Synthesis and application of new 2D Mxenes

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  • 1. Institute of Land Engineering and Technology,Shaanxi Provincial Land Engineering Construction Group Co.,Ltd.,Xi'an 710075;
    2. Shaanxi Provincial Land Engineering Construction Group Co.,Ltd.,Xi'an 710075;
    3. Key Laboratory of Degraded and Unused Land Consolidation Engineering,the Ministry of Land and Resources,Xi'an 710075;
    4. Shaanxi Provincial Land Consolidation Engineering Technology Research Center,Xi'an 710075

Received date: 2020-03-27

  Revised date: 2021-04-01

  Online published: 2021-08-19

Abstract

MXenes is a new class of two-dimensional(2D) transition metal carbides,nitrides,and carbonitrides.Due to its unique conductivity,hydrophilicity,excellent thermal stability,large interlayer distance,easy-to-adjust structure,and high ratio Characteristics such as surface area have received widespread attention in recent years.The current synthesis methods of 2D MXenes were discussed,and introduced the current applications in batteries,supercapacitors,adsorption,membranes,and photocatalysis through the properties of different 2D MXenes materials.

Key words: MXene; synthesis; application

Cite this article

Yang Chenxi, Wang Jian, Lu Yangjie, Shi Chendi . Synthesis and application of new 2D Mxenes[J]. New Chemical Materials, 2021 , 49(7) : 52 -55 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.07.012

References

[1] 樊懋,王琳,张玉娟,等.MXene材料用于放射性元素及重金属离子去除的研究进展[J].中国科学:化学,2019,49(1):27-38.
[2] 彭超.二维过渡金属碳化物(MXene)基光催化剂的制备、性能与催化机理研究[D].广州:华南理工大学,2017.
[3] Jun B,Kim S,Heo J,et al.Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications[J].Nano Research,2019,12(1):471-487.
[4] Chaudhari N,Jin H,Kim B,et al.MXene:an emerging two-dimensional material for future energy conversion and storage applications[J].Journal of Materials Chemistry A,2017,5(47):24564-24579.
[5] Hu M,Hu T,Li Z,et al.Surface functional groups and interlayer water determine the electrochemical capacitance of Ti3C2Tx MXene[J].ACS Nano,2018,12(4):3578-3586.
[6] Thakur A,Hwang J,Sathyamurthy R.A state of art critical review on advancement in MXenes for electrochemical energy storage in the view of interlayer spacing[J].ECS Transactions,2020,99(1):143-152.
[7] Zhang C,Ma Y,Zhang X,et al.Two-dimensional transition metal carbides and nitrides (MXenes):synthesis,properties,and electrochemical energy storage applications[J].Energy & Environmental Materials,2019,3(1):29-55.
[8] Tygesen A,Pandey M,Vegge T,et al.The role of long-range dispersion forces in modelling of MXenes as battery electrode materials[J].The Journal of Physical Chemistry C,2019,123(7):4064-4071.
[9] Aierken Y,Sevik C,Gülseren O,et al.MXenes/graphene heterostructures for Li battery applications:a first principles study[J].Journal of Materials Chemistry A,2018,6(11):2337-2345.
[10] Zhang Y,Zhang N,Ge C.First-principles studies of adsorptive remediation of water and air pollutants using two-dimensional MXene materials[J].Materials,2018,11(11):2281-2290.
[11] Xu D,Li Z,Li L,et al.Insights into the photothermal conversion of 2D MXene nanomaterials:synthesis,mechanism,and applications[J].Advanced Functional Materials,2020,30(47):712-726.
[12] Wu Y,Li X,Zhao H,et al.Recent advances in transition metal carbides and nitrides (MXenes):characteristics,environmental remediation and challenges[J].Chemical Engineering Journal,2021,418:121-132.
[13] Jun B,Kim S,Heo J,et al.Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications[J].Nano Research,2019,12:471-487.
[14] 朱小磊.基于新型多孔碳/铋复合材料和MXenes的重金属电化学传感研究[D].武汉:华中科技大学,2018.
[15] Wei Y,Soomro R,Xie X,et al.Design of efficient electrocatalysts for hydrogen evolution reaction based on 2D MXenes[J].Journal of Energy Chemistry,2020,55:244-255.
[16] Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2[J].Adv Mater,2011,23(37):4248-4253.
[17] Naguib M,Come J,Dyatkin B,et al.MXene:a promising transition metal carbide anode for lithium-ion batteries[J].Electrochem Commun,2012,16(1):61-64.
[18] Chang R,Zhao M,Makaryan T,et al.Porous two-dimensional transition metal carbide (MXene) flakes for high-performance Li-ion storage[J].Chemelectrochem,2016,3(8):689-693.
[19] Tang Q,Zhou Z,Shen P.Are MXenes promising anode materials for Li ion batteries?Computational studies on electronic properties and Li storage capability of Ti3C2 and Ti3C2X2(X=F,OH) monolayer[J].J Am Chem Soc,2012,134(40):16909-16916.
[20] Halim J,Lukatskaya M,Cook K,et al.Transparent conductive two-dimensional titanium carbide epitaxial thin films[J].Chemistry of Materials,2014,26(7):2374-2381.
[21] Karlsson L,Birch J,Halim J,et al.Atomically resolved structural and chemical investigation of single MXene sheets[J].Nano Letters,2015,15(8):4955-4960.
[22] Wang L,Zhang H,Wang B,et al.Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process[J].Electronic Materials Letters,2016,12(5):702-710.
[23] Fu Q,Wang X,Zhang N,et al.Self-assembled Ti3C2Tx/SCNT composite electrode with improved electrochemical performance for supercapacitor[J].J Colloid Interf Sci,2018,511(1):128-134.
[24] Liu F,Zhou J,Wang S,et al.Preparation of high-purity V2C MXene and electrochemical properties as Li-ion batteries[J].J Electrochem Soc,2017,164(4):709-713.
[25] 谢俊峰.二维晶体的功能导向性设计及其电化学性能研究[D].合肥:中国科学技术大学,2014.
[26] Xiao Y,Hang J,Sun Y.Transition metal carbide-based materials:synthesis and applications in electrochemical energy storage[J].J Mater Chem A,2016,4(27):10379-10393.
[27] Ghidiu M,Kota S,Halim J,et al.Alkylammonium cation intercalation into Ti3C2 (MXene):effects on properties and ion-exchange capacity estimation[J].Chemistry of Materials,2017,29(3):1099-1106.
[28] Ahmed B,Anjum D,Gogotsi Y,et al.Atomic layer deposition of SnO2 on MXene for Li-ion battery anodes[J].Nano Energy,2017,34(1):249-256.
[29] Jiang Q,Narendra K,Mohamed A,et al.All Pseudocapacitive MXene-RuO2asymmetric supercapacitors[J].Advanced Energy Materials,2018,8(13):170-179.
[30] Chowdhury S,Balasubramanian R.Recent advances in the use of graphene-family nanoadsorbents for removal of toxic pollutants from wastewater[J].Adv Colloid Interface Sci,2014,204(2):35-56.
[31] Fard A,Mckay G,Chamoun R,et al.Barium removal from synthetic natural and produced water using MXene as two dimensional (2-D) nanosheet adsorbent[J].Chemical Engineering Journal,2017,1(317):331-342.
[32] Zhu J,Hou J,Uliana A,et al.The rapid emergence of two-dimensional nanomaterials for high-performance separation membranes[J].J Mater Chem A,2018,6(9):3773-3792.
[33] Liu G,Shen J,Liu Q,et al.Ultrathin two-dimensional MXene membrane for pervaporation desalination[J].Journal of Membrane Science,2017,548(15):548-558.
[34] Ran J,Gao G,Li F,et al.Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production[J].Nature Communications,2017,8(3):13907.
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