Research progress on core-shell structure and doping element of Pt based catalyst for DMFC

Zhang Man, Yang Mingrong

doi:10.19817/j.cnki.issn 1006-3536.2021.09.011

New Chemical Materials >

2021 , Vol. 49 >Issue 9: 47 - 50

DOI: https://doi.org/10.19817/j.cnki.issn 1006-3536.2021.09.011

Research progress on core-shell structure and doping element of Pt based catalyst for DMFC

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Department of Chemistry and Life Sciences,Chifeng University,Chifeng 024000

Received date: 2020-06-04

Revised date: 2021-06-10

Online published: 2021-09-30

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Abstract

Direct methanol fuel cell (DMFC) has been widely concerned as an environmentally friendly clean energy source,but its promotion has been seriously hindered due to its catalyst limitations.In recent years,there have been many reports on the research and preparation of platinum(Pt) based catalysts.The modification,doping elements and the regulation of catalyst structure of DMFC Pt based catalysts by scholars at home and abroad were reviewed.It was found that most of the non-metallic elements doped carbon and nitrogen,graphene as the support of the catalyst electrocatalytic effect was significant.The transition metal doping changed the electronic structure of the catalyst to speed up the reaction process.More scholars tend to prepare core-shell Pt based catalyst,the advantage was that the active site exposure was more obvious,the catalytic effect was better.

Key words： core-shell structure; transition metal; low platinum; carbon material; nitrogen doping

Cite this article

Zhang Man, Yang Mingrong . Research progress on core-shell structure and doping element of Pt based catalyst for DMFC[J]. New Chemical Materials, 2021 , 49(9) : 47 -50 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.09.011

References

[1] 林佩俭,苗鹤,王洲航,等.固体氧化物燃料电池(SOFC)钛基钙钛矿阳极的研究进展[J].材料导报,2020,34(5):5032-5038.
[2] 李春光,彭宇,潘庆芝,等.直接甲醇燃料电池催化剂的制备与表征综合化学实验[J].化学教育(中英文),2019,40(20):27-30.
[3] 郑霞,肖海连,白强,等.TRIZ理论在甲醇燃料电池催化剂性能改进中的应用[J].山东化工,2019,48(23):148-149,151.
[4] Jeon I Y,Zhang S,Zhang L P,et al.Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction:the electron spin effect[J].Advanced materials (Deerfield Beach,Fla.),2013,25(42):1-8.
[5] Deng Yijie,Dong Yuanyuan,Wang Guanghua,et al.Well-defined ZIF-derived Fe-N codoped carbon nanoframes as efficient oxygen reduction catalysts[J].ACS Applied Materials & Interfaces,2017,9(11):1-28.
[6] 杨伟,陈胜洲,董新法,等.直接甲醇燃料电池用Co-N-C电催化剂的制备及性能[J].华南理工大学学报(自然科学版),2012,40(3):10-14.
[7] Xu Feng,Wang Dingqi,Sa Baisheng,et al.One-pot synthesis of Pt/CeO₂/C catalyst for improving the ORR activity and durability of PEMFC[J].International Journal of Hydrogen Energy,2017,42(18):13011-13019.
[8] 刘帅超.基于多孔石墨烯材料的直接甲醇燃料电池阳极催化剂的制备和性能研究[D].呼和浩特:内蒙古大学,2019.
[9] 郑锐萍,廖世军.碳材料的掺杂改性及其用于燃料电池催化剂的研究[J].表面技术,2015,44(1):34-40.
[10] Groves M N,Chan A S W,Malardier-Jugroot C,et al.Improving platinum catalyst binding energy to graphene through nitrogen doping[J].Chemical Physics Letters,2009,481(4):214-219.
[11] 郭瑞华,景晓环,李慧琴,等.基于不同碳载体的直接乙醇燃料电池阳极Pt基催化剂的制备及性能表征[J].稀有金属材料与工程,2019,48(7):2284-2291.
[12] Liang Liang,Xiao Meiling,Zhu Jianbing,et al.Low-temperature synthesis of nitrogen doped carbon nanotubes as promising catalyst support for methanol oxidation[J].Journal of Energy Chemistry,2018,04(3):001-014.
[13] Lai L F,Potts J R,Zhan D,et al.Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction[J].Energy & Environmental Science,2012,5(7):7936.
[14] Hou Lijie,Guo Jianing,Xiang Zhonghua.Highly efficient electrocatalysts derived from carbon black supported non-precious metal macrocycle catalysts for oxygen reduction reaction[J].Journal of Energy Chemistry,2018,20(38):1-6.
[15] Du Nana,Wang Chengming,Long Ran,et al.N-doped carbon-stabilized PtCo nanoparticles derived from Pt@ZIF-67:highly active and durable catalysts for oxygen reduction reaction[J].Nano Research,2017,10(9):0124-0134.
[16] 郭瑞华,钱飞,安胜利,等.Ni添加对直接乙醇燃料电池Pt基催化剂催化性能的影响[J].稀有金属材料与工程,2019,48(8):2683-2688.
[17] Chen C,Kang Yijin,Huo Ziyang,et al.ChemInform abstract:highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces[J].ChemInform,2014,343(6177):1339-1343.
[18] 唐雪君,方达晖,瞿丽娟,等.微量Co修饰的碳载超细Pt纳米粒子的制备及其在燃料电池氧还原催化中的应用(英文)[J].催化学报,2019,40(4):504-516.
[19] Zhang Huijuan,Jiang Qizhong,Sun Liangliang,et al.3D non-precious metal-based electrocatalysts for the oxygen reduction reaction in acid media[J].International Journal of Hydrogen Energy,2009,35(15):8295-8302.
[20] 牛立博,褚晓宁,张淼,等.Ni-La@mSiO₂催化剂的制备及其在二苯酮加氢反应中的性能[J].河北大学学报(自然科学版),2016,36(4):369-373,386.
[21] Chen Xiaoqi,Deng Dehui,Pan Xiulian,et al.Iron catalyst encapsulated in carbon nanotubes for CO hydrogenation to light olefins[J].Chinese Journal of Catalysis,2015,36(9):1631-1637.
[22] Hunt S T,Milina M,Alba-Rubio A C,et al.Self-assembly of noble metal monolayerson transition metal carbide nanoparticle catalysts[J].Science,2016,352:974-978.
[23] Peng Yi,Chen Shaowei.Electrocatalysts based on metal@carbon core@shell nanocomposites:an overview[J].Green Energy & Environment,2018,3(4):335-351.
[24] 龙翔宇,雷霆,王坤婵,等.以HKUST-1为前驱体的Cu@Pt/C催化剂的结构及对甲醇的催化氧化性能研究[J].粉末冶金材料科学与工程,2019,24(3):289-295.
[25] Ye Bo,Jiang Ronghua,Yu Zebin,et al.Pt(111) quantum dot engineered Fe-MOF nanosheet arrays with porous core-shell as an electrocatalyst for efficient overall water splitting[J].Journal of Catalysis,2019,380:307-317.
[26] Lee Sehyun,Jang Juehyuk,Jang Injoon,et al.Development of robust Pt shell through organic hydride donor in PtCo@Pt core-shell electrocatalysts for highly stable proton exchange membrane fuel cells[J].Journal of Catalysis,2019,379:112-120.
[27] Tian Xinlong,Luo Junming,Nan Haoxiong,et al.Transition metal nitride coated with atomic layers of Pt as a low-cost,highly stable electrocatalyst for the oxygen reduction reaction[J].Pubmed,2016,138(5):1-27.
[28] Jung W S,Popov B N.Hybrid cathode catalyst with synergistic effect between carbon composite catalyst and Pt for ultra-low Pt loading in PEMFCs[J].Elsevier B V,2017,295(1):65-74.
[29] Lee Hyunjoon,Sung Yungeun,Choi Insoo,et al.Novel synthesis of highly durable and active Pt catalyst encapsulated in nitrogen containing carbon for polymer electrolyte membrane fuel cell[J].Elsevier B V,2017,362(2):228-235.

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