9,10-dihydro-9-oxa-10-phenanthrene-10-oxide (DOPO),as a new organophosphorus flame retardant,has the characteristics of low toxicity,low smoke,non-migration and good compatibility with polymer.Therefore,the synthesis of DOPO and its derivatives and their application in flame-retarding polymer materials were introduced.
Wang Junkai, Song Wensheng, Xu Shaoshuai, Liu Jichun, Gou Minglei
. Advances in the synthesis and application of DOPO and its derivative[J]. New Chemical Materials, 2021
, 49(5)
: 245
-248
.
DOI: 10.19817/j.cnki.issn 1006-3536.2021.05.055
[1] Wang C S,Shieh J Y,Sun Y M.Synthesis and properties of phosphorus containing PET and PEN(I)[J].Journal of Application Polymer Science,1998,70(10):1959-1964.
[2] Wang C S,Shieh J Y.Synthesis and properties of epoxy resins containing 2-(6-oxid-6H-dibenz〈c,e〉〈1,2〉oxaphosphorin-6-yl)1,4-benzenediol[J].Polymer,1998,39(23):5819-5826.
[3] Ulrich W,Franck M.Benzoxazine fireproofing agents in thermoplastic or thermosetting composition,WOP0257279[P].2002-05-25.
[4] Saito T,Shi K.Cyclic organophosphorus compounds and process for marking same,USP3702878[P].1972-11-24.
[5] Saito T,Kitani M,Mori K,et al.organophosphorus compounds and process for production thereof,USP4086206[P].1978-04-25.
[6] Hans-Josef Buysch,Volker Glock,Bernd Griehsel,et al.Process for preparing 6-oxo-(6H)-dibenz-[c,e][1,2]-oxaphosphorins,USP 5650530[P].1997-07-22.
[7] 蒋建中,蔡春.新型反应型阻燃剂中间体DOPO的合成工艺改进[J].南京理工大学学报,2005,29(6):716-719.
[8] 洪呈祥,马会娟,郑磊,等.DOPO型环氧树脂的制备及阻燃性能研究[J].胶体与聚合物,2015,33(1):17-19.
[9] 任庆龙,夏英,丛世杰,等.DOPO无卤阻燃PP/EVA复合材料的性能研究[J].合成纤维工业,2016,39(6):26-29.
[10] 王兆礼,赵升云,赵缙云,等.DOPO阻燃PLA/BF复合材料的制备与性能研究[J].塑料科技,2018,46(4):29-33.
[11] 凤四海,陈豪,智茂永,等.DOPO阻燃剂对软质聚氨酯泡沫阻燃性能的影响[J].塑料科技,2019,47(10):137-141.
[12] Endo S,Kashihara T,Osako A,et al.Phosphorus-containing compounds,USP 4172590[P].1978-11-28.
[13] 刘吉平,王正伟,陈丽春.DOPO衍生物的制备[J].中国阻燃,2010(5):4-5.
[14] 蒋建中.新型反应型阻燃剂中间体DOPO及其衍生物的合成[D].南京:南京理工大学,2004.
[15] Lin C H,Wu C Y,Wang C S.Synthesis and properties of phosphorus‐containing advanced epoxy resins Ⅱ[J].Journal of Applied Polymer Science,2000,78(1):228-235.
[16] Wang C S,Lin C H,Chiu H C.Phosphorus-containing flame-re-tardant cured epoxy resins,USP 20010003771[P].2001-06-14.
[17] Wang C S,Lin C H.Synthesis and properties of phosphorus containing polyarylates derived from 2-(6-oxid-6H-dibenz〈c,e〉〈1,2〉oxaphosphorin-6-yl)-1,4-dithydroxy-phenylene[J].Polymer,1999,40(15):4387-4398.
[18] Wang C S,Lin C H,Chen C Y.Synthesis and properties of phosphorus-containing polyesters derived from 2-(6-oxid-6H-dibenz〈c,e〉〈1,2〉oxaphosphorin-6-yl)-1,4-hydroxyethoxy phenylene[J].Polym Sci PartA:Polym Chem,1998,36(17):3051-3061.
[19] 杜峰,项尚林,邹巍巍.有机磷阻燃剂DOPO-HQ改性吸油聚氨酯泡沫的研究[J].中国塑料,2015,29(5):85-88.
[20] 张立强,张猛,周永红,等.阻燃剂DOPO-FR的合成及阻燃聚氨酯的性能研究[J].中国塑料,2013,27(11):84-88.
[21] 周威,郑开梅,周永红,等.新型含磷阻燃型桐油基聚氨酯硬泡的制备及性能表征[J].化工进展,2019,38(7):278-283.
[22] 王浩,郭文征,刘治国,等.DAM-DOPO的合成及其阻燃性能[J].中国塑料,2014,28(4):87-91.
[23] 张五一,王喜顺.新型DOPO基反应型阻燃剂在聚氨酯中的应用[J].塑料,2013,42(4):89-92.
[24] 万元俊,吴爽,马晓峰,等.DOPO及其衍生物的合成和阻燃性能研究进展[J].高分子通报,2017(11):45-53.
[25] 周颖,张道海,秦舒浩.DOPO衍生物的合成与阻燃应用研究现状[J].材料导报,2019,30(5):901-906.
[26] Jian R K,Wang P,Duan W,et al.Synthesis of a novel P/N/S-containing flame retardant and its application in epoxy resin:thermal property,flame retardance and pyrolysis behavior[J].Industrial & Engineering Chemistry Research,2016,55:11520-11527.
