemical properties of gel polymer electrolyte with hybrid copolymer of organic palygorskite and methyl methacrylate[J].Materials,2018,11(10):1814.
[30] Tian L,Wang M,Xiong L,et al.Preparation and performance of p(OPal-MMA)/PVDF blend polymer membrane via phase-inversion process for lithium-ion batteries[J].Journal of Electroanalytical Chemistry,2019,839(2):264-273.
[31] Yao P,Zhu B,Zhai H,et al.PVDF/palygorskite nanowire composite electrolyte for 4V rechargeable lithium batteries with high energy density[J].Nano Letters,2018,18(10):6113-6120.
[32] Ulaganathan M,Lei Y L,Flora X H,et al.Charge transport,mechanical and storage performances of sepiolite based composite polymer electrolytes[J].Chemistry Select,2016,1(18):5821-5827.
[33] Mejía A,Devaraj S,Guzmán J,et al.Scalable plasticized polymer electrolytes reinforced with surface-modified sepiolite fillers-afeasibility study in lithium metal polymer batteries[J].Journal of Power Sources,2016,306:772-778.
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