利用芳砜纶的阻燃性和金属丝的导电性制备了芳砜纶/不锈钢丝阻燃导电织物,并研究了织物的力学性能、阻燃性能和电磁屏蔽性能。结果表明:用细度为20S/2的芳砜纶做包覆材料纺成的包芯纱断裂强度和断裂伸长率最大,用该规格包芯纱制备的导电织物阻燃性能最好,燃烧损毁长度为56.34mm;织物的电磁屏蔽效能与织物层数、层压角度有关,在导电织物层压角度为0°/45°/90°/-45°/0°/45°和0°/90°/0°/90°/0°/90°且织物层数为4层时,3种导电织物的平均电磁屏蔽效能比单层时约提高9dB;当织物层数为5层及以上时,电磁屏蔽效能比单层时平均提高约15dB,电磁屏蔽效能显著增加。
The flame retardancy of polysufonamide and the electrical conductivity of metal filaments were used to prepare knitted fabrics with electromagnetic shielding and flame retardancy,and the mechanical properties,flame retardancy and electromagnetic shielding effectiveness of the fabrics were investigated.Results shown that the breaking strength and elongation at break of core spun yarn used polysulfonamide with the fineness of 20S/2 as cladding materials were all the largest.The flame retardant performance of the conductive fabric woven by this specification of core spun yarn was the best,and the burning damage length was 56.34mm.When the laminating angles of the fabric were 0°/45°/90°/-45°/0°/45° and 0°/90°/0°/90°/0°/90° and the laminating number was 4 layers,the average value of dB was about 9 higher than that of the single layer.When the laminating number was 5 layers or more,the dB value was increased by about 15dB compared with the single layer,and the electromagnetic shielding effect was significantly increased.
[1] 戴玉婷,王莉莉,荣新山,等.电磁屏蔽材料的研究进展[J].化工新型材料,2015,43(10):24-26.
[2] Lou Chingwen,Lin Tingan,Chen Anpang et al.Stainless steel/polyester woven fabrics and copper/polyester woven fabrics:manufacturing techniques and electromagnetic shielding effectiveness[J].Journal of Industrial Textiles,2015,45(1).:214-236.
[3] 文珊.不锈钢纤维织物的屏蔽和服用性能[J].纺织学报,2004,25(6):79-81.
[4] 肖红,唐章宏,王群,等.电磁屏蔽织物的导电网格结构及其屏蔽效能的一般影响规律研究[J].纺织学报,2015,36(2):35-42.
[5] Park J G,Louis J,Cheng Q,et al.Electromagnetic interference shielding properties of carbon nanotube buckypaper composites[J].Nanotechnology,2009,20(41):415702.
[6] Hwang P W,Chen A P,Lou C W,et al.Electromagnetic shielding effectiveness and functions of stainless steel/bamboo charcoal conductive fabrics[J].Journal of Industrial Textiles,2013,44(3):477-494.
[7] Chen H C,Lee K C,Lin J H,et al.Comparison of electromagnetic shielding effectiveness properties of diverse conductive textiles via various measurement techniques[J].Journal of Materials Processing Technology,2007,192-193(4):549-554.
[8] Lin J H,Chen A P,Hsieh C T,et al.Physical properties of the functional bamboo charcoal/stainless steel core-sheath yarns and knitted fabrics[J].Textile Research Journal,2011,81(6):567-573.
[9] Ramachandran T,Vigneswaran C.Design and development of copper core conductive fabrics for smart textiles[J].Journal of Industrial Textiles,2009,39(1):81-93.
[10] Erdumlu N,Saricam C.Electromagnetic shielding effectiveness of woven fabrics containing cotton/metal-wrapped hybrid yarns[J].Journal of Industrial Textiles,2016,46(4):1084-1103.
[11] 汪晓峰,张玉华.芳砜纶的性能及其应用[J].纺织导报,2005(1):18-20.
[12] 任加荣,汪晓峰,张玉华.芳砜纶的市场开发与应用[J].产业用纺织品,2007,25(5):1-6.[13] Li H,Zhu Y,Xu B,et al.Preparation and characterization of all para-position polysulfonamide fiber[J].Journal of Applied Polymer Science,2013,127(1):342-348.
[14] Wang Zhenhua,Shen Henggen.Tensile behavior of polysulfonamide fiber after chemical treatment[J].Energy Procedia,2012,16:432-437.
[15] 任加荣,王锦,俞镇慌.芳砜纶纤维热处理力学性能分析[J].国际纺织导报,2007(11):27-33.
[16] 张丽,李亚滨,刘建中.芳砜纶纤维耐热性能的研究[J].天津工业大学学报,2006,25(6):17-19.
[17] Peng H K,Wang Y T,Li T T,et al.Superhydrophobic/flame retardant/EMI shielding fabrics:manufacturing techniques and property evaluations[J].Applied Sciences-Basel,2019,9(9):1914.
[18] Koprowska J,Pietranik M,Stawski W.New type of textiles with shielding properties[J].Fibres & Textiles in Eastern Europe,2004,3(47):39-42.
[19] Chen H C,Lin J H,Lee K C.Electromagnetic shielding effectiveness of copper/stainless steel/polyamide fiber co-woven-knitted fabric reinforced polypropylene composites[J].Journal of Reinforced Plastics & Composites,2007,27(2):187-204.
[20] Tezel S,Kavusturan Y,Vandenbosch G A,et al.Comparison of electromagnetic shielding effectiveness of conductive single jersey fabrics with coaxial transmission line and free space measurement techniques[J].Textile Research Journal,2014,84:461-476.
基金资助
国家自然科学基金青年项目(51503145);高技术有机纤维四川省重点实验室开放课题基金(PLN2016-07)